Fibers with chemical markers used for coding

Patent metadata

Field	Value
Publication number	US-9851341-B2
Application number	US-201514748753-A
Country	US
Kind code	B2
Filing date	Jun 24, 2015
Priority date	Jun 27, 2014
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Disclosed are fibers which contain identification fibers. The identification fibers can comprise one or more chemical markers, or taggants, which may vary among the fibers or be incorporated throughout all of the fibers. The disclosure also relates to the method for making and characterizing the fibers. Characterization of the fibers can include identifying chemical markers and correlating the chemical markers and a taggant chemical marker amounts of at least one of the chemical markers to manufacturer-specific taggants to determine supply chain information. The supply chain information can be used to track the fibers from manufacturing through intermediaries, conversion to final product, and/or the consumer.

First claim

We claim:

1. A method for characterizing a fiber sample wherein the fiber sample comprises fibers,
wherein the fibers comprise identification fibers,
wherein the identification fibers comprise 1 to 100 chemical markers,
wherein an amount of each of the chemical markers, based on a weight of the fibers, is defined as a chemical marker amount,
wherein at least one of the chemical marker amounts corresponds to a taggant chemical marker amount, and
wherein (i) the chemical markers and (ii) the at least one taggant chemical marker amounts are representative of at least one supply chain component of the fiber sample, and
wherein the method comprises:
(a) dissolving the fiber sample in a solvent to produce a sample solution and/or insolubles;
(b) analyzing the sample solution and/or the insoluble to identify the chemical markers and each of the chemical marker amounts.

2. The method of claim 1 , wherein the fibers further comprise standard fibers.

3. The method of claim 2 , further comprising
(a) correlating one or more of the chemical markers and the taggant chemical marker amounts to a database, wherein the database comprises manufacturer specific taggants; and
(b) determining the at least one supply chain component of the fiber sample, wherein the at least one supply chain component comprises a manufacturer of the standard fibers, a manufacture site of the standard fibers, a manufacturing line of the standard fibers, a production run of the standard fibers, a production date of the standard fibers, a package of the standard fibers, a warehouse of the standard fibers, a customer of the standard fibers, a ship-to location of the standard fibers, a manufacturer of a fiber band comprising the fibers, a manufacturing site of the fiber band, a manufacturing line of the fiber band, a production run of the fiber band, a production date of the fiber band, a package of the fiber band, a warehouse of the fiber band, a customer of the fiber band, or a ship-to location of the fiber band.

4. The method of claim 3 , wherein the at last one supply chain component comprises the manufacturer of the standard fibers or the fiber band comprising the fibers.

5. The method of claim 3 , wherein the at last one supply chain component comprises the manufacturer of the standard fibers or the fiber band comprising the fibers and the customer of the standard fibers or the fiber band.

6. The method of claim 3 , wherein the at last one supply chain component comprises the manufacturer of the standard fibers or a fiber band comprising the fibers and the ship-to location of the standard fibers or the fiber band.

7. The method of claim 3 , wherein the fiber sample comprises a portion of a filter rod or a portion of a cigarette filter.

8. The method of claim 1 , wherein the identification fibers comprise 1 to 50 of the chemical markers.

9. The method of claim 1 , further comprising adding N,O-bis(trimethylsilyl)trifluoroacetamide to the sample solution.

10. The method of claim 1 , wherein one or more of the chemical markers is selected from the group consisting of one or more taggant non-volatile organic compounds, one or more taggant photoluminescent materials, one or more taggant polymeric additives, one or more taggant carbohydrates, one or more taggant metal oxides, one or more taggant inorganic salts, one or more taggant optical isomers, one or more taggant isotopically labeled molecules, and one or more taggant trace chemicals inherent to a manufacturer of the standard fibers, and wherein a number of the taggant chemical marker amounts for each of the chemical makers ranges from 1 to 20.

11. The method of claim 10 , wherein a number of the taggant nonvolatile organic compounds ranges from 1 to 20 and wherein the taggant non-volatile organic compounds comprise lauric acid, palmitic acid, or stearic acid.

12. The method of claim 10 , wherein a number of the taggant photoluminescent materials ranges from 1 to 10, wherein the taggant photoluminescent materials comprise phosphorescent quantum dots, and wherein the phosphorescent quantum dots comprise Cd/Se ligand stabilized fluorescent nano-crystals.

13. The method of claim 10 , wherein a number of the taggant polymeric additives ranges from 1 to 20, wherein the taggant polymeric additives comprise polystyrene, and wherein an average molecular weight of the polystyrene ranges from 500 to 20,000,000.

14. The method of claim 10 , wherein a number of the taggant carbohydrates ranges from 1 to 10 and wherein the taggant carbohydrates comprise glucose, fructose, sucrose, or lactose.

15. The method of claim 10 , wherein the chemical markers comprise the taggant metal oxides or the taggant inorganic salts,
wherein a number of the taggant metal oxides ranges from 1 to 20, or wherein a number of the taggant inorganic salts ranges from 1 to 20,
wherein the taggant metal oxides comprise titanium dioxide, zirconium oxides, zinc oxides, aluminum oxides, manganese oxides, magnesium oxides, calcium oxides, tin oxides, vanadium oxides, nickel oxides or iron oxide or wherein the taggant inorganic salts comprise salts of cesium, indium, or samarium.

16. The method of claim 1 and wherein each of the chemical marker amounts range from 100 ppb to 10,000 ppm, based on the weight of the fibers.

17. The method of claim 1 , wherein the fibers comprise acrylic, modacrylic, aramid, nylon, polyester, polypropylene, rayon, polyacrylonitrile, polyethylene, PTFE, or cellulose acetate.

18. The method of claim 1 , wherein the identification fibers comprise acrylic, modacrylic, aramid, nylon, polyester, polypropylene, rayon, polyacrylonitrile, polyethylene, PTFE, or cellulose acetate, and the standard fibers comprise cellulose acetate.

19. The method of claim 1 , wherein the solvent comprises acetone, tetrahydrofuran, dichloromethane, methanol, chloroform, dioxane, N,N-dimethylformamide, dimethyl sulfoxide, methyl acetate, ethyl acetate, nitric acid or pyridine.

20. The method of claim 1 , wherein the analyzing comprises a use of mass spectrometry, spectroscopy, nuclear magnetic resonance, or x-ray diffraction.

21. The method of claim 1 , wherein the analyzing comprises a use of chromatography.

22. The method of claim 1 , wherein the analyzing comprises a use of gas chromatography coupled to flame ionization detection, size exclusion chromatography followed by UV-vis spectroscopy, fluorescence spectroscopy, inductively coupled plasma (ICP) followed by mass spectrometry, or ICP followed by optical emission spectrometry.

23. The method of claim 1 , further comprising
(a) correlating one or more of the chemical markers and the taggant chemical marker amounts to a database, wherein the database comprises manufacturer specific taggants; and
(b) determining the at least one supply chain component of the fiber sample, wherein the at least one supply chain component comprises a manufacturer of the fibers, a manufacture site of the fibers, a manufacturing line of the fibers, a production run of the fibers, a production date of the fibers, a package of the fibers, a warehouse of the fibers, a customer of the fibers, a ship-to location of the fibers, a manufacturer of a fiber band comprising the fibers, a manufacturing site of the fiber band, a manufacturing line of the fiber band, a production run of the fiber band, a production date of the fiber band, a package of the fiber band, a warehouse of the fiber band, a customer of the fiber band, or a ship-to location of the fiber band.

Assignees

• Eastman Chem Co

Inventors

• Gaynor Scott Gregory
• Mcleod Andrew Ervin
• Rodig Michael John
• Steach Jeremy Kenneth
• Collazo Humberto
• Wilson Steven Anthony
• Salyer Lydia J
• Seiler Brian Douglas
• Horton Jonathan

Classifications

• G01N2223/056

  diffraction · CPC title

• A24D3/067

  characterised by functional properties · CPC title

• A24D3/00

  Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes · CPC title

• A24D3/063

  of the fibers · CPC title

• G01N33/365

  Filiform textiles, e.g. yarns · CPC title