Diamond material

Patent metadata

Field	Value
Publication number	US-9840419-B2
Application number	US-201514722628-A
Country	US
Kind code	B2
Filing date	May 27, 2015
Priority date	Jun 26, 2009
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

The present disclosure relates to a method of making fancy orange synthetic CVD diamond material. Among other things, the method may involve (i) providing a single crystal diamond material that has been grown by CVD and has a [N s 0 ] concentration less than 5 ppm; (ii) irradiating the provided CVD diamond material so as to introduce isolated vacancies V into at least part of the provided CVD diamond material such that the total concentration of isolated vacancies [V T ] in the irradiated diamond material is at least the greater of (a) 0.5 ppm and (b) 50% higher than the [N s 0 ] concentration in ppm in the provided diamond material; and (iii) annealing the irradiated diamond material to forming vacancy chains from at least some of the introduced isolated vacancies.

First claim

The invention claimed is:

1. A method of making fancy orange synthetic CVD diamond material, the method comprising: (i) irradiating a single crystal diamond material that has been grown by CVD and has a [N s 0 ] concentration less than 5 ppm to introduce isolated vacancies V into at least part of the CVD diamond material, the total concentration of isolated vacancies [V T ] in the irradiated diamond material being at least the greater of (a) 0.5 ppm and (b) 50% higher than the [N s 0 ] concentration in ppm in the single crystal diamond material, and (ii) annealing the irradiated diamond material to form vacancy chains from at least some of the introduced isolated vacancies.

2. A method according to claim 1 , wherein the annealing is carried out at a temperature of at least 700° C. and at most 900° C.

3. A method according to claim 1 , wherein the annealing is carried out for a period of at least 2 hours.

4. A method according to claim 1 , wherein the annealing steps reduce the concentration of isolated vacancies in the irradiated diamond material, whereby the concentration of isolated vacancies in the irradiated and annealed diamond material is <0.3 ppm.

5. A method according to claim 1 , wherein the absorption coefficients at 350 nm and 510 nm for the diamond material prior to irradiation are less than 3 cm −1 and 1 cm −1 respectively.

6. A method according to claim 1 , wherein the atomic boron concentration [B] in the diamond material is less than 5×10 15 cm −1 .

7. A method according to claim 1 , wherein uncompensated boron is present in the diamond material in a concentration of >5×10 15 cm −3 , and the irradiation step (ii) introduces sufficient isolated vacancies into the diamond material so that total concentration of isolated vacancies [V T ] in the irradiated diamond material, after isolated vacancies have been used to compensate the boron, is at least the greater of (a) 0.5 ppm and (b) 50% higher than the [N s 0 ] concentration in ppm in the diamond material prior to its irradiation.

8. A method according to claim 1 , wherein the diamond material is irradiated from two or more sides.

9. A method according to claim 1 , wherein at least 50% of the CVD diamond has been formed from a single growth sector.

10. A method according to claim 1 , wherein, after the irradiation and annealing steps (ii) and (iii), the absorption in the 250 nm region of the irradiated and annealed diamond material, when measured at room temperature, is greater than 5 cm −1 .

11. A method according to claim 1 , wherein the diamond material prior to irradiation according to step (i) of the method shows a measurable difference in at least one of its absorption characteristics in first and second states, the first state being after exposure to irradiation having an energy of at least 5.5 eV and the second state being after thermal treatment at 798K (525° C.), and wherein after the irradiation and annealing steps of the method the change in color saturation value C* between the diamond material in the said first and second states is reduced by at least 0.5 compared to the change in color saturation value C* between the diamond material in the said first and second states for the diamond material prior to its irradiation.

12. A method according to claim 1 , wherein after the irradiation and annealing steps of the method, the change in color saturation C* of the diamond material in first and second states is less than 1, the first state being after exposure to irradiation having an energy of at least 5.5 eV and the second state being after thermal treatment at 798 K (525° C.).

13. A method according to claim 1 , wherein the diamond material is annealed in the temperature range 1400° C.-2500° C. prior to the irradiation step.

14. A method according to claim 1 , wherein the annealing step (ii) of method claim 1 is carried out after irradiation step (i) of method claim 1 is complete.

Assignees

• Element Six Tech Ltd

Inventors

• Twitchen Daniel James
• Geoghegan Sarah Louise
• Perkins Neil

Classifications

• C30B25/105

  by irradiation or electric discharge · CPC title

• C23C16/27

  Diamond only · CPC title

• A44C17/008

  Glass stones · CPC title

• C30B29/04

  Diamond · CPC title

• C01B32/28 Primary

  After-treatment, e.g. purification, irradiation, separation or recovery · CPC title