Catalyst material extraction from polycrystalline diamond tables

Patent metadata

Field	Value
Publication number	US-9878957-B2
Application number	US-201515107004-A
Country	US
Kind code	B2
Filing date	Jun 30, 2015
Priority date	Jun 30, 2015
Publication date	Jan 30, 2018
Grant date	Jan 30, 2018

Abstract

Catalyst extraction from polycrystalline diamond table may be achieved by treating with a halogen (in the gas phase or dissolved in a nonpolar organic solvent) to convert the catalyzing material to a salt. Then, polar organic solvents may optionally be used to leach the salt from the polycrystalline diamond table. The polycrystalline diamond (with the salt of the catalyzing material present or at least partially leached therefrom) may be brazed to a hard composite substrate to produce a cutter suitable for use in a matrix drill bit.

First claim

What is claimed is:

1. A method comprising:
exposing a catalyzing material disposed in interstitial spaces of a polycrystalline diamond table to a halogen gas to produce a catalyst salt in the interstitial spaces of the polycrystalline diamond table, wherein exposing is at a temperature and a pressure sufficient to react the catalyzing material and the halogen gas but insufficient to cause the catalyst salt to incorporate into a gas phase.

2. The method of claim 1 further comprising:
brazing the polycrystalline diamond table having the catalyst salt therein to a hard composite substrate.

3. The method of claim 1 further comprising:
treating the polycrystalline diamond table having the catalyst salt therein with a polar organic solvent, thereby removing at least some of the catalyst salt from the interstitial spaces of a polycrystalline diamond table.

4. The method of claim 3 further comprising:
brazing the polycrystalline diamond table having at least some of the catalyst salt removed to a hard composite substrate.

5. The method of claim 1 , wherein the halogen gas is bromine, the catalyzing material is cobalt, the temperature is 20° C. to 100° C., and the pressure is 0.1 MPa to 4 MPa.

6. The method of claim 1 , wherein the temperature is 0° C. to 300° C.

7. The method of claim 1 , wherein the pressure is ambient pressure to 4 MPa.

8. The method of claim 1 , wherein the catalyst salt comprises at least one of: cobalt fluoride, cobalt chloride, cobalt bromide, cobalt iodide, nickel fluoride, nickel chloride, nickel bromide, nickel iodide, iron fluoride, iron chloride, iron bromide, or iron iodide.

9. The method of claim 1 further comprising: diluting the halogen gas in an inert gas.

10. The method of claim 9 , the halogen gas is present at 10% to 99% of a total gas phase by mole.

11. A method comprising:
exposing a catalyzing material disposed in interstitial spaces of a polycrystalline diamond table to a halogen dissolved in a nonpolar organic solvent to produce a catalyst salt in the interstitial spaces of the polycrystalline diamond table, wherein the catalyst salt has a solubility of less than 0.1 g/100 mL in the nonpolar organic solvent.

12. The method of claim 11 further comprising:
brazing the polycrystalline diamond table having the catalyst salt therein to a hard composite substrate.

13. The method of claim 11 further comprising:
treating the polycrystalline diamond table having the catalyst salt therein with a polar organic solvent, thereby removing at least some of the catalyst salt from the interstitial spaces of the polycrystalline diamond table.

14. The method of claim 13 further comprising:
brazing the polycrystalline diamond table having at least some of the catalyst salt removed to a hard composite substrate.

15. The method of claim 11 , wherein exposing the catalyzing material to the halogen dissolved in the nonpolar organic solvent is at a temperature of 0° C. to 300° C.

16. The method of claim 11 , wherein exposing the catalyzing material to the halogen dissolved in the nonpolar organic solvent is at a pressure of ambient pressure to 4 MPa.

17. The method of claim 11 , wherein the catalyst salt comprises at least one of: cobalt fluoride, cobalt chloride, cobalt bromide, cobalt iodide, nickel fluoride, nickel chloride, nickel bromide, nickel iodide, iron fluoride, iron chloride, iron bromide, or iron iodide.

Assignees

• Halliburton Energy Services Inc

Inventors

• Reyes Enrique Antonio
• Pinder Tiffany Anne
• Liang Qi
• Saini Gagan
• Atkins Brian

Classifications

• B23K2103/50

  Inorganic materials other than metals or composite materials · CPC title

• B23K2101/002

  Drill-bits · CPC title

• C04B2235/427

  Diamond · CPC title

• C22C26/00

  Alloys containing diamond {or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes} · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title