Coated photoconductors

Patent metadata

Field	Value
Publication number	US-9366978-B2
Application number	US-201214391012-A
Country	US
Kind code	B2
Filing date	Jun 25, 2012
Priority date	Jun 25, 2012
Publication date	Jun 14, 2016
Grant date	Jun 14, 2016

Abstract

The present disclosure is related to coated photoconductors. In an example, a coated photoconductor can comprise a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto and a top coating adhered to the photoconductor. The top coating can comprise a cross-linkable polymer, a cross-linker, and a polymeric dopant having a weight average molecular weight of less than 500,000. Additionally, the top coating can have a thickness of 0.1 μm to 12 μm and the polymeric dopant can be present in the top coating at a concentration of 0.1 wt % to 10 wt %.

First claim

What is claimed is:

1. A coated photoconductor, comprising:
a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto; and
a top coating adhered to the photoconductor, the top coating comprising a cross-linkable polymer, a cross-linker, and a polymeric dopant having charge transport properties and having a weight average molecular weight of less than 500,000;
wherein the top coating has a thickness of 0.1 μm to 12 μm and the polymeric dopant is present in the top coating at a concentration of 0.1 wt % to 10 wt %.

2. The coated photoconductor of claim 1 , wherein the top coating has a thickness of 0.2 μm to 1 μm.

3. The coated photoconductor of claim 1 , wherein the polymeric dopant is present in the top coating at a concentration of 0.1 wt % to 2 wt %.

4. The coated photoconductor of claim 1 , wherein the substrate is a photo imaging plate of a liquid electrophotographic printer.

5. The coated photoconductor of claim 1 , wherein the cross-linkable polymer comprises polymerized monomers selected from acrylates, methacrylates, styrenes, vinyl monomers, and combinations thereof.

6. The coated photoconductor of claim 1 , wherein the cross-linkable polymer comprises a polymerized monomer selected from the group of methyl methacrylate, butyl acrylate, butyl methacrylate, hexyl acrylate, hexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, lauryl acrylate, lauryl methacrylate, octadecyl acrylate, octadecyl methacrylate, stearyl methacrylate, acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, styrene, methylstyrene, and combinations thereof.

7. The coated photoconductor of claim 1 , wherein the cross-linkable polymer is an acrylate copolymer or methacrylate copolymer.

8. The coated photoconductor of claim 1 , wherein the cross-linker is selected from the group of polyisocyanates, polyols, polyesters, polyamines, and combinations thereof.

9. The coated photoconductor of claim 1 , wherein the charge generation layer comprises charge generation materials selected from the group of crystalline selenium, amorphous selenium, selenium-tellurium, selenium-tellurium-halogen, selenium-arsenic compound, amorphous silicon, phthalocyanine pigments, metal phthalocyanine, non-metal phthalocyanine, azulenium salt pigments, aquatic acid methine pigment, azo pigments having a carbazole skeleton, azo pigments having a triphenylamine skeleton, azo pigments having diphenylamine skeleton, azo pigments having dibenzothiophene skeleton, azo pigments having fluorenone skeleton, azo pigments having oxadiazole skeleton, azo pigments having bisstylbene skeleton, azo pigments having distyryl oxidiazole skeleton, azo pigments having distyrylcarbazole skeleton, perylene pigments, anthraquinone quinone pigments, polycyclic quinone pigments, quinone imine pigments, diphenylmethane pigments, triphenylmethane pigments, benzoquinone pigments, naphtoquinone pigments, cyanine pigments, azomethine pigments, indigoido pigments, bisbenzimidazole pigments, and mixtures thereof.

10. The coated photoconductor of claim 1 , wherein the charge transport layer comprises charge transport materials selected from the group of chloroanil, bromoanil, tetracyanoethylene, tetracyano quinodimethane, 2,4,7-trinitro-9-fluorenone, 2,4,5,7-tetranitro-9-fluorenone, 2,4,5,7-tetranitroxanthone, 2,4,8-trinitrothioxanthone, 2,6,8-trinitro-4H-indino[1,2-b]thiophene-4-on, 1,3,7-trinitro-dibenzothiophene-5,5-dioxide, diphenoquinones, oxazoles, oxadiazoles, imidazoles, monoarylamines, diarylamines, triarylamines, stilbenes, α-phenyl stilbenes, benzidines, diarylmethanes, triarylmethanes, 9-styrylanthracenes, pyrazolines, divinyl benzenes, hydrazones, indenes, butadienes, pyrenes, bisstylbenes, enamines, aromatic tertiary amines, and mixtures thereof.

11. The coated photoconductor of claim 1 , wherein the top coating provides an optical density of at least 0.2 after 300,000 printed images at 20% nominal coverage and provides an optical density of at least 0.8 after 300,000 impressions at 80% nominal coverage.

12. A coated photoconductor comprising:
a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto; and
a top coating adhered to the photoconductor, the top coating comprising a cross-linkable polymer, a cross-linker, and a polymeric dopant having charge transport properties and having a weight average molecular weight of less than 500,000;
wherein the top coating has a thickness of 0.1 μm to 12 μm and the polymeric dopant is present in the top coating at a concentration of 0.1 wt % to 10 wt %, and
wherein the polymeric dopant is selected from the group of polyfluorene and its co-polymers; polyanilines and its co-polymers; polythiophenes and its co-polymers; polycarbazoles and its co-polymers; and mixtures thereof.

13. A coated photoconductor comprising:
a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto; and
a top coating adhered to the photoconductor, the top coating comprising a cross-linkable polymer, a cross-linker, and a polymeric dopant having charge transport properties and having a weight average molecular weight of less than 500,000;
wherein the top coating has a thickness of 0.1 μm to 12 μm and the polymeric dopant is present in the top coating at a concentration of 0.1 wt % to 10 wt %, and
wherein the polymeric dopant is a polyfluorene copolymer having a weight average molecular weight of less than 50,000.

14. A process of manufacturing a photoconductor, comprising applying a top coating to the photoconductor, the photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto, wherein the top coating comprises a cross-linkable polymer, a cross-linker, and a polymeric having charge transport properties, and having a weight average molecular weight of less than 500,000, and wherein the polymeric dopant is dispersed throughout the top coating.

15. The process of claim 14 , further comprising the step of heating the top coating to cross-link the cross-linkable polymer.

16. A process of manufacturing a photoconductor, comprising applying a top coating to the photoconductor, the photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto, wherein the top coating comprises a cross-linkable polymer, a cross-linker, and a polymeric dopant having charge transport properties, and having a weight average molecular weight of less than 500,000, and wherein the polymeric dopant is dispersed throughout the top coating,
wherein the polymeric dopant is at least one of:
selected from the group of polyfluorene and its co-polymers; polyanilines and its co-polymers; polythiophenes and its co-polymers; and polycarbazoles and its co-polymers; and
a polyfluorene copolymer having a weight average molecular weight of less than 50,000.

Assignees

• Nauka Krzysztof
• Zhou Zhang-Lin
• Ng Hou T
• Hewlett Packard Development Co

Inventors

• Nauka Krzysztof
• Zhou Zhang-Lin
• Ng Hou T

Classifications

• G03G5/14778

  Polycondensates comprising sulfur atoms in the main chain · CPC title

• G03G5/14734

  Polymers comprising at least one carboxyl radical, e.g. polyacrylic acid, polycrotonic acid, polymaleic acid; Derivatives thereof, e.g. their esters, salts, anhydrides, nitriles, amides · CPC title

• G03G5/14752

  Polyesters · CPC title

• G03G5/14769

  Other polycondensates comprising nitrogen atoms with or without oxygen atoms in the main chain · CPC title

• G03G5/005

  Materials for treating the recording members, e.g. for cleaning, reactivating, polishing · CPC title