Method of manufacturing optical fiber preform and optical fiber preform
US-2017101334-A1 · Apr 13, 2017 · US
US9910216B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9910216-B2 |
| Application number | US-201715645303-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 10, 2017 |
| Priority date | Jan 14, 2015 |
| Publication date | Mar 6, 2018 |
| Grant date | Mar 6, 2018 |
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One of embodiments relates to an optical fiber in which an alkali metal element is efficiently doped to its core to suppress transmission loss from increasing. A mean concentration or a concentration distribution of the alkali metal element is adjusted such that 0.48 or less is obtained as an weighted value obtained by weighting a distribution of field intensity of guided light at a wavelength of 1550 nm, with respect to a radial direction distribution of a ratio I D2 /I ω3 of an intensity I D2 of Raman scattering light by a silica three-membered ring structure and an intensity I ω3 of Raman scattering light by a Si—O stretching vibration, in a cross-sectional region having a diameter of 20 μm.
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The invention claimed is: 1. An optical fiber mainly comprised of silica-based glass, comprising: a core extending along an optical axis and including an alkali metal element; and a cladding surrounding the core and having a refractive index lower than that of the core, wherein, where an intensity of Raman scattering light ω 3 by a Si—O stretching vibration in a Raman scattering spectrum is I ω3 and an intensity of Raman scattering light D 2 by a silica three-membered ring structure is I D2 , a mean concentration of the alkali metal element in the core or a shape of a concentration distribution of the alkali metal element in the core is adjusted such that 0.48 or less is obtained as a weighted value of a distribution of a ratio I D2 /I ω3 along the radial direction of the optical fiber, the weighted value being obtained by weighting the distribution of the ratio I D2 /I ω3 with a distribution of field intensity along a radial direction of guided light at a wavelength of 1550 nm, calculated from a refractive index profile along the radial direction of the optical fiber, in a region including the optical axis as a center and having a diameter of 20 μm in a cross section of the optical fiber orthogonal to the optical axis. 2. The optical fiber according to claim 1 , wherein the alkali metal element includes potassium. 3. The optical fiber according to claim 1 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which a first concentration peak is located in an annular region surrounding the optical axis in a state in which the annular region is separated by a predetermined distance from the optical axis. 4. The optical fiber according to claim 3 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which a second concentration peak, having a maximum concentration lower than a maximum concentration of the first concentration peak, is located in a region surrounded by the annular region. 5. The optical fiber according to claim 1 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which there are a plurality of concentration peaks separated from each other along the radial direction of the optical fiber, and a maximum concentration of one concentration peak close to the optical axis in two adjacent concentration peaks included in the plurality of concentration peaks is lower than a maximum concentration of the other concentration peak in the two adjacent concentration peaks. 6. An optical fiber mainly comprised of silica-based glass, comprising: a core extending along an optical axis and including an alkali metal element; and a cladding surrounding the core and having a refractive index lower than that of the core, wherein, where an intensity of Raman scattering light ω 3 by a Si—O stretching vibration in a Raman scattering spectrum is I ω3 and an intensity of Raman scattering light D 2 by a silica three-membered ring structure is I D2 , a mean concentration of the alkali metal element in the core or a shape of a concentration distribution of the alkali metal element in the core is adjusted such that 0.50 or less is obtained as a ratio I D2 /I ω3 at a position where a field intensity of guided light at a wavelength of 1550 nm calculated from a refractive index profile along a radial direction of the optical fiber is maximized, in a cross section of the optical fiber orthogonal to the optical axis. 7. The optical fiber according to claim 6 , wherein the alkali metal element includes potassium. 8. The optical fiber according to claim 6 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which a first concentration peak is located in an annular region surrounding the optical axis in a state in which the annular region is separated by a predetermined distance from the optical axis. 9. The optical fiber according to claim 8 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which a second concentration peak, having a maximum concentration lower than a maximum concentration of the first concentration peak, is located in a region surrounded by the annular region. 10. The optical fiber according to claim 6 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which there are a plurality of concentration peaks separated from each other along the radial direction of the optical fiber, and a maximum concentration of one concentration peak close to the optical axis in two adjacent concentration peaks included in the plurality of concentration peaks is lower than a maximum concentration of the other concentration peak in the two adjacent concentration peaks. 11. An optical fiber mainly comprised of silica-based glass, comprising: a core extending along an optical axis and including an alkali metal element; and a cladding surrounding the core and having a refractive index lower than that of the core, wherein, where an intensity of Raman scattering light ω 3 by a Si—O stretching vibration in a Raman scattering spectrum is I ω3 and an intensity of Raman scattering light D 2 by a silica three-membered ring structure is I D2 , a mean concentration of the alkali metal element in the core or a shape of a concentration distribution of the alkali metal element in the core is adjusted such that 0.15 or less is obtained as a difference between a value of a ratio I D2 /I ω3 at a position where a field intensity of guided light at a wavelength of 1550 nm calculated from a refractive index profile along a radial direction of the optical fiber is maximized and a value of a ratio I D2 /I ω3 on the optical axis, in a cross section of the optical fiber orthogonal to the optical axis. 12. The optical fiber according to claim 11 , wherein the alkali metal element includes potassium. 13. The optical fiber according to claim 11 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which a first concentration peak is located in an annular region surrounding the optical axis in a state in which the annular region is separated by a predetermined distance from the optical axis. 14. The optical fiber according to claim 13 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which a second concentration peak, having a maximum concentration lower than a maximum concentration of the first concentration peak, is located in a region surrounded by the annular region. 15. The optical fiber according to claim 11 , wherein the concentration distribution of the alkali metal element, in the cross section of the optical fiber orthogonal to the optical axis, has a shape in which there are a plurality of concentration peaks separated from each other along the radial direction of the optical fiber, and a maximum concentration of one concentration peak close to the optical axis in two adjacent concentration peaks included in the plurality of concentration peaks is lower than a maximum concentration of t
containing alkali metals · CPC title
with more than 90% silica by weight, e.g. quartz {(C03C3/045 takes precedence)} · CPC title
by glass deposition on a glass substrate, e.g. by {inside-, modified-, plasma- or plasma modified-} chemical vapour deposition {[ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod} (C03B37/016 takes precedence; surface treatment of glass by coating with glass C03C17/02) · CPC title
Multiple layers differing in properties other than the refractive index, e.g. attenuation, diffusion, stress properties · CPC title
with glass (C03C17/34, C03C17/44 take precedence) · CPC title
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