Methods for producing C2 to C5 paraffins using a hybrid catalyst comprising gallium metal oxide
US-12030036-B2 · Jul 9, 2024 · US
US2016288093A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016288093-A1 |
| Application number | US-201415035315-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 2, 2014 |
| Priority date | Dec 16, 2013 |
| Publication date | Oct 6, 2016 |
| Grant date | — |
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A heterogeneous catalyst suitable for use in alkane dehydrogenation has an active layer that includes alumina and gallia. The active layer is dispersed on a support such as alumina or silica-modified alumina.
Opening claim text (preview).
What is claimed is: 1 . A heterogeneous alkane dehydrogenation catalyst consisting of a combination of a) both aluminum oxide and gallium oxide dispersed as an active layer on b) an alumina support or a silica-modified alumina support. 2 . The catalyst of claim 1 , wherein the aluminum and the gallium in the active layer are present in a molar ratio of gallium to aluminum that is within a range of from greater than 0.5:1 to less than 15:1. 3 . The catalyst of claim 2 , wherein the molar ratio is within a range of from 1:1 to 10:1. 4 . The catalyst of claim 1 , wherein the aluminum oxide in the active layer is present in an amount within a range of from 0.05 percent by weight to 14 percent by weight and the gallium oxide in the active layer is present in an amount within a range of from greater than 0 percent by weight to less than fourteen by weight, each weight percent being based upon total catalyst weight. 5 . The catalyst of claim 4 , wherein the amount of aluminum oxide is within a range of from 0.05 percent by weight to 5 percent by weight and the gallium oxide is present in an amount within a range of from greater than 0 percent by weight to less than seven percent by weight, each weight percent being based upon total catalyst weight.
of gallium, indium or thallium · CPC title
Boron or aluminium; Oxides or hydroxides thereof · CPC title
of gallium, indium or thallium · CPC title
Impregnation · CPC title
Silica and alumina · CPC title
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