Light-emitting element

Patent metadata

Field	Value
Publication number	US-9604928-B2
Application number	US-201213370679-A
Country	US
Kind code	B2
Filing date	Feb 10, 2012
Priority date	Feb 16, 2011
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

A light-emitting element having high external quantum efficiency is provided. A light-emitting element having a long lifetime is provided. A light-emitting element is provided which includes a light-emitting layer containing a phosphorescent compound, a first organic compound, and a second organic compound between a pair of electrodes, in which a combination of the first organic compound and the second organic compound forms an exciplex (excited complex). The light-emitting element transfers energy by utilizing an overlap between the emission spectrum of the exciplex and the absorption spectrum of the phosphorescent compound and thus has high energy transfer efficiency. Therefore, a light-emitting element having high external quantum efficiency can be obtained.

First claim

The invention claimed is:

1. A light-emitting element comprising:
a pair of electrodes; and
a light-emitting layer comprising a phosphorescent compound, a first organic compound, and a second organic compound between the pair of electrodes,
wherein the first organic compound, the second organic compound, and the phosphorescent compound are mixed in the light-emitting layer,
wherein the first organic compound and the second organic compound are selected so as to form an exciplex, and
wherein a peak of an emission spectrum of the exciplex overlaps with an absorption based on a triplet metal-to-ligand charge transfer of the phosphorescent compound.

2. The light-emitting element according to claim 1 , wherein a molar absorption coefficient of the absorption is 2000 M −1 •cm −1 or more.

3. The light-emitting element according to claim 1 , wherein a molar absorption coefficient of the absorption is 5000 M −1 •cm −1 or more.

4. The light-emitting element according to claim 1 , wherein an excitation energy of the exciplex is transferred to the phosphorescent compound so that the phosphorescent compound emits phosphorescence.

5. The light-emitting element according to claim 1 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.

6. The light-emitting element according to claim 1 , wherein the phosphorescent compound is selected from bis(3,5-dimethyl-2-phenylpyrazinato)(dipivaloylmethanato)iridium(III), (acetylacetonato)bis(4,6-diphenylpyrimidinato)iridium(III), bis(2,3,5-triphenylpyrazinato)(dipivaloylmethanato)iridium(III), (acetylacetonato)bis(6-methyl-4-phenylpyrimidinato)iridium(III), and (acetylacetonato)bis(6-tert-butyl-4-phenylpyrimidinato)iridium(III).

7. An electronic device comprising the light-emitting element according to claim 1 .

8. A lighting device comprising the light-emitting element according to claim 1 .

9. A light-emitting element comprising:
a pair of electrodes; and
an EL layer between the pair of electrodes, the EL layer comprising:
a hole-injection layer;
a hole-transport layer over the hole-injection layer;
a light-emitting layer over the hole-transport layer, the light-emitting layer comprising a phosphorescent compound, a first organic compound, and a second organic compound;
an electron-transport layer over the light-emitting layer; and
an electron-injection layer over the electron-transport layer,

wherein the first organic compound, the second organic compound, and the phosphorescent compound are mixed in the light-emitting layer,
wherein the first organic compound and the second organic compound are selected so as to form an exciplex, and
wherein a peak of an emission spectrum of the exciplex overlaps with an absorption based on a triplet metal-to-ligand charge transfer of the phosphorescent compound.

10. The light-emitting element according to claim 9 , wherein a molar absorption coefficient of the absorption is 2000 M −1 •cm −1 or more.

11. The light-emitting element according to claim 9 , wherein a molar absorption coefficient of the absorption is 5000 M −1 •cm −1 or more.

12. The light-emitting element according to claim 9 , wherein an excitation energy of the exciplex is transferred to the phosphorescent compound so that the phosphorescent compound emits phosphorescence.

13. The light-emitting element according to claim 9 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.

14. The light-emitting element according to claim 9 , wherein the phosphorescent compound is selected from bis(3,5-dimethyl-2-phenylpyrazinato)(dipivaloylmethanato)iridium(III), (acetylacetonato)bis(4,6-diphenylpyrimidinato)iridium((III)), bis(2,3,5-triphenylpyrazinato)(dipivaloylmethanato)indium((III)), (acetylacetonato)bis(6-methyl-4-phenylpyrimidinato)indium(III), and (acetylacetonato)bis(6-tert-butyl-4-phenylpyrimidinato)indium(III).

15. An electronic device comprising the light-emitting element according to claim 9 .

16. A lighting device comprising the light-emitting element according to claim 9 .

17. A light-emitting element comprising:
a pair of electrodes;
a first EL layer;
a second EL layer; and
a charge-generation layer between the first EL layer and the second EL layer,
wherein the first EL layer, the second EL layer, and the charge-generation layer are stacked between the pair of electrodes,
wherein at least one of the first EL layer and the second EL layer comprises a light-emitting layer which comprises a phosphorescent compound, a first organic compound, and a second organic compound,
wherein the first organic compound, the second organic compound, and the phosphorescent compound are mixed in the light-emitting layer,
wherein the first organic compound and the second organic compound are selected so as to form an exciplex, and
wherein a peak of an emission spectrum of the exciplex overlaps with an absorption based on a triplet metal-to-ligand charge transfer of the phosphorescent compound.

18. The light-emitting element according to claim 17 , wherein a molar absorption coefficient of the absorption is 2000 M −1 •cm −1 or more.

19. The light-emitting element according to claim 17 , wherein a molar absorption coefficient of the absorption is 5000 M −1 •cm −1 or more.

20. The light-emitting element according to claim 17 , wherein an excitation energy of the exciplex is transferred to the phosphorescent compound so that the phosphorescent compound emits phosphorescence.

21. The light-emitting element according to claim 17 , wherein at least one of the first organic compound and the second organic compound is a fluorescent compound.

22. The light-emitting element according to claim 17 , wherein the phosphorescent compound is selected from bis(3,5-dimethyl-2-phenylpyrazinato)(dipivaloylmethanato)iridium((III)), (acetylacetonato)bis(4,6-diphenylpyrimidinato)iridium(III), bis(2,3,5-triphenylpyrazinato)(dipivaloylmethanato)iridium(III), (acetylacetonato)bis(6-methyl-4-phenylpyrimidinato)iridium(III), and (acetylacetonato)bis(6-tert-butyl-4-phenylpyrimidinato)iridium(III).

23. The light-emitting element according to claim 17 , wherein emission colors of the first and the second EL layers are complementary to each other so that the light-emitting element emits white light.

24. An electronic device comprising the light-emitting element according to claim 17 .

25. A lighting device comprising the light-emitting element according to claim 17 .

26. The light-emitting element according to claim 1 , wherein the first organic compound is a heteroaromatic compound and the second organic compound is an aromatic amine compound.

27. The light-emitting element according to claim 1 , wherein the first organic compound is a heteroaromatic compound and the second organic compound is a carbazole compound.

28. The light-emitting element according to claim 9 , wherein the first organic compound is a heteroaromatic compound and the second organic compound is an aromatic amine compound.

29. The light-emitting element according to claim 9 , wherein the first organic compound is a heteroaromatic compound and the second organic compound is a carbazole compound.

30. The light-emitting element according to claim 17 , wherein the first organic compound is a heteroaromatic compound and the se

Assignees

• Shitagaki Satoko
• Seo Satoshi
• Ohsawa Nobuharu
• Inoue Hideko
• Suzuki Kunihiko
• Semiconductor Energy Lab

Inventors

• Shitagaki Satoko
• Seo Satoshi
• Ohsawa Nobuharu
• Inoue Hideko
• Suzuki Kunihiko

Classifications

• C07D209/86 Primary

  with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system · CPC title

• C07F15/0033

  Iridium compounds · CPC title

• C07D409/10

  linked by a carbon chain containing aromatic rings · CPC title

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• C07D241/12

  with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms · CPC title