Oxidative desulfurization of oil fractions and sulfone management using an FCC
US-10087377-B2 · Oct 2, 2018 · US
US9850197B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9850197-B2 |
| Application number | US-201414563159-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 8, 2014 |
| Priority date | Aug 29, 2008 |
| Publication date | Dec 26, 2017 |
| Grant date | Dec 26, 2017 |
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Ionic liquids of the general formula C + A − where C + represents an organic cation, specifically, but not limited to the imidazolium, pyridinium, isoquinolinium, ammonium types, which have aliphatic and aromatic substituents, while A − represents a carboxylate, aromatic and aliphatic anion. The ionic liquids are synthesized under conventional heating or microwave irradiation This invention is also related to the application of ionic liquids to remove sulfur compounds of naphthas through a liquid-liquid extraction and the recovery and reuse of ionic liquids by the application of heat, reduced pressure and washing with solvents.
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What is claimed is: 1. An ionic liquid containing a heterocyclic cation and a carboxylate anion and having the formula C + A − wherein C + is an isoquinolinium cation, and A − is a carboxylate anion having the formula where R 4 is selected from the group consisting of cycloalkyl, alkenyl, and benzylic. 2. The ionic liquid of claim 1 , wherein said heterocyclic cation is an isoquinolinium cation having at least one substituent selected from the group consisting of benzylic, cycloalkyl, and alkenyl having 1 to 10 carbon atoms. 3. The ionic liquid of claim 1 , wherein said isoquinolinium cation has the formula where R is selected from the group consisting of alkyl, cycloalkyl, alkenyl, benzylic, and functionalized alkyl having 1 to 10 carbon atoms.
Heteroatoms content, i.e. S, N, O, P · CPC title
Recovery of used solvent · CPC title
Organic compounds only · CPC title
Light gasoline having a boiling range of about 20 - 100 °C · CPC title
Quaternary ammonium compounds · CPC title
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