Method for washing reactor

Patent metadata

Field	Value
Publication number	US-10076773-B2
Application number	US-201113817218-A
Country	US
Kind code	B2
Filing date	Aug 12, 2011
Priority date	Aug 19, 2010
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

The method for cleaning a reactor of the present invention comprises passing a solvent through a wax-fraction hydrocracking apparatus which is charged with a catalyst and to which supply of a wax fraction is stopped, wherein the solvent comprising at least one oil selected from a group consisting of hydrocarbon and vegetable oils, and having a sulfur content of less than 5 ppm and being in a liquid state at 15° C.

First claim

The invention claimed is:

1. A method for regenerating a catalyst, to which wax and oil are attached, comprising:
stopping the supply of a wax fraction through a fixed-bed flow reactor charged with a catalyst for hydrocracking a wax fraction;
passing a solvent comprising at least one oil selected from the group consisting of hydrocarbon and vegetable oils, wherein the oil has a sulfur content of less than 5 ppm and is in a liquid state at 15° C., through a fixed-bed flow reactor charged with the catalyst for hydrocracking the wax fraction, said wax fraction being dissolved in the solvent;
picking a check-up sample from the solvent discharged from the fixed-bed flow reactor;
visually checking, at a temperature at or below the temperature at which the wax deposits from the solvent with a desired level of wax concentration, for the presence or absence of wax deposition in the check-up sample;
continuing the passage of the solvent through the fixed-bed flow reactor if wax deposition is present in the check-up sample, but discontinuing the passage of the solvent through the fixed-bed flow reactor if wax deposition is absent in the check-up sample;
discharging the catalyst from the reactor when wax deposition is absent in the check-up sample and the flow passage of the solvent through the reactor is stopped; and
removing oil on the catalyst discharged from the fixed-bed flow reactor after the wax fraction present on and around the catalyst is removed by the solvent, by heating the catalyst under an inert gas atmosphere to evaporate the oil an obtain a deoiled catalyst.

2. The method according to claim 1 , wherein the solvent passed through the fixed-bed flow reactor is then fractionated in a rectifying tower positioned downstream of the fixed-bed flow reactor, and again passed through the fixed-bed flow reactor prior to said discontinuing of the passage of the solvent through the fixed-bed flow reactor.

3. The method according to claim 1 , wherein the solvent is a hydrocarbon produced by a GTL process.

4. The method according to claim 1 , wherein the solvent is a light oil fraction produced by a GTL process.

5. The method according to claim 1 , wherein the temperature at or below the temperature at which the wax deposits from the solvent with a desired level of wax concentration is between −20° C. to 40° C.

6. The method according to claim 1 , wherein the inert gas atmosphere comprises nitrogen gas.

7. The method according to claim 6 , wherein the deoiled catalyst is heated under an air atmosphere to obtain a regenerated catalyst.

8. A method for regenerating a catalyst, to which wax and oil are attached, comprising:
stopping the supply of a wax fraction through a fixed-bed flow reactor charged with a catalyst for hydrocracking a wax fraction;
passing a solvent comprising at least one oil selected from the group consisting of hydrocarbon and vegetable oils, wherein the oil has a sulfur content of less than 5 ppm and is in a liquid state at 15° C., through a fixed-bed flow reactor charged with the catalyst for hydrocracking the wax fraction, said wax fraction being dissolved in the solvent;
picking a check-up sample from the solvent discharged from the fixed-bed flow reactor;
checking, at a temperature at or below the temperature at which the wax deposits from the solvent with a desired level of wax concentration, for the presence or absence of wax deposition in the check-up sample;
continuing the passage of the solvent through the fixed-bed flow reactor if wax deposition is present in the check-up sample, but discontinuing the passage of the solvent through the fixed-bed flow reactor if wax deposition is absent in the check-up sample;
discharging the catalyst from the reactor when wax deposition is absent in the check-up sample and the flow passage of the solvent through the reactor is stopped; and
removing oil on the catalyst discharged from the fixed-bed flow reactor after the wax fraction present on and around the catalyst is removed by the solvent, by heating the catalyst under an inert gas atmosphere in order to evaporate the oil and obtain a deoiled catalyst,
wherein the temperature is set such that the concentration of the wax in the solvent is confirmed to be decreasing, between each pass-through of the solvent, to a desired level based on a previously obtained relationship between the concentration of the wax in the solvent and a temperature at which the wax starts depositing.

9. The method according to claim 8 , wherein the solvent passed through the fixed-bed flow reactor is then fractionated in a rectifying tower positioned downstream of the fixed-bed flow reactor, and again passed through the fixed-bed flow reactor prior to said discontinuing of the passage of the solvent through the fixed-bed flow reactor.

10. The method according to claim 8 , wherein the solvent is a hydrocarbon produced by a GTL process.

11. The method according to claim 8 , wherein the temperature at or below the temperature at which the wax deposits from the solvent with a desired level of wax concentration is between −20° C. to 40° C.

12. The method according to claim 8 , wherein the inert gas atmosphere comprises nitrogen gas.

13. The method according to claim 12 , wherein the deoiled catalyst is heated under an air atmosphere to obtain a regenerated catalyst.

Assignees

• Takahashi Shinya
• Tasaka Kazuhiko
• Tanaka Yuichi
• Iwama Marie
• Japan Oil Gas & Metals Jogmec
• Inpex Corp
• Jx Nippon Oil & Energy Corp
• Japan Petroleum Exploration Co Ltd
• Cosmo Oil Co Ltd
• Nippon Steel & Sumikin Eng Co

Inventors

• Takahashi Shinya
• Tasaka Kazuhiko
• Tanaka Yuichi
• Iwama Marie

Classifications

• C10G2300/4031

  Start up or shut down operations · CPC title

• C10G2300/1022

  Fischer-Tropsch products · CPC title

• C10G2300/1014

  of vegetal origin · CPC title

• C10G47/36

  Controlling or regulating · CPC title

• C10G47/00

  Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title