Process for producing olefin polymer and olefin polymer
US-2016376385-A1 · Dec 29, 2016 · US
US9896526B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9896526-B2 |
| Application number | US-201615195426-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 28, 2016 |
| Priority date | Sep 25, 2012 |
| Publication date | Feb 20, 2018 |
| Grant date | Feb 20, 2018 |
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[Problem to be solved] There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity. [Solution to problem] The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and α-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and α-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, [in the formula [I], R 1 , R 3 and R 5 to R 16 are each independently a hydrogen atom, a hydrocarbon group or the like; R 2 is a hydrocarbon group or the like; R 4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].
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The invention claimed is: 1. A 4-methyl-1-pentene polymer fulfilling the following requirements (d) to (f): (d) the amount of constituent units derived from 4-methyl-1-pentene is more than 50 mol % and less than 80 mol %, and the amount of constituent units derived from at least one selected from olefins having 2 to 30 carbon atoms (except 4-methyl-1-pentene) is more than 20 mol % and less than 50 mol %; (e) the meso diad fraction (m) as measured by 13 C-NMR is 98.5% to 100%; and (f) the melting point Tm as measured by Differential Scanning Calorimetry (DSC) is lower than 100° C. or is substantially absent.
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