Toner, image forming apparatus, and image forming method

Patent metadata

Field	Value
Publication number	US-9904195-B2
Application number	US-201715416055-A
Country	US
Kind code	B2
Filing date	Jan 26, 2017
Priority date	Jan 28, 2016
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

A toner comprising: a toner particle containing a binder resin and a colorant, and an inorganic fine particle A and B present on the surface of the toner particle, wherein the inorganic fine particle A is a silica fine particle having a number-average particle diameter (D 1 ) of primary particles in a specific range, the inorganic fine particle B has a number-average particle diameter (D 1 ) of primary particles in a specific range, and is at least one fine particle selected from a group consisting of a silica fine particle, a titanium oxide fine particle, and an alumina fine particle, A total fixing ratio of the inorganic fine particle A and B is 75% or more, and an inter-particle force Fp(A) and an inter-particle force Fp(B) are within specific numerical ranges and satisfy a specific relationship.

First claim

What is claimed is:

1. A toner comprising: a toner particle containing a binder resin and a colorant, and an inorganic fine particle A and an inorganic fine particle B present on a surface of the toner particle, wherein
the inorganic fine particle A is a silica fine particle having a number-average particle diameter (D 1 ) of primary particles of not less than 80 nm and not more than 200 nm;
the inorganic fine particle B has a number-average particle diameter (D 1 ) of primary particles of not less than 5 nm and not more than 25 nm, and is at least one fine particle which is selected from a group consisting of a silica fine particle, a titanium oxide fine particle, and an alumina fine particle;
when a fixing ratio of the inorganic fine particle A to the toner particle is represented by a fixing ratio A and a fixing ratio of the inorganic fine particle B to the toner particle is represented by a fixing ratio B,
a sum of the fixing ratio A and the fixing ratio B is 75% or more,
where an inter-particle force measured after a load of 78.5 N is applied to the toner is Fp(A) and an inter-particle force measured after a load of 157.0 N is applied to the toner is Fp(B),
the Fp(A) and the Fp(B) satisfy the following Formulas (1) and (2):
Fp ( A )≦30.0 nN, and   Formula (1):

( Fp ( B )− Fp ( A ))/ Fp ( A )≦0.90.   Formula (2):

2. The toner according to claim 1 , wherein the inorganic fine particle A has a half width of a maximum peak, in a particle size distribution of primary particles, of 25 nm or less.

3. The toner according to claim 1 , wherein a ratio of coverage of the surface of the toner particle with the inorganic fine particle B is from 45.0% to 90.0%.

4. The toner according to claim 1 , wherein
the colorant includes a magnetic body; and
a content of the magnetic body in the toner is from 20 mass % to 60 mass %.

5. The toner according to claim 1 , wherein an average circularity of the toner is 0.960 or more.

6. An image forming apparatus comprising:
an electrostatic latent image bearing member;
a contact type charging roller that electrically charges the electrostatic latent image bearing member;
image exposure means for forming an electrostatic latent image on a surface of the electrically charged electrostatic latent image bearing member;
development means for developing the electrostatic latent image with a toner and forming a toner image;
transfer means for transferring the toner image onto a transfer material via an intermediate transfer body or without the intermediate transfer body; and
fixing means for fixing the toner image, which has been transferred onto the transfer material, to the transfer material,
the image forming apparatus including no cleaning means for removing residual toner in a region downstream of the transfer means and upstream of the contact type charging roller, and the residual toner being recovered by the development means, wherein
the toner is the toner according to claim 1 .

7. An image forming method comprising:
a charging step of charging a surface of an electrostatic latent image bearing member by using a contact type charging roller;
an electrostatic latent image forming step of exposing the electrically charged surface of the electrostatic latent image bearing member and forming an electrostatic latent image;
a development step of developing the electrostatic latent image with a toner and forming a toner image;
a transfer step of transferring the toner image onto a transfer material via an intermediate transfer body or without the intermediate transfer body; and
a fixing step of fixing the toner image, which has been transferred onto the transfer material, to the transfer material,
the image forming method including no cleaning step of removing residual toner between the transfer step and the charging step, and the residual toner being recovered by development means, wherein
the toner comprising: a toner particle containing a binder resin and a colorant, and an inorganic fine particle A and an inorganic fine particle B present on a surface of the toner particle, wherein
the inorganic fine particle A is a silica fine particle having a number-average particle diameter (D 1 ) of primary particles of not less than 80 nm and not more than 200 nm;
the inorganic fine particle B has a number-average particle diameter (D 1 ) of primary particles of not less than 5 nm and not more than 25 nm, and is at least one fine particle which is selected from a group consisting of a silica fine particle, a titanium oxide fine particle, and an alumina fine particle;
when a fixing ratio of the inorganic fine particle A to the toner particle is represented by a fixing ratio A and a fixing ratio of the inorganic fine particle B to the toner particle is represented by a fixing ratio B,
a sum of the fixing ratio A and the fixing ratio B is 75% or more,
where an inter-particle force measured after a load of 78.5 N is applied to the toner is Fp(A) and an inter-particle force measured after a load of 157.0 N is applied to the toner is Fp(B),
the Fp(A) and the Fp(B) satisfy the following Formulas (1) and (2):
Fp ( A )≦30.0 nN, and   Formula (1):

( Fp ( B )− Fp ( A ))/ Fp ( A )≦0.90.   Formula (2):

Assignees

• Canon Kk

Inventors

• Matsui Takashi
• Okamoto Naoki
• Arimura Satoshi
• Tanaka Keisuke
• Tsuda Shohei

Classifications

• G03G15/08 Primary

  using a solid developer, e.g. powder developer · CPC title

• G03G9/083

  Magnetic toner particles · CPC title

• G03G9/087

  Binders for toner particles · CPC title

• G03G9/09 Primary

  Colouring agents for toner particles · CPC title

• G03G9/09725

  Silicon-oxides; Silicates · CPC title