Catalyst bed system for an endothermic catalytic dehydrogenation process and an endothermic dehydrogenation process

Patent metadata

Field	Value
Publication number	US-9926241-B2
Application number	US-201214353619-A
Country	US
Kind code	B2
Filing date	Oct 22, 2012
Priority date	Oct 24, 2011
Publication date	Mar 27, 2018
Grant date	Mar 27, 2018

Abstract

A catalyst bed system, and a dehydrogenation process using the same, including a horizontal catalyst bed having a mixture of at least one catalytic material and at least one first inert material, a predetermined volume of at least one second inert material arranged upstream of the catalyst bed, wherein the volume of the reactor above the catalyst bed system is not filled by any solid material (empty space). The volume of the second inert material and the volume of the reactor above the second inert material (empty space) is between 0.04 and 0.73, preferably between 0.06 and 0.3, most preferably between 0.09 and 0.2.

First claim

The invention claimed is:

1. An endothermic catalytic dehydrogenation process comprising:
providing a catalyst bed system in a reactor, wherein the catalyst bed system comprises (1) a horizontal catalyst bed comprising a catalytic material and a first inert material, and (2) a layer of a second inert material of a predetermined volume arranged upstream of the horizontal catalyst bed, wherein the volume of the reactor above the second inert material is not filled by any solid material, wherein the ratio of volume of the second inert material to the volume of the reactor above the second inert material is between 0.04 and 0.73, and wherein the second inert material is selected from:
(i) an oxide of a main group II element, an oxide of a main group III element, an oxide of a transition group III element, an oxide of a transition group IV element, an oxide of a transition group V element, and mixtures thereof,
(ii) a nitride of a main group III element, a nitride of a main group IV element, and mixtures thereof, and
(iii) a carbide of a main group III element, a carbide of a main group IV element, and mixtures thereof;

optionally contacting the catalytic material with a reduction gas to reduce the catalytic material;
passing a heat stream having a first temperature T 1 through the volume of the second inert material and the horizontal catalyst bed, thereby heating the second inert material and the horizontal catalyst bed and regenerating the catalytic material; and
subsequent to passing the heat stream through the volume of the second inert material, passing a hydrocarbon stream having a second temperature T 2 through the volume of the second inert material and the horizontal catalyst bed, thereby dehydrogenating the hydrocarbon stream in the horizontal catalyst bed, wherein:
(i) the second inert material is upstream of the horizontal catalyst bed for both the heat stream and the hydrocarbon stream,
(ii) T 1 is between 700 and 1000° C. and T 2 is between 400 and 650° C., and
(iii) T 1 >T 3 >T 2 , wherein T 3 is a temperature at the interface of the second inert material and the horizontal catalyst bed which fluctuates by about 10 to 100° C.

2. The process according to claim 1 , wherein the temperature T 1 of the heat stream is between 725 and 810° C.

3. The process according to claim 1 , wherein the temperature T 2 of the hydrocarbon stream is between 550 and 650° C.

4. The process according to claim 1 , wherein the temperature T 3 is between 500 and 800° C.

Assignees

• Borealis Ag

Inventors

• Weyne Kristof
• Mathivanan Guhan

Classifications

• B01J8/0285

  Heating or cooling the reactor (for tubular reactors in furnaces B01J8/062) · CPC title

• C07C2521/04

  Alumina · CPC title

• B01J8/0419

  the beds being placed in separate reactors · CPC title

• C07C2523/26

  Chromium · CPC title

• B01J2208/00522

  using inert heat absorbing solids outside the bed · CPC title