Nanowire and microwire fabrication technique and product

Patent metadata

Field	Value
Publication number	US-9903033-B2
Application number	US-201313948652-A
Country	US
Kind code	B2
Filing date	Jul 23, 2013
Priority date	Jul 24, 2012
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

A continuous or semi-continuous process for fabricating nanowires or microwires makes use of the substantially planar template that may be moved through electrochemical solution to grow nanowires or microwires on exposed conductive edges on the surface of that template. The planar template allows fabrication of the template using standard equipment and techniques. Adhesive transfer may be used to remove the wires from the template and in one embodiment to draw a continuous wire from the template to be wound around the drum.

First claim

What is claimed is:

1. An apparatus for fabricating wire comprising:
a chamber configured to retain a volume of an electrochemical solution;
a substantially planar template providing a surface and a conductive layer with an electrically conductive ultranano crystalline diamond edge in nano or micro scale dimensions formed in a predefined pattern, the template mounted for rotation about a first axis perpendicular to the surface;
wherein a portion of the template is configured to be selectively immersed in the electrochemical solution in the chamber, the template configured to interact with, the template configured to interact with the electrochemical solution to form a wire;
a transfer element comprising a chamfered edge parallel to the surface, the chamfered edge having an adhesive surface and mounted for movement with respect to the template and contact with the template, the transfer element configured to remove from the template at least a portion of the wire grown by electrochemical action on the structure of the template; and
an electrical power source having one electrode within the chamber connectable to an electrochemical solution in the chamber and a second electrode connecting to the electrically conductive edge of the structure.

2. The apparatus of claim 1 wherein the transfer element is a disk rotating about a second axis angled with respect to the first axis, the disk having the chamfered edge contacting the surface of the template and following an annular track on the surface of the template concentric about the first axis on the template with mutual rotation of the transfer element and template.

3. The apparatus of claim 2 wherein the chamfered edge of the disk of the transfer element is non-perpendicular with respect to the second axis.

4. The apparatus of claim 2 further including a drum rotating about a third axis and providing an adhesive surface and mounted for movement with respect to transfer element and contact between the drum adhesive surface and the chamfered edge to pull wires off of the transfer element with rotating contact between the drum and transfer element.

5. The apparatus of claim 4 wherein the drum further translates along the third axis with respect to the transfer element and with rotation of the drum to spool a wire received from the transfer element in a helical coil along a surface of the drum.

6. The apparatus of claim 5 wherein the predefined pattern defines at least one substantially continuous circle on the planar template centered about the axis.

7. The apparatus of claim 1 including a second chamber for holding a releasing liquid and positioned to admit a portion of the transfer element to move through the releasing liquid with rotation of the transfer element about the second axis.

8. The apparatus of claim 7 wherein the second chamber includes an agitation element for agitating the releasing liquid.

9. The apparatus of claim 1 wherein the chamber is open upward to admit a portion of the template during rotation of the template with the surface of the template extending vertically.

10. The apparatus of claim 1 wherein the predefined pattern of the electrically conductive edge defines multiple discontinuous elements positioned over the surface of the template.

11. The apparatus of claim 1 wherein the transfer element is a flexible tape having an adhesive surface and pressed against a surface of the template by a guide to follow an annular track on the surface of the template with rotation of the template.

12. The apparatus of claim 1 further including an electronic computer executing a stored program controlling operation of the apparatus selected from the group consisting of:
(a) a rate of rotation of the template through the electrochemical solution;
(b) an applied voltage across the electrodes; and
(c) the composition of the electrochemical solution.

13. An apparatus for fabricating wire comprising:
a template having a surface defining a plane and further having an electrically conductive ultranano crystalline layer and an insulating layer, the ultranano crystalline layer disposed between the surface and the insulating layer and having an exposed conductive ultranano crystalline diamond edge, the template mounted for rotation about a first axis perpendicular to the plane;
a chamber configured to retain a volume of an electrochemical solution, the template at least partially immersible in the chamber, the template configured to interact with the electrochemical solution to form a wire on the exposed conductive ultranano crystalline diamond edge;
a transfer element comprising a chamfered edge parallel to the plane, the chamfered edge providing an adhesive surface and mounted for movement with respect to the template, the transfer element configured to remove from the template at least a portion of the wire grown by electrochemical action on the structure of the template; and
an electrical power source having one electrode within the chamber connectable to an electrochemical solution in the chamber and a second electrode connecting to the conductive ultranano crystalline diamond edge.

14. The apparatus of claim 13 , wherein the ultranano crystalline diamond edge is broken into discrete portions by one or more insulated portions.

15. The apparatus of claim 14 , wherein the one or more insulating portions comprise a second conductive layer having an exposed second conductive layer edge perpendicular to the plane defined by the surface and a third electrode connecting to the second conductive layer edge such that the wire includes gaps.

16. The apparatus of claim 15 , wherein the one or more insulating portions comprise a third conductive layer having an exposed third conductive layer edge perpendicular to the plane defined by the surface and a fourth electrode connecting to the conductive second conductive layer edge.

17. The apparatus of claim 13 , wherein electrochemical solution is an ionic liquid.

18. The apparatus of claim 15 , wherein the second conductive layer edge is configured to interact with a second electrochemical solution to form a first junction.

19. The apparatus of claim 15 , wherein the third conductive layer edge is configured to interact with a third electrochemical solution to form a second junction.

20. The apparatus of claim 15 , wherein the first junction and second junction comprise a material selected from CdS, CdSe, CdTe, Al, CuO, ZnS, and ZnSe and the first junction and second junction fill in the gaps in the wire.

21. The apparatus of claim 13 , wherein the exposed conductive ultranano crystalline diamond edge is perpendicular to the plane defined by the surface.

22. The apparatus of claim 13 , wherein the exposed conductive ultranano crystalline diamond edge is non-parallel to the plane defined by the surface.

23. The apparatus of claim 13 further comprising an agitation element for agitating a releasing liquid, the agitation element selected from the group consisting of an ultrasonic transducer and an air knife.

Assignees

• Uchicago Argonne Llc
• Uchicago Argonne Llc

Inventors

• Sumant Anirudha V
• Zach Michael
• Marten Alan David

Classifications

• C25D1/04 Primary

  Wires; Strips; Foils · CPC title

• C25D1/006

  Nanostructures, e.g. using aluminium anodic oxidation templates [AAO] · CPC title

• C25D1/10 Primary

  Moulds; Masks; Masterforms · CPC title

• C25D1/00

  Electroforming · CPC title