Watch components

Patent metadata

Field	Value
Publication number	US-9920245-B2
Application number	US-201314438637-A
Country	US
Kind code	B2
Filing date	Nov 7, 2013
Priority date	Nov 7, 2012
Publication date	Mar 20, 2018
Grant date	Mar 20, 2018

Abstract

Watch component made of a persistent phosphorescent ceramic composite material which is a sintered dense body comprising two or more phases, a first phase consisting of at least one metal oxide and a second phase consisting of a metal oxide containing at least one activating element in a reduced oxidation state, the watch component having a surface which comprises an area which shows phosphorescent emission and an area which does not show phosphorescent emission or which shows phosphorescent emission with an intensity which is lower than that of the emission of the other area.

First claim

The invention claimed is:

1. A watch component made of a persistent phosphorescent ceramic composite material which is a sintered dense body comprising at least two phases, wherein the at least two phases comprise:
50 to 95% by weight of a first phase consisting of at least one metal oxide and
5 to 50% by weight of a second phase consisting of a metal oxide containing at least one activating element in a reduced oxidation state, the weight proportions of said first and second phases relative to the total weight of the two phases, wherein

the watch component has a surface which comprises
(i) a first area which shows phosphorescent emission and
(ii) a second area
(a) which does not show phosphorescent emission or
(b) which shows phosphorescent emission with an intensity which is lower than that of the emission of the first area.

2. The watch component according to claim 1 , wherein the metal oxide in the first phase of the persistent phosphorescent ceramic composite material is selected from the group consisting of aluminum oxide, zirconium oxide, magnesium oxide, silicon oxide, titanium oxide, barium oxide, beryllium oxide, calcium oxide and chromium oxide.

3. The watch component according to claim 1 , wherein the metal oxide in the first phase of the persistent phosphorescent ceramic composite material is zirconia stabilized with a dopant selected from the group consisting of Ce, Mg and Y.

4. The watch component according to claim 1 , wherein the metal oxide in the first phase of the persistent phosphorescent ceramic composite material is zirconia stabilized with yttria.

5. The watch component according to claim 1 , wherein the metal oxide in the second phase of the persistent phosphorescent ceramic composite material is selected from Ca, Ba, Sr and/or Mg-aluminates, Ca, Ba, Sr and/or Mg silicates, and Ca, and/or Sr aluminosilicates.

6. The watch component according to claim 2 , wherein the metal oxide in the second phase of the persistent phosphorescent ceramic composite material is selected from Ca, Ba, Sr and/or Mg-aluminates, Ca, Ba, Sr and/or Mg silicates, and Ca, and/or Sr aluminosilicates.

7. The watch component according to claim 5 , wherein the metal oxide in the second phase of the persistent phosphorescent ceramic composite material is a strontium aluminate.

8. The watch component according to claim 1 , wherein the amount of the first phase in the persistent phosphorescent ceramic composite material is 50 to 80% by weight and the amount of the second phase in the persistent phosphorescent ceramic composite material is 20 to 50% by weight, relative to the total weight of the two phases.

9. The watch component according to claim 2 , wherein the amount of the first phase in the persistent phosphorescent ceramic composite material is 50 to 80% by weight and the amount of the second phase in the persistent phosphorescent ceramic composite material is 20 to 50% by weight, relative to the total weight of the two phases.

10. The watch component according to claim 1 , wherein the area which is not phosphorescent is covered with a shielding layer.

11. The watch component according to claim 2 , wherein the area which is not phosphorescent is covered with a shielding layer.

12. The watch component according to claim 10 , wherein the shielding layer is made of a metallic material or of an oxide or nitride or carbide material or of a combination of the foregoing.

13. The watch component according to claim 12 , wherein the metallic material is selected from the group consisting of Au, Ag, Ni, Pt, Pd or alloys of these materials.

14. The watch component according to claim 11 , wherein the shielding layer is made of a metallic material or of an oxide or nitride or carbide material or of a combination of the foregoing.

15. The watch component according to claim 14 , wherein the metallic material is selected from the group consisting of Au, Ag, Ni, Pt, Pd or alloys of these materials.

16. A watch component made of a persistent phosphorescent ceramic composite material which is a sintered dense body comprising at least two phases, wherein the at least two phases comprise:
50 to 95% by weight of a first phase comprising at least one metal oxide selected from the group consisting of aluminum oxide, zirconium oxide, magnesium oxide, silicon oxide, titanium oxide, barium oxide, beryllium oxide, calcium oxide and chromium oxide and
5 to 50% by weight of a second phase comprising of a metal oxide containing at least one activating element in a reduced oxidation state, the metal oxides selected from Ca, Ba, Sr and/or Mg-aluminates, Ca, Ba, Sr and/or Mg silicates, and Ca, and/or Sr aluminosilicates;
the weight proportions of said first and second phases relative to the total weight of the two phases, wherein

the watch component has a surface which comprises
(i) a first area which shows phosphorescent emission and
(ii) a second area
(a) which does not show phosphorescent emission or
(b) which shows phosphorescent emission with an intensity which is lower than that of the emission of the first area.

17. The watch component of claim 16 , wherein the second area does not show phosphorescent emission, and wherein said second area is covered with a shielding layer, said shielding layer being made of a metallic material or of an oxide or nitride or carbide material or of a combination of the foregoing, wherein the wherein the metallic material is selected from the group consisting of Au, Ag, Ni, Pt, Pd or alloys thereof.

18. A watch component made of a persistent phosphorescent ceramic composite material which is a sintered dense body comprising at least two phases, wherein the at least two phases comprise:
50 to 95% by weight of a first phase comprising a zirconium oxide, and
5 to 50% by weight of a second phase comprising a strontium aluminate,
the weight proportions of said first and second phases relative to the total weight of the two phases, wherein

the watch component has a surface which comprises
(i) a first area which shows phosphorescent emission and
(ii) a second area
(a) which does not show phosphorescent emission or
(b) which shows phosphorescent emission with an intensity which is lower than that of the emission of the first area.

19. The watch component of claim 18 , wherein the strontium aluminate is selected from the group consisting of SrAl 2 O 4 , SrAl 4 O 7 , SrAl 12 O 19 and Sr 4 Al 14 O 25 .

20. The watch component of claim 19 , wherein the second area does not show phosphorescent emission, and wherein said second area is covered with a shielding layer, said shielding layer being made of a metallic material or of an oxide or nitride or carbide material or of a combination of the foregoing, wherein the wherein the metallic material is selected from the group consisting of Au, Ag, Ni, Pt, Pd or alloys thereof.

Assignees

• Rolex Sa

Inventors

• Berner Detlef
• Girod Romain
• Pujol Ollivier
• Rigot Isabelle

Classifications

• C09K11/025

  non-luminescent particle coatings or suspension media · CPC title

• C04B2235/76

  Crystal structural characteristics, e.g. symmetry · CPC title

• C04B35/481

  containing silicon, e.g. zircon · CPC title

• C04B2235/77

  Density · CPC title

• C04B2235/9646

  Optical properties · CPC title