Reactive dye bath and dyeing process for textiles

Patent metadata

Field	Value
Publication number	US-10604891-B2
Application number	US-201616078649-A
Country	US
Kind code	B2
Filing date	Mar 8, 2016
Priority date	Mar 2, 2016
Publication date	Mar 31, 2020
Grant date	Mar 31, 2020

Abstract

The present invention relates to a reactive dye bath and a dyeing process for textiles. The reactive dye bath for textiles comprises an organic solvent, an aqueous dye solution, a surfactant and a co-surfactant. The reactive dye bath or the dyeing process of the present invention allows for full up-take of the dye without subjecting the textiles to any special pre-treatment and without the addition of a salt for accelerating dyeing, so as to obtain dyed textiles with a higher dyeing depth, uniformity and fastness.

First claim

The invention claimed is:

1. A reactive dye bath for textiles, characterized in that the reactive dye bath comprises a dye emulsion comprising an organic solvent, an aqueous reactive dye solution, a surfactant and a co-surfactant, wherein said aqueous reactive dye solution has a mass ratio of the reactive dye to water is 1:10-200, and wherein the volume ratio of said aqueous reactive dye solution to said organic solvent is 1:1-20.

2. The reactive dye bath for textiles according to claim 1 , wherein the organic solvent is a non-polar organic hydrophobic solvent which can form an immiscible emulsion with water; and wherein the non-polar organic hydrophobic solvent comprises C6-C8 alkanes, C6-C8 isoalkanes, perchloroethylene, decamethylcyclopentasiloxane, dibutyl acetal, glycol ethers, and high flash point hydrocarbons.

3. The reactive dye bath for textiles according to claim 1 , wherein said surfactant is a non-ionic or cationic surfactant; and the volume ratio of said surfactant to said organic solvent is 1:5-20.

4. The reactive dye bath for textiles according to claim 1 , wherein said co-surfactant is an alcohol substance that can change the surface activity and the hydrophilicity-lipophilicity balance of the surfactant; wherein the co-surfactant comprises ethanol, n-propanol, isopropanol, n-butanol, isobutanol, n-pentanol, isopentanol, 1-hexanol, 2-hexanol, 1-octanol, 2-octanol, and fusel oil; and wherein the volume ratio of said co-surfactant to said organic solvent is 1:5-20.

5. A process for dyeing a textile, characterized in that the process comprises the following steps:
(i) preparing a dye bath by uniformly mixing an organic solvent, an aqueous dye solution, a surfactant and a co-surfactant;
(ii) immersing the textile in the dye bath with a bath ratio of 1:5-50, a dyeing time of 10-60 minutes and a dyeing temperature of 40-80° C.;
(iii) removing the textile from the dye bath and squeezing the textile to remove the dye solution until a take-up of 50-150%;
(iv) adding a predetermined amount of an aqueous fixation agent solution to the dye bath, and stirring and mixing the aqueous fixation agent solution and the dye solution until uniform;
(v) re-immersing the textile in the dye bath, to which the aqueous fixation agent solution has been added, with a fixation time of 15-90 minutes and a fixation temperature of 40-80° C.; and
(vi) removing the textile from the dye bath, squeezing the dye solution out of the textile; washing floating colours out of the textile, and hanging and air-drying the textile.

6. The process for dyeing a textile according to claim 5 , wherein said aqueous fixation agent solution is an aqueous solution of sodium carbonate or sodium bicarbonate, with the mass ratio of the fixation agent to water being 1:5-100; and wherein the volume ratio of said aqueous fixation agent solution to said dye solution is 1:1-20.

7. The process for dyeing a textile according to claim 5 , wherein the process further comprises
recovering the organic solvent from the dye solution using methods selected from the group including distillation method, thin membrane filtration, and centrifugation.

8. The process for dyeing a textile according to claim 5 , wherein said textile is loose fibres, yarns and a fabric composed of at least one of cellulosic fibres, protein fibres, and chemical synthetic fibres, wherein said cellulose fibres comprise cotton, hemp, and regenerated cellulose fibres, wherein said protein fibres comprise wool, silkworm silk, and regenerated protein fibres, and wherein said chemical synthetic fibres comprise chinlon 6 and chinlon 66.

9. The process for dyeing a textile according to claim 8 , wherein said textile contains at least one reactive group of hydroxy, amino and carboxy groups, and the textile can be dyed directly without any special pre-treatment.

Assignees

• Hong Kong Res Inst Textiles & Apparel Ltd

Inventors

• Keh Yee Man Edwin

Classifications

• D06P3/666

  reactive group not directly attached to heterocyclic group · CPC title

• D06P5/002

  Locally enhancing dye affinity of a textile material by chemical means · CPC title

• D06P3/248

  using reactive dyes · CPC title

• D06P1/38 Primary

  using reactive dyes · CPC title

• D06P3/66

  using reactive dyes · CPC title