Preparation method for composite ferrate reagent

Patent metadata

Field	Value
Publication number	US-9902624-B2
Application number	US-201415111995-A
Country	US
Kind code	B2
Filing date	Apr 30, 2014
Priority date	Jan 15, 2014
Publication date	Feb 27, 2018
Grant date	Feb 27, 2018

Abstract

A preparation method for a composite ferrate reagent. 1, Weigh raw materials; 2, evenly mix a ferric salt, an activating agent and an alkali maintaining agent and heat the mixture; 3, add an oxidant solution; and 4, cool and mix the solution with water. The technical problems of high energy consumption, low yield and poor ferrate product stability of the existing method for preparing ferrate are solved. The obtained product can be stably stored, and the yield of the ferrate reaches 60% to 95%.

First claim

What is claimed is:

1. A preparation method for ferrate composite agent, characterized in that, the preparation method for ferrate composite agent comprises the steps, in order, of:
(1) weighing iron salt, activate agent, alkalinizing agent and oxidizing agent solution obtain a molar ratio of iron salt and activate agent of 1:0.001˜10, a molar ratio of iron salt and alkalinizing agent of 1:2˜20, a molar ratio of iron salt and oxidizing agent in the oxidizing agent solution of 1:0.1˜10;
(2) mixing said iron salt, said activate agent and said alkalinizing agent obtained from the step (1) uniformly, heating said iron salt, said activate agent and said alkalinizing agent after mixing to a heating temperature of 150° C.˜390° C. and maintaining said iron salt, said activate agent and said alkalinizing agent after heating for a heating period of 5 min˜20 min, and obtaining a mixture;
(3) adding said oxidizing agent solution from the step (1) to said mixture in the step (2), wherein an adding time is controlled below 10 minutes, then obtaining a precursor; and
(4) cooling said precursor obtained from the step (3) naturally, then mixing said precursor with water according to a volume ratio of said precursor and said water of 1:1˜5, stirring uniformly and obtaining the ferrate composite agent;
wherein in the step (1), said activate agent is one or a combination of two or more selected from the group consisting of: potassium permanganate, potassium dichromate, potassium chlorate, persulfate and monopersulfate; and said oxidizing agent is one or a combination of two or more selected from the group consisting of: potassium permanganate, potassium dichromate, hydrogen peroxide, ozone, sodium hypochlorite, potassium hypochlorite, potassium chlorate, perchlorate, persulfate and monopersulfate, wherein a concentration of said oxidizing agent solution is 0.1 mol/L˜3 mol/L.

2. The preparation method for ferrate composite agent according to claim 1 , characterized in that, in the step (1), said iron salt is one or a combination of two or more selected from the group consisting of: ferric chloride, ferrous chloride, ferric nitrate, ferrous nitrate, ferric sulfate and ferrous sulfate.

3. The preparation method for ferrate composite agent according to claim 1 , characterized in that, in the step (1), said alkalinizing agent is one or a combination of two or more selected from the group consisting of: sodium hydroxide, sodium carbonate, sodium bicarbonate, potassium hydroxide, potassium bicarbonate and potassium carbonate.

4. The preparation method for ferrate composite agent according to claim 1 , characterized in that, said concentration of said oxidizing agent solution is 1.5 mol/L.

5. A preparation method for ferrate composite agent, consisting the steps, in order, of:
(1) weighing iron salt, activate agent, alkalinizing agent and oxidizing agent solution obtain a molar ratio of iron salt and activate agent of 1:0.001˜10, a molar ratio of iron salt and alkalinizing agent of 1:2˜20, a molar ratio of iron salt and oxidizing agent in the oxidizing agent solution of 1:0.1˜10, wherein said activate agent is one or a combination of two or more selected from the group consisting of: potassium permanganate, potassium dichromate, potassium chlorate, persulfate and monopersulfate, wherein said oxidizing agent is one or a combination of two or more selected from the group consisting of: potassium permanganate, potassium dichromate, hydrogen peroxide, ozone, sodium hypochlorite, potassium hypochlorite, potassium chlorate, perchlorate, persulfate and monopersulfate, wherein a concentration of said oxidizing agent solution is 0.1 mol/L˜3 mol/L;
(2) mixing said iron salt, said activate agent and said alkalinizing agent obtained from the step (1) uniformly, heating said iron salt, said activate agent and said alkalinizing agent after mixing to a heating temperature of 150° C.˜390° C. and maintaining said iron salt, said activate agent and said alkalinizing agent after heating for a heating period of 5 min˜20 min, and obtaining a mixture;
(3) adding said oxidizing agent solution from the step (1) to said mixture in the step (2), wherein an adding time is controlled below 10 minutes, then obtaining a precursor; and
(4) cooling said precursor obtained from the step (3) naturally, then mixing said precursor with water according to a volume ratio of said precursor and said water of 1:1˜5, stirring uniformly and obtaining the ferrate composite agent.

6. The preparation method for ferrate composite agent according to claim 5 , wherein in the step (1), said iron salt is a divalent iron compound.

7. The preparation method for ferrate composite agent according to claim 5 , wherein in the step (1), said iron salt is a trivalent iron compound.

8. The preparation method for ferrate composite agent according to claim 5 , wherein in the step (1), said iron salt is one or a combination of the group consisting of a divalent iron compound or a trivalent iron compound.

9. The preparation method for ferrate composite agent according to claim 5 , wherein in the step (1), said iron salt is one or a combination of two or more selected from the group consisting of: ferric chloride, ferrous chloride, ferric nitrate, ferrous nitrate, ferric sulfate and ferrous sulfate.

10. The preparation method for ferrate composite agent according to claim 5 , wherein in the step (1), said iron salt is one or a combination of two or more selected from the group consisting of: ferrous chloride, ferrous nitrate, and ferrous sulfate.

11. The preparation method for ferrate composite agent according to claim 5 , wherein in the step (1), said alkalinizing agent is one or a combination of two or more selected from the group consisting of: sodium hydroxide, sodium carbonate, sodium bicarbonate, potassium hydroxide, potassium bicarbonate and potassium carbonate.

12. The preparation method for ferrate composite agent according to claim 9 , wherein in the step (1), said alkalinizing agent is one or a combination of two or more selected from the group consisting of: sodium hydroxide, sodium carbonate, sodium bicarbonate, potassium hydroxide, potassium bicarbonate and potassium carbonate.

13. The preparation method for ferrate composite agent according to claim 5 , wherein said concentration of said oxidizing agent solution is 1.5 mol/L.

14. The preparation method for ferrate composite agent according to claim 12 , wherein said concentration of said oxidizing agent solution is 1.5 mol/L.

Assignees

• Harbin Inst Technology

Inventors

• Ma Jun
• Liu Yulei
• Wang Lu
• Zhao Xiaodan
• Liu Qingliang

Classifications

• C01G49/0081 Primary

  containing iron in unusual valence state [IV, V, VI] · CPC title