Procatalyst for polymerization of olefins

Patent metadata

Field	Value
Publication number	US-9868799-B2
Application number	US-201415104808-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 20, 2013
Publication date	Jan 16, 2018
Grant date	Jan 16, 2018

Abstract

The invention relates to a procatalyst for polymerization of olefins. The invention also relates to a process for preparing said procatalyst. Furthermore, the invention is directed to a catalyst system for polymerization of olefins comprising the said procatalyst, a co-catalyst and optionally an external electron donor; a process of preparing polyolefins by contacting an olefin with said catalyst system and to polyolefins obtained or obtainable by said process. The invention also relates to the use of said procatalyst in the polymerization of olefins.

First claim

The invention claimed is:

1. A process for preparing a procatalyst for preparing a catalyst composition for olefin polymerization, said process comprising:
i) contacting a compound R 4 z MgX 4 2-z with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product, being a solid Mg(OR 1 ) x X 1 2-x , wherein: R 4 is the same as R 1 being a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group may be substituted or unsubstituted, may contain one or more heteroatoms; X 4 and X 1 are each independently selected from the group consisting of fluoride (F − ), chloride (Cl − ), bromide (Br − ) or iodide (I − ); z is in a range of larger than 0 and smaller than 2, being 0<z<2; x is in a range of larger than 0 and smaller than 2, being 0<x<2;
ii) optionally contacting the solid Mg(OR 1 ) x X 1 2-x obtained in step i) with at least one activating compound selected from the group formed by activating electron donors and metal alkoxide compounds of formula M 1 (OR 2 ) v-w (OR 3 ) w or M 2 (OR 2 ) v-w (R 3 ) w , to obtain a second intermediate reaction product; wherein: M 1 is a metal selected from the group consisting of Ti, Zr, Hf, Al or Si; M 2 is a metal being Si; v is the valency of M 1 or M 2 ; w is smaller than v; R 2 and R 3 are each a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group may be substituted or unsubstituted, may contain one or more heteroatoms;
iii) contacting the first or second intermediate reaction product obtained in step i) or ii) respectively, with a halogen-containing titanium compound and either an activator or an internal electron donor to obtain a third intermediate reaction product;
iv) modifying the third intermediate reaction product obtained in step iii) with a modifier having the formula M(p)X p , wherein M is selected from the group consisting of aluminum, boron, gallium, zinc, copper, thallium, indium, vanadium, chromium and iron, p is the oxidation state of M, and wherein X is a halide, to yield a modified intermediate reaction product; and
v) contacting said modified intermediate reaction product obtained in step iv) with a halogen-containing titanium compound and, in the case that in step iii) an activator was used, an internal donor to obtain the procatalyst.

2. The process according to claim 1 , wherein the activator added during step iii) is selected from the group consisting of alkylbenzoate, benzamide, and monoester.

3. The process according to claim 1 , wherein the activator added during step iii) is ethylbenzoate and the internal donor used during step v) is 4-[benzoyl(methyl)amino]pentan-2-yl benzoate.

4. The process according to claim 1 , wherein during step iv) aluminum halide is used as the modifier.

5. The process according to claim 1 , wherein the compound of formula R 4 MgX 4 2-z used in step i), the halogen-containing titanium compound used in step iii) and step v) and the modifier used in step iv) are used in such amounts that the resulting procatalyst comprises in wt. % based on the total weight of the procatalyst: magnesium: from 15 to 24; titanium: from 1 to 4; modifier: from 0.05 to 2.0.

6. The process according to claim 1 , wherein step ii) is carried out using a combination of an alcohol and an tetra alkoxy titanium compound, as the activating compounds.

7. The process according to claim 1 , wherein steps iii), iv) and v) are carried out in the same reactor.

8. The process according to claim 1 , wherein the internal donor used during step iii) or step v) is selected from the group consisting of dicarboxylic acid esters according to Formula VI and aminobenzoates according to formula XI:

wherein R 40 and R 41 are each independently a linear, branched or cyclic, and substituted or unsubstituted hydrocarbyl group selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof; and wherein
R 42 , R 43 , R 44 , R 45 are each independently selected from hydrogen, a halide or a linear, branched or cyclic, and a substituted or unsubstituted hydrocarbyl group and one or more combinations thereof; wherein R 80 is a substituted or unsubstituted aromatic group, selected from aryl or alkylaryl groups, having from 6 to 20 carbon atoms; R 81 , R 82 , R 83 , R 84 , R 85 , and R 86 are each independently selected from hydrogen or a linear, branched or cyclic, and substituted or unsubstituted hydrocarbyl group and one or more combinations thereof.

9. The process according to claim 5 , wherein the resulting procatalyst comprises in wt. % based on the total weight of the procatalyst: magnesium: from 19.0 to 19.5; titanium: from 1.5 to 3.5; Group 13 or transition metal: from 0.1 to 0.4.

Assignees

• Saudi Basic Ind Corp
• Sabic Global Technologies Bv

Inventors

• Siddiqui Inaamul Haq
• Al-Bahily Khalid Abdullah
• Al-Gahtani Khalid Mohammed

Classifications

• C08F110/06 Primary

  Propene · CPC title

• C08F4/6567

  and aluminium or compounds thereof · CPC title

• C08F2500/04

  Broad molecular weight distribution, i.e. Mw/Mn > 6 · CPC title

• C08F4/654

  with magnesium or compounds thereof · CPC title

• C08F4/6557

  and metals of C08F4/64 or compounds thereof · CPC title