Functional polymer membrane and method of producing the same

Patent metadata

Field	Value
Publication number	US-9850147-B2
Application number	US-201514668222-A
Country	US
Kind code	B2
Filing date	Mar 25, 2015
Priority date	Sep 28, 2012
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

A functional polymer membrane having a pore volume fraction of 0.6% or more and 3.0% or less by allowing a reaction of curing a composition containing a polymerizable compound (A) and a copolymerizable monomer (B).

First claim

The invention claimed is:

1. A functional polymer membrane having a pore volume fraction of 0.6% or more and 3.0% or less prepared by allowing a reaction of curing a composition containing a polymerizable compound (A) and a copolymerizable monomer (B),
wherein the polymerizable compound (A) has at least two ethylenically unsaturated groups in its molecule, and is water soluble, and
wherein a solid content of the polymerizable compound (A) is 20 to 85 parts by mass based on 100 parts by mass of the total solid content in the composition.

2. The functional polymer membrane according to claim 1 , wherein the polymerizable compound (A) is a compound selected from the group consisting of a (meth)acrylate compound, a (meth)acrylamide compound, a vinyl ether compound, an aromatic vinyl compound, an N-vinylamide compound, and an allyl compound.

3. The functional polymer membrane according to claim 1 , wherein the polymerizable compound (A) is a compound represented by Formula (1), and wherein the copolymerizable monomer (B) is a monofunctional polymerizable compound,

wherein R 1 represents a hydrogen atom or a methyl group; L 1 represents a linear or branched alkylene group having 2 to 4 carbon atoms; in L 1 , the oxygen atom and nitrogen atom bonded to both ends of L 1 do not bind to the same carbon atom of L 1 ; L 2 represents a divalent linking group; k represents 2 or 3; x, y and z each independently represent an integer of from 0 to 6; and (x+y+z) satisfies from 0 to 18.

4. The functional polymer membrane according to claim 1 , wherein molar ratio r of the polymerizable compound (A) to the copolymerizable monomer (B) is 0.1<r<3.5.

5. The functional polymer membrane according to claim 1 , wherein the copolymerizable monomer (B) has a dissociative group.

6. The functional polymer membrane according to claim 5 , wherein the dissociative group is a sulfo group or a salt thereof, or a carboxy group or a salt thereof.

7. The functional polymer membrane according to claim 5 , wherein the dissociative group is selected from the group consisting of a sulfo group or a salt thereof, a carboxy group or a salt thereof, an ammonio group and a pyridinio group.

8. The functional polymer membrane according to claim 1 , wherein the copolymerizable monomer (B) is a (meth)acrylate compound or a (meth)acrylamide compound, each of which has a chemical structure different from that of the polymerizable compound (A).

9. The functional polymer membrane according to claim 1 , which contains a support.

10. The functional polymer membrane according to claim 9 , wherein the support is a synthetic woven fabric or a synthetic non-woven fabric, a sponge-like film or a film having microscopic through-holes.

11. The functional polymer membrane according to claim 9 , wherein the support is made from polyolefin.

12. The functional polymer membrane according to claim 1 , wherein the functional polymer membrane is an ion exchange membrane, a reverse osmosis membrane, a forward osmosis membrane, or a gas separation membrane.

13. The functional polymer membrane according to claim 1 , wherein a water uptake of the functional composite membrane is less than 70% based on the mass of a dry membrane.

14. The functional polymer membrane according to claim 1 , wherein the polymerizable compound (A) is water soluble in the degree that at least 50 parts by mass are dissolved into 100 parts by mass of distilled water at 25° C.

15. A method of producing a functional polymer membrane, comprising the step of:
allowing a reaction of curing a composition containing a polymerizable compound (A) and a copolymerizable monomer (B), thereby adjusting a pore volume fraction to 0.6% or more and 3.0% or less,
wherein the polymerizable compound (A) has at least two ethylenically unsaturated groups in its molecule, and is water soluble, and
wherein a solid content of the polymerizable compound (A) is 20 to 85 parts by mass based on 100 parts by mass of the total solid content in the composition.

16. The method of producing a functional polymer membrane according to claim 15 ,
wherein the polymerizable compound (A) is a compound represented by Formula (1), and wherein the copolymerizable monomer (B) is a monofunctional polymerizable compound,

wherein R 1 represents a hydrogen atom or a methyl group; L 1 represents a linear or branched alkylene group having 2 to 4 carbon atoms; in L 1 , the oxygen atom and nitrogen atom bonded to both ends of L 1 do not bind to the same carbon atom of L 1 ; L 2 represents a divalent linking group; k represents 2 or 3; x, y and z each independently represent an integer of from 0 to 6; and (x+y+z) satisfies from 0 to 18.

17. The method of producing a functional polymer membrane according to claim 15 , wherein a solvent (C) is contained in the composition, and a content of the solvent (C) is 1 to 35 parts by mass based on 100 parts by mass of the total mass of the composition.

18. The method of producing a functional polymer membrane according to claim 17 , wherein the solvent (C) is water or a water-miscible solvent.

19. The method of producing a functional polymer membrane according to claim 15 , comprising the steps of:
applying and/or impregnating the composition to a support; and
allowing a reaction of curing the composition to form a membrane.

20. The method of producing a functional polymer membrane according to claim 15 , wherein the curing reaction includes a curing reaction due to polymerization of the composition by irradiating the composition with energy rays.

Assignees

• Fujifilm Corp

Inventors

• Takamoto Tetsufumi
• AMAO Akihito
• Toihara Nagisa
• Ikeda Morihito
• Sano Satoshi
• Kodama Keisuke

Classifications

• C02F2301/00

  General aspects of water treatment · CPC title

• C08F222/385

  Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide · CPC title

• B01D2325/20

  Specific permeability or cut-off range · CPC title

• B01D2323/30

  Cross-linking · CPC title

• B01D71/40

  Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters · CPC title