Light-emitting device

Patent metadata

Field	Value
Publication number	US-9929350-B2
Application number	US-201213405627-A
Country	US
Kind code	B2
Filing date	Feb 27, 2012
Priority date	Feb 28, 2011
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A light-emitting element includes a light-emitting layer including a guest, an n-type host and a p-type host between a pair of electrodes, where the difference between the energy difference between a triplet excited state and a ground state of the n-type host (or p-type host) and the energy difference between a triplet excited state and a ground state of the guest is 0.15 eV or more. Alternatively, in such a light-emitting element, the LUMO level of the n-type host is higher than the LUMO level of the guest by 0.1 eV or more, or the HOMO level of the p-type host is lower than the HOMO level of the guest by 0.1 eV or more.

First claim

What is claimed is:

1. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising:
a phosphorescent compound;
a first organic compound having an electron-transport property superior to a hole-transport property; and
a second organic compound having a hole-transport property superior to an electron-transport property,

wherein an energy difference between a triplet excited state and a ground state of the first organic compound and an energy difference between a triplet excited state and a ground state of the second organic compound are both higher than an energy difference between a triplet excited state and a ground state of the phosphorescent compound by 0.15 eV or more,
wherein a combination of the first organic compound and the second organic compound is capable of forming an exciplex therebetween,
wherein an excited energy of the exciplex is transferred to the phosphorescent compound so as to emit phosphorescence from the phosphorescent compound, and
wherein the phosphorescent compound, the first organic compound, and the second organic compound are mixed in the light-emitting layer.

2. The light-emitting element according to claim 1 , wherein the exciplex is formed from an anion of the first organic compound and a cation of the second organic compound.

3. The light-emitting element according to claim 1 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.

4. The light-emitting element according to claim 1 , wherein the phosphorescent compound is an organometallic complex.

5. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising:
a phosphorescent compound;
a first organic compound having an electron-transport property superior to a hole-transport property; and
a second organic compound having a hole-transport property superior to an electron-transport property,

wherein a lowest unoccupied molecular orbital level of the first organic compound is higher than a lowest unoccupied molecular orbital level of the phosphorescent compound by 0.1 eV or more,
wherein a combination of the first organic compound and the second organic compound is capable of forming an exciplex therebetween,
wherein an excited energy of the exciplex is transferred to the phosphorescent compound so as to emit light from the phosphorescent compound, and
wherein the phosphorescent compound, the first organic compound, and the second organic compound are mixed in the light-emitting layer.

6. The light-emitting element according to claim 5 , wherein the exciplex is formed from an anion of the first organic compound and a cation of the second organic compound.

7. The light-emitting element according to claim 5 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.

8. The light-emitting element according to claim 5 , wherein the phosphorescent compound is an organometallic complex.

9. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising:
a phosphorescent compound;
a first organic compound having an electron-transport property superior to a hole-transport property; and
a second organic compound having a hole-transport property superior to an electron-transport property,

wherein a highest occupied molecular orbital level of the second organic compound is lower than a highest occupied molecular orbital level of the phosphorescent compound by 0.1 eV or more,
wherein a combination of the first organic compound and the second organic compound is capable of forming an exciplex therebetween,
wherein an excited energy of the exciplex is transferred to the phosphorescent compound so as to emit light from the phosphorescent compound, and
wherein the phosphorescent compound, the first organic compound, and the second organic compound are mixed in the light-emitting layer.

10. The light-emitting element according to claim 9 , wherein the exciplex is formed from an anion of the first organic compound and a cation of the second organic compound.

11. The light-emitting element according to claim 9 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.

12. The light-emitting element according to claim 9 , wherein the phosphorescent compound is an organometallic complex.

13. The light-emitting element according to claim 1 ,
wherein a highest occupied molecular orbital level of the first compound is lower than a highest occupied molecular orbital level of the second compound,
wherein the highest occupied molecular orbital level of the second compound is lower than a lowest unoccupied molecular orbital level of the first compound, and
wherein the lowest unoccupied molecular orbital level of the first compound is lower than a lowest unoccupied molecular orbital level of the second compound.

14. The light-emitting element according to claim 5 ,
wherein a highest occupied molecular orbital level of the first compound is lower than a highest occupied molecular orbital level of the second compound,
wherein the highest occupied molecular orbital level of the second compound is lower than the lowest unoccupied molecular orbital level of the first compound, and
wherein the lowest unoccupied molecular orbital level of the first compound is lower than a lowest unoccupied molecular orbital level of the second compound.

15. The light-emitting element according to claim 9 ,
wherein a highest occupied molecular orbital level of the first compound is lower than the highest occupied molecular orbital level of the second compound,
wherein the highest occupied molecular orbital level of the second compound is lower than a lowest unoccupied molecular orbital level of the first compound, and
wherein the lowest unoccupied molecular orbital level of the first compound is lower than a lowest unoccupied molecular orbital level of the second compound.

16. The light-emitting element according to claim 1 , wherein a molar absorption coefficient of an absorption band in a longest wavelength region of the phosphorescent compound is preferably 2000M −1 ·cm −1 or more.

17. The light-emitting element according to claim 5 , wherein a molar absorption coefficient of an absorption band in a longest wavelength region of the phosphorescent compound is preferably 2000M −1 ·cm −1 or more.

18. The light-emitting element according to claim 9 , wherein a molar absorption coefficient of an absorption band in a longest wavelength region of the phosphorescent compound is preferably 2000M −1 ·cm −1 or more.

19. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer between the pair of electrodes, the light-emitting layer comprising:
a phosphorescent compound;
a first organic compound; and
a second organic compound,

wherein an energy difference between a triplet excited state and a ground state of the first organic compound is higher than an energy difference between a triplet excited state and a ground state of the phosphorescent compound by 0.15 eV or more,
wherein an energy difference between a triplet excited state and a ground state of the second organic compound is higher than an energy difference between the triplet excited state and the ground state of the phosphorescent co

Assignees

• Yamazaki Shunpei
• Seo Satoshi
• Ohsawa Nobuharu
• Shitagaki Satoko
• Inoue Hideko
• Kadoma Hiroshi
• Osaka Harue
• Suzuki Kunihiko
• Takemura Yasuhiko
• Semiconducor Energy Laboratory Co Ltd

Inventors

• Yamazaki Shunpei
• Seo Satoshi
• Ohsawa Nobuharu
• Shitagaki Satoko
• Inoue Hideko
• Kadoma Hiroshi
• Osaka Harue
• Suzuki Kunihiko
• Takemura Yasuhiko

Classifications

• H01L51/0059 Primary

  Electricity · mapped topic

• H01L2251/552

  Electricity · mapped topic

• H01L2251/5384

  Electricity · mapped topic

• H01L51/0067

  Electricity · mapped topic

• H10K50/81

  Anodes · CPC title