Method of manufacturing metal composite powder by wire explosion in liquid and multi carbon layer coated metal composite powder

Patent metadata

Field	Value
Publication number	US-9855602-B2
Application number	US-201614994386-A
Country	US
Kind code	B2
Filing date	Jan 13, 2016
Priority date	Jan 13, 2015
Publication date	Jan 2, 2018
Grant date	Jan 2, 2018

Abstract

Disclosed are a method of producing a metal composite powder by wire explosion in a liquid and a metal composite powder that is coated with a multi carbon layer. The production method includes a process of forming a first carbon layer on a surface of a metal wire consisting of a first metal, a process of forming a metal layer consisting of a second metal, which is different from the first metal, on a surface of the first carbon layer, and a process of forming a metal composite powder coated with a multi carbon layer by wire exploding the metal wire containing the first carbon layer and the metal layer formed on a surface thereof in a solution.

First claim

What is claimed is:

1. A method of producing a metal composite powder by electrically exploding a wire in a liquid, the method comprising:
forming a first carbon layer on a surface of a metal wire;
forming a metal layer on a surface of the first carbon layer; and
forming a metal composite powder coated with a multi carbon layer by exploding the metal wire in a solution,
wherein the metal wire comprises a first metal and the metal layer comprises a second metal which is different from the first metal.

2. The method of claim 1 , further comprising:
forming a second carbon layer on the metal layer, prior to the forming of the metal composite powder coated with the multi carbon layer by wire exploding the metal wire in the solution.

3. The method of claim 1 , wherein the metal layer is formed by electroplating or electroless plating.

4. The method of claim 1 , wherein the first metal and the second metal each comprises any one of copper (Cu), nickel (Ni), aluminum (Al), iron (Fe), zinc (Zn), gold (Au), silver (Ag), cobalt (Co), or chromium (Cr).

5. The method of claim 1 , wherein the multi carbon layer comprises 2 to 20 carbon atom layers of graphene.

6. The method of claim 1 , wherein the solution is an organic solution, an inorganic solution, or an organic-inorganic mixed solution.

7. A method producing a metal composite powder by electrically exploding a wire in a liquid, the method comprising:
forming a metal layer on a surface of a metal wire;
forming a carbon layer on a surface of the metal layer; and
forming a metal composite powder coated with a multi carbon layer by exploding the metal wire in a solution,
wherein the metal wire comprises a first metal and the metal layer comprises a second metal which is different from the first metal.

8. The method of claim 7 , wherein the first metal and the second metal each comprises any one of Cu, Ni, Al, Fe, Zn, Au, Ag, Co, or Cr.

9. The method of claim 1 or claim 7 , wherein the metal wire is made of Cu, the metal layer comprises a Ni layer, and a Ni content of the metal composite powder in a region in which the metal composite powder and the multi carbon layer form an interfacial surface is higher than a Ni content at a center of the metal composite powder.

10. A metal composite powder that is coated with a multi carbon layer, the metal composite powder comprising:
a metal composite particle containing a first metal and a second metal which is different from the first metal; and
a multi carbon layer formed on a surface of the metal composite particle, covering the metal composite particle, and containing at least two carbon atom layers,
wherein the metal composite particle contains Cu and Ni, and a Ni content of the metal composite powder in a region in which the metal composite powder and the multi carbon layer form an interfacial surface is higher than a Ni content at a center of the metal composite powder.

11. The metal composite powder of claim 10 , wherein the metal composite particle contains at least two selected from the group consisting of Cu, Ni, Al, Fe, Zn, Au, Ag, Co, and Cr.

Assignees

• Research & Business Found Sungkyunkwan Univ

Inventors

• Seo Su-Jeong
• Song Young-Il
• Park Jung-Kab
• Kim Tae-Yoo
• Son Hwa-Jin
• Shin Jin-Ha
• Lee Jungwoo
• Cho Younglae
• Park Jung-Ho
• Baeg Seung-Bin
• Ahn Byung-Wook
• Yun Sook-Young

Classifications

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• C25D5/48

  After-treatment of electroplated surfaces · CPC title

• C23C28/34

  including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title

• B22F9/14 Primary

  using electric discharge · CPC title