Process for producing olefin polymer and olefin polymer

Patent metadata

Field	Value
Publication number	US-9458257-B2
Application number	US-201314429917-A
Country	US
Kind code	B2
Filing date	Sep 24, 2013
Priority date	Sep 25, 2012
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

There is provided a process for producing an olefin polymer that is capable of producing an olefin polymer having high heat resistance and high molecular weight with excellent catalytic activity.
The process for producing an olefin polymer includes a step of polymerizing at least one olefin selected from ethylene and α-olefins having 4 to 30 carbon atoms in the presence of an olefin polymerization catalyst containing a transition metal compound represented by the general formula [I], the olefin polymer including constituent units derived from ethylene and α-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %,

[in the formula [I], R 1 , R 3 and R 5 to R 16 are each independently a hydrogen atom, a hydrocarbon group or the like; R 2 is a hydrocarbon group or the like; R 4 is a hydrogen atom; M is a transition metal of Group IV; Q is a halogen atom or the like; and j is an integer of 1 to 4].

First claim

The invention claimed is:

1. A process for producing an olefin polymer comprising a step of polymerizing at least one olefin selected from ethylene and α-olefins having 4 to 30 carbon atoms, and optional propylene, in the presence of an olefin polymerization catalyst comprising at least one transition metal compound (A) selected from transition metal compounds represented by the general formula [I] and enantiomers thereof,
the olefin polymer including constituent units derived from the at least one selected from ethylene and α-olefins having 4 to 30 carbon atoms in a total amount between more than 50 mol % and not more than 100 mol %, and constituent units derived from propylene in an amount between 0 mol % and less than 50 mol %, wherein the content of the constituent units derived from ethylene and α-olefins having 4 to 30 carbon atoms and the content of the constituent units derived from propylene total 100 mol %,

wherein in the formula [I], R 1 , R 3 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 are each independently a hydrogen atom, a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R 2 is a hydrocarbon group, a hetero atom-containing hydrocarbon group, or a silicon-containing group; R 4 is a hydrogen atom; R 5 is an alkyl group having 2 or more carbon atoms, a cycloalkyl group or a cycloalkenyl group, or R 5 and R 7 are bonded to each other to form a ring; any two substituents of the substituents R 1 to R 16 except R 4 are optionally bonded to each other to form a ring; M is a transition metal of Group IV; Q is a halogen atom, a hydrocarbon group, an anionic ligand, or a neutral ligand coordinatable with a lone electron pair; j is an integer of 1 to 4; and when j is an integer of 2 or greater, Qs are the same or different from one another.

2. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 1 and R 3 are hydrogen atoms.

3. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 2 is a hydrocarbon group having 1 to 20 carbon atoms.

4. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 2 is a substituent in which a carbon bonded to the cyclopentadienyl ring is a tertiary carbon.

5. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 9 , R 12 , R 13 and R 16 are hydrogen atoms.

6. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 10 , R 11 , R 14 and R 15 are hydrocarbon groups, or R 10 and R 11 are bonded to each other to form a ring and R 14 and R 15 are bonded to each other to form a ring.

7. The process for producing an olefin polymer according to claim 1 , wherein the olefin polymerization catalyst further comprises at least one compound (B) selected from:
(B-1) organometallic compounds,
(B-2) organoaluminum-oxy compounds, and
(B-3) compounds that react with the transition metal compound (A) to form an ion pair.

8. The process for producing an olefin polymer according to claim 1 , wherein the olefin polymerization catalyst further comprises a carrier (C), and the transition metal compound (A) that is supported on the carrier (C) is used.

9. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], the MQ j moiety is in front of the plane of the paper, and the bridge is behind the plane of the paper.

10. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 5 is an alkyl group having 3 or more carbon atoms, the cycloalkyl group or the cycloalkenyl group.

11. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 5 is an alkyl group having 4 or more carbon atoms, the cycloalkyl group or the cycloalkenyl group.

12. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 5 is the cycloalkyl group.

13. The process for producing an olefin polymer according to claim 1 , wherein in the general formula [I], R 5 is the cycloalkenyl group.

Assignees

• Mitsui Chemicals Inc

Inventors

• Funaya Munehito
• Sakuma Atsushi
• Ebisawa Ikuko
• Kinoshita Shinsuke
• Matsumoto Akiko
• Tanaka Hirokazu
• Tanaka Shinya

Classifications

• C08F10/08

  Butenes · CPC title

• C08F4/65916

  supported on a carrier, e.g. silica, MgCl2, polymer · CPC title

• C08F236/08

  Isoprene · CPC title

• C08F10/00 Primary

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title