Flame retardant synthetic leather

Patent metadata

Field	Value
Publication number	US-9920472-B2
Application number	US-201314405519-A
Country	US
Kind code	B2
Filing date	Jun 7, 2013
Priority date	Jun 11, 2012
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

Flame retardant synthetic leather having high flame retardancy and excellent physical properties (light resistance, heat resistance and feeling).
The flame retardant synthetic leather contains an organic phosphorus compound (component A) represented by the following formula (1).

(In the formula, X 1 and X 2 are the same or different and each an aromatic substituted alkyl group represented by the following formula ( 2 ).)

AL (Ar) n   (2)

(In the formula, AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, and Ar is a phenyl group, naphthyl group or anthryl group, all of which may have a substituent. “n” is an integer of 1 to 3, and Ar may be bonded to any carbon atom contained in AL.)

First claim

The invention claimed is:

1. A flame retardant synthetic leather comprising a fiber substrate, an adhesive layer and a surface resin layer,
(i) wherein the surface resin layer comprises a polyurethane and has a thickness of 10 to 500 μm, and
(ii) wherein an organic phosphorus compound of the following formula (1-a), which has an average particle diameter of 5 to 100 μm is contained in at least one selected from the group consisting of the fiber substrate, the adhesive layer and the surface resin layer,

2. The flame retardant synthetic leather according to claim 1 , wherein the organic phosphorus compound of the formula (1-a) is contained in an amount of 1 to 300 parts by weight based on 100 parts by weight of the fiber substrate.

3. The flame retardant synthetic leather according to claim 1 , wherein the organic phosphorus compound of the formula (1-a) is contained in an amount of 1 to 300 parts by weight based on 100 parts by weight of the surface resin layer.

4. The flame retardant synthetic leather according to claim 1 , wherein the organic phosphorus compound of the formula (1-a) is contained in an amount of 1 to 300 parts by weight based on 100 parts by weight of the adhesive layer.

5. The flame retardant synthetic leather according to claim 1 , wherein at least one compound selected from the group consisting of aluminum hydroxide, titanium oxide, zinc oxide, expandable graphite, magnesium hydroxide, calcium carbonate, zinc borate, melamine, red phosphorus, ammonium polyphosphate, melamine polyphosphate, melamine cyanurate and phosphoric ester is contained in an amount of 1 to 200 parts by weight based on 100 parts by weight of the organic phosphorus compound of the formula (1-a).

Assignees

• Teijin Ltd
• Marubishi Oil Chemical

Inventors

• Yamanaka Katsuhiro
• Takeda Tsuyoshi
• Kondo Kuniaki
• HARUYOSHI Masaki

Classifications

• D06N2211/28

  Artificial leather · CPC title

• C14C9/00

  Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes · CPC title

• C08K5/5357

  cyclic · CPC title

• C09K21/12

  containing phosphorus · CPC title

• C07F9/657181

  the ring phosphorus atom and, at least, one ring oxygen atom being part of a (thio)phosphonic acid derivative · CPC title