Method for colour-fixing processing of textile and device therefor

Patent metadata

Field	Value
Publication number	US-9920473-B2
Application number	US-201314916031-A
Country	US
Kind code	B2
Filing date	Sep 3, 2013
Priority date	Sep 3, 2013
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

A device for color-fixing processing on textiles includes a supercritical carbon dioxide fluid unit, a fixing liquid storage tank ( 2 ) and a fixing reactor ( 9 ). The fixing liquid storage tank ( 2 ) is below the fixing reactor ( 9 ) and sealed connected by a connecting device ( 6 ). The fixing liquid storage tank ( 2 ) has a cylindrical cavity in which a fluid distributor ( 4 ) is mounted. The fluid distributor ( 4 ) is composed of several interconnected pipes which bend down with the nozzles downward, and one of the pipes is used as circulated fluid inlet ( 1 ) connected with the supercritical carbon dioxide fluid unit, and the rest of the pipes are used as circulated fluid outlets.

First claim

What is claimed is:

1. A device for colour-fixing processing on textiles comprising
a supercritical carbon dioxide fluid unit,
a fixing liquid storage tank ( 2 ), and
a fixing reactor ( 9 ),
wherein said fixing liquid storage tank ( 2 ) is below said fixing reactor ( 9 ), sealed, and connected by a connecting device ( 6 ); said fixing liquid storage tank ( 2 ) has a cylindrical cavity in which a fluid distributor ( 4 ) is mounted; said fluid distributor ( 4 ) is composed of a plurality of interconnected pipes which bend down with the nozzles downward, and one of the pipes is used as circulated fluid inlet ( 1 ) connected with said supercritical carbon dioxide fluid unit, and the rest of the pipes are used as circulated fluid outlets; said fixing reactor ( 9 ) has a cylindrical cavity, with a circulated fluid outlet ( 11 ) on the top and connected with said supercritical carbon dioxide fluid unit; a porous filter ( 5 ) is installed at the bottom of the reactor ( 9 ); and the lower part of a fluid diversion cover ( 7 ) is horn shaped, covering the top of the porous filter ( 5 ), and the top port of the fluid diversion cover ( 7 ) is connected with the opposed port of a textile winding shaft ( 8 ), said textile winding shaft ( 8 ) is a cylindrical hollow shaft, whose top port is closed and holes are set on the cylinder.

2. The device for colour-fixing processing on textiles according to claim 1 , wherein the material of said shaft textile winding ( 8 ) or the material of the internal and external surface of said shaft textile winding ( 8 ) is teflon or non-thermal conductivity material.

3. The device for colour-fixing processing on textiles according to claim 1 , wherein said porous filter ( 5 ) has a shape of a plate of single layer or multi-layer, distributed with micro-porous with mesh number of 50˜2000.

4. A process for colour-fixing processing on textiles comprising the following steps:
a0. providing a device for colour-fixing processing on textiles according to claim 1 ;
a. evenly wrapping textiles which have been dyed in supercritical carbon dioxide fluid around the textile winding shaft in loose state, with a layer of seamless mesh cloth set on the outermost layer, and placing said textile winding shaft into the fixing reactor whose lower port is connected with the top port of the fluid diversion cover;
b. adding fixing mixture containing alkaline fixing accelerant and phase transfer catalyst in the fixing liquid storage tank, and seal connecting the fixing liquid storage tank with the fixing reactor;
c. connecting the circulated fluid outlet of the fixing liquid storage tank and the circulated fluid inlet of the fluid distributor with the supercritical carbon dioxide fluid unit respectively, opening the supercritical carbon dioxide fluid unit, so that the circulated fluid comes into the fixing mixture through the fluid distributor in the fixing liquid storage tank and gets in touch with the mixture; with the help of phase transfer catalyst, alkaline accelerant enters into the hydrophobic fluid phase, and reacts with the functional groups on fibres, achieving the process of phase transfer catalytic fixation on textiles.

5. The process for colour-fixing processing on textiles according to claim 4 , wherein said alkaline fixing accelerants are selected from sodium hydroxide, sodium carbonate and sodium phosphate.

6. The process for colour-fixing processing on textiles according to claim 4 , wherein said phase transfer catalyst is selected from perfluoroalkylsulfonyl quaternary ammonium salt, or quaternary ammonium salt with fat chain containing C 12 ˜C 18 or possessing aromatic base.

Assignees

• Univ Soochow

Inventors

• Long Jiajie
• Cui Chuanglong
• Xu Hongmei
• Wei Xiaochen
• Chen Feng

Classifications

• D06P5/02

  After-treatment · CPC title

• D06P1/67333

  Salts or hydroxides (hydroxylamines D06P1/67308) · CPC title

• D06P1/94

  using dyes dissolved in solvents which are in the supercritical state · CPC title

• D06P5/10 Primary

  with compounds containing metal · CPC title

• D06P1/655

  Compounds containing ammonium groups · CPC title