Liquid phase oxidation of aromatic feedstocks with manganate recycling to produce carboxylic acids

Patent metadata

Field	Value
Publication number	US-9902677-B2
Application number	US-201615184398-A
Country	US
Kind code	B2
Filing date	Jun 16, 2016
Priority date	Dec 12, 2013
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

Systems and methods for liquid-phase oxidation of an aromatic feedstock containing at least one oxidizable aromatic compound may incorporate an oxidation reactor, a separation apparatus in fluidic communication with the oxidation reactor, a solids treatment unit, and a product recovery unit in fluidic communication with the separation apparatus. The oxidation reactor may conduct liquid-phase oxidation of the oxidizable aromatic compound in the aromatic feedstock in the presence of a manganate salt to form a slurry containing liquid product and solid manganese dioxide. The separation apparatus may accept the slurry from the oxidation reactor and separate the liquid component from the solid component. The solids treatment unit accepts the solid component from the separation apparatus, treats the solid component with a basic liquid to oxidize the manganese dioxide in the solid component and form a regenerated manganate salt, which may be recycled back to the oxidation reactor.

First claim

What is claimed is:

1. A system for liquid-phase oxidation of an aromatic feedstock containing at least one oxidizable aromatic compound, the system comprising:
an oxidation reactor;
a separation apparatus in fluidic communication with the oxidation reactor;
a solids treatment unit in fluidic communication with the separation apparatus and the oxidation reactor; and
an alkali stream in fluidic communication with the solids treatment unit; and
a product recovery unit in fluidic communication with the separation apparatus,

wherein:
the oxidation reactor is adapted to conduct liquid-phase oxidation of the at least one oxidizable aromatic compound in the aromatic feedstock to a carboxylate in the presence of a manganate salt in an alkaline medium to form a slurry comprising a liquid component containing the carboxylate and a solid component containing manganese dioxide;
the separation apparatus accepts the slurry from the oxidation reactor and separates the liquid component from the solid component;
the product recovery unit accepts the liquid component from the separation apparatus;
the solids treatment unit accepts the solid component from the separation apparatus, treats the solid component with a basic liquid from the alkali stream to oxidize the manganese dioxide in the solid component and form a regenerated manganate salt, and sends at least a portion of the regenerated manganate salt back to the oxidation reactor.

2. The system of claim 1 , further comprising a supplemental manganate source in fluidic communication with the solids treatment unit and the oxidation reactor, the supplemental manganate source providing supplemental manganate salt to the portion of the regenerated manganate salt being sent back to the oxidation reactor.

3. The system of claim 1 , further comprising a supplemental manganese dioxide source in fluidic communication with the solids treatment unit, the supplemental manganese dioxide source providing supplemental manganese dioxide to the manganese dioxide being oxidized to increase an amount of manganate salt to be sent back to the oxidation reactor.

4. The system of claim 1 , wherein the separation apparatus is a filtration apparatus.

5. The system of claim 1 , wherein the product recovery unit is in fluidic communication with an acid stream that is combined with the carboxylate to form a carboxylic acid from the carboxylate.

6. The system of claim 1 , wherein the at least one oxidizable aromatic compound is chosen from monomethylbenzenes, dimethylbenzenes, trimethylbenzenes, monomethylnaphthalenes, and dimethylnaphthalenes.

7. The system of claim 1 , wherein the at least one oxidizable aromatic compound is chosen from chosen from p-xylene, m-xylene, o-xylene, and combinations thereof.

8. The system of claim 1 , wherein the at least one oxidizable aromatic compound comprises p-xylen and the carboxylate comprises a benzene-1,4-dicarboxylate.

Assignees

• Saudi Arabian Oil Co

Inventors

• Tammana Veera Venkata Ramakrishna
• Shaik Kareemuddin M
• Raynel Guillaume Robert Jean Francois

Classifications

• B01J2219/00759

  Purification of compounds synthesised · CPC title

• C07C63/06

  Benzoic acid · CPC title

• C07C51/285

  with peroxy-compounds · CPC title

• B01J2219/00599

  Solution-phase processes · CPC title

• C07C51/295 Primary

  with inorganic bases, e.g. by alkali fusion · CPC title