Methods and apparatus for making catalyst films

Patent metadata

Field	Value
Publication number	US-9861973-B2
Application number	US-201314399593-A
Country	US
Kind code	B2
Filing date	May 10, 2013
Priority date	May 10, 2012
Publication date	Jan 9, 2018
Grant date	Jan 9, 2018

Abstract

The present disclosure provides improved films/coatings (e.g., catalyst films/coatings), and improved assemblies/methods for fabricating such films/coatings. More particularly, the present disclosure provides advantageous assemblies/methods for fabricating or synthesizing catalytic material (e.g., catalytic nanostructures) in flame and depositing the catalytic material onto substrates. The present disclosure provides improved catalytic nanostructures, and improved assemblies and methods for their manufacture. In exemplary embodiments, the present disclosure provides for methods/assemblies for synthesizing electrocatalytic nanostructures in flame and depositing such material or catalyst onto different substrates or supports. As such, the present disclosure provides advantageous assemblies that are configured and dimensioned to deposit fully dense, controlled porosity films (e.g., films of metals and oxides or core-shell particles) onto different substrates.

First claim

What is claimed is:

1. A method for fabricating catalytic material comprising:
providing a first elongated member extending from a first end to a second end, the first end in fluid communication with a liquid precursor feedstock that includes particles;
providing a second elongated member extending from a first end to a second end, the first end mounted with respect to the second end of the first elongated member and in fluid communication with the liquid precursor feedstock;
providing a channel of a housing, the channel disposed around at least a portion of the second elongated member;
supplying a fuel to the channel, the channel configured and dimensioned to supply the fuel along with the liquid precursor feedstock from the second end of the second elongated member to form a substantially co-flow spray;
supplying the substantially co-flow spray into the open atmosphere proximal to the second end of the second elongated member and igniting it to form a flame spray;
providing a surface of the housing positioned proximal to the second end of the second elongated member and angled relative to the central axis of the second elongated member, the angled surface including a plurality of ports, each port configured and dimensioned to supply a gas stream;
igniting the gas stream to stabilize the flame spray;
providing a circular quench assembly that includes a plurality of circumferentially-spaced nozzles that define a substantially circular quench zone distal to the second end of the second elongated member;
providing air flow at an inlet pressure through the plurality of circumferentially-spaced nozzles to establish a region of reduced pressure relative to the inlet pressure in the center of the substantially circular quench zone that pulls in a volume of surrounding air and creates a conical ring of air, thereby introducing turbulence and vapor to the flame spray to cool the flame spray and dilute the gas stream; and
directing the stabilized flame spray toward a substrate for deposition of the particles thereon.

2. The method of claim 1 , wherein the substrate is mounted with respect to a substrate holder, the substrate holder configured and dimensioned to hold a liquid to hydrate or cool the substrate.

3. The method of claim 1 , wherein the deposited particles include a microstructure having nanosized features.

4. The method of claim 1 , wherein the liquid precursor feedstock includes propane; and
wherein the co-flow spray is formed at least in part by a combination of pressure, heat and supercritical atomization due to the expansion of the propane above its critical temperature thereby forming droplets.

5. The method of claim 1 , wherein the angled surface of the housing is angled at about 45° relative to the central axis of the second elongated member.

6. The method of claim 1 , wherein the angled surface includes six ports, the ports positioned substantially evenly spaced apart from one another about a radius around the central axis of the second elongated member.

7. The method of claim 1 , further comprising at least one humidifier nozzle, the at least one humidifier nozzle configured and dimensioned to supply humidity to the substrate.

8. The method of claim 1 , wherein the deposited particles include platinum particles; and wherein the substrate includes a corrosion resistant support.

9. The method of claim 1 , wherein the deposited particles form at least a portion of an oxygen evolution anode.

10. The method of claim 1 , wherein the deposited particles form at least a portion of a lithium battery cathode or anode.

11. The method of claim 1 , wherein the deposited particles form at least a portion of a core-shell particle structure.

12. The method of claim 1 , wherein the substrate includes nanofibers; and
wherein at least a portion of the particles are deposited on the nanofibers.

13. The method of claim 1 , wherein the deposited particles include amorphous particles.

14. The method of claim 1 , wherein the deposited particles include crystalline particles.

15. A fabrication method, comprising:
providing a first elongated member extending from a first end to a second end, the first end in fluid communication with a liquid precursor feedstock that includes particles;
providing a second elongated member extending from a first end to a second end, the first end mounted with respect to the second end of the first elongated member and in fluid communication with the liquid precursor feedstock;
providing a channel of a housing, the channel disposed around at least a portion of the second elongated member;
supplying a fuel to the channel, the channel configured and dimensioned to supply the fuel along with the liquid precursor feedstock from the second end of the second elongated member to form a substantially co-flow spray;
supplying the substantially co-flow spray into the open atmosphere proximal to the second end of the second elongated member and igniting it to form a flame spray;
providing a surface of the housing positioned proximal to the second end of the second elongated member and angled relative to the central axis of the second elongated member, the angled surface including a plurality of ports, each port configured and dimensioned to supply a gas stream;
igniting the gas stream to stabilize the flame spray;
providing a circular quench assembly that includes a plurality of circumferentially-spaced nozzles that define a substantially circular quench zone distal to the second end of the second elongated member;
delivering a quenching gas flow at an inlet pressure through the plurality of circumferentially-spaced nozzles to establish a region of reduced pressure relative to the inlet pressure in the center of the substantially circular quench zone, thereby introducing turbulence and vapor to the flame spray to cool the flame spray and dilute the gas stream; and
directing the stabilized flame spray toward a substrate for deposition of the particles thereon.

16. The method of claim 15 , wherein the substrate is mounted with respect to a substrate holder, the substrate holder configured and dimensioned to hold a liquid to hydrate or cool the substrate.

17. The method of claim 15 , wherein the deposited particles include a microstructure having nanosized features.

18. The method of claim 15 , wherein the angled surface of the housing is angled at about 45° relative to the central axis of the second elongated member.

19. The method of claim 15 , wherein the angled surface includes six ports, the ports positioned substantially evenly spaced apart from one another about a radius around the central axis of the second elongated member.

20. The method of claim 15 , further comprising at least one humidifier nozzle, the at least one humidifier nozzle configured and dimensioned to supply humidity to the substrate.

Assignees

• Univ Connecticut

Inventors

• Roller Justin
• Maric Radenka

Classifications

• B01J23/755

  Nickel · CPC title

• B05C19/00

  Apparatus specially adapted for applying particulate materials to surfaces · CPC title

• B01J23/468

  Iridium · CPC title

• H01M4/886

  Powder spraying, e.g. wet or dry powder spraying, plasma spraying · CPC title

• H01M4/926

  on carbon or graphite · CPC title