Reformate hydrotreatment method

Patent metadata

Field	Value
Publication number	US-9879186-B2
Application number	US-201314430456-A
Country	US
Kind code	B2
Filing date	Sep 18, 2013
Priority date	Sep 21, 2012
Publication date	Jan 30, 2018
Grant date	Jan 30, 2018

Abstract

Provided is a reformate hydrotreatment method, the method comprising: under liquid phase hydrotreatment conditions, bringing the reformate and a catalyst having a catalytic hydrogenation effect into contact in a hydrogenation reactor, the hydrogen used in the hydrotreating process at least partially coming from the hydrogen dissolved in the reformate. According to the method of the present invention, the reformate separated from a reformate products separating tank can directly undergo liquid phase hydrotreatment; therefore not only can the hydrogen dissolved in the reformate be fully utilized, but the olefins in the reformate can also be removed, while eliminate the requirements for recycle hydrogen and a recycle device thereof. The reformate obtained by the method of the present invention reduces the bromine index to below 50 mgBr 2 /100 g, and has an arene loss of less than 0.5 wt %.

First claim

The invention claimed is:

1. A method for hydroprocessing reformate, comprising:
contacting a hydrocarbon oil with a catalyst having a catalytic reforming function to obtain a catalytic reforming mixture;
separating the catalyst reforming mixture in a gas-liquid separator to obtain a reformate, wherein the reformate is a liquid with hydrogen dissolved therein;
injecting a supplemental hydrogen into the reformate through a plurality of pores having an average pore diameter of 1 nm to 1,000 nm in a mixing device to obtain an hydrogen enriched reformate;
introducing the hydrogen enriched reformate that exits from an outlet of the mixing device into an inlet of a hydrogenation reactor containing a catalyst having a catalytic hydrogenation function; and
withdrawing a hydrogenated reformate from an outlet of the hydrogenation reactor.

2. The method according to claim 1 , wherein the supplemental hydrogen gas is injected into the reformate in one or more locations.

3. The method according to claim 1 , wherein the reformate comprises 0.001-0.025 wt % of the dissolved hydrogen based on a total weight of the reformate.

4. The method according to claim 1 , wherein the mixing device comprises at least one liquid passage for accommodating the reformate and at least one gas passage for accommodating the supplemental hydrogen gas, and a porous nozzle having the plurality of pores, the supplemental hydrogen gas is injected into the reformate through the plurality of pores in the nozzle.

5. The method according to claim 3 , wherein the average pore diameter is in a range of 30 nm to 1,000 nm.

6. The method according to claim 2 , wherein an amount of the supplemental hydrogen gas injected is 0.01 to 4 times of a saturated solubility of hydrogen in the reformate, the saturated solubility is measured at a temperature and under a pressure in the hydrogenation reactor.

7. The process according to claim 6 , wherein the amount of the supplemental hydrogen gas is 0.1 times to less than 1 time of the saturated solubility.

8. The method according to claim 1 , further comprising removing light constituents in the hydrogenated reformate to obtain a light constituent-removed oil, and exchanging heat between the reformate and the light constituent-removed oil prior to feeding the reformate into the hydrogenation reactor.

9. The method according to claim 1 , wherein the hydrogenation reactor is a tubular fixed-bed hydrogenation reactor.

10. The method according to claim 9 , wherein the reformate has a volume space velocity in a range of 5 h −1 to 20 h −1 .

11. The method according to claim 1 , further comprising injecting the supplemental hydrogen into the hydrogen enriched reformate during the step of contacting the hydrogen enriched reformate with the catalyst having the catalytic hydrogenation function.

12. The method according to claim 1 , wherein a temperature in the hydrogenation reactor is in a range of 130° C. to 200° C. and a pressure by gage pressure in the hydrogenation reactor is in a range of 1.5 MPa to 3.5 MPa.

13. The method according to claim 1 , wherein contacting the reformate with the catalyst having the catalytic hydrogenation function is carried out without the presence of diluent and/or circulating oil.

Assignees

• China Petroleum & Chem Corp
• Hunan Changling Petrochemical Science And Tech Development Co Ltd

Inventors

• Li Hua
• Liu Jianping
• She Xichun
• He Xiaojun
• Li Qinghua
• Chen Qingling
• Jiang Lei
• Zeng Zhiyu
• Yang Qingpin
• Liu Chengli

Classifications

• B01J8/065

  Feeding reactive fluids · CPC title

• C10G49/007

  in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment · CPC title

• B01J2208/00176

  outside the reactor · CPC title

• C10G59/02

  plural serial stages only · CPC title

• C10G65/08

  at least one step being a hydrogenation of the aromatic hydrocarbons · CPC title