Gas sensor using an ionic liquid electrolyte

Patent metadata

Field	Value
Publication number	US-9835581-B2
Application number	US-201314037959-A
Country	US
Kind code	B2
Filing date	Sep 26, 2013
Priority date	Sep 26, 2013
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

A gas sensor having a housing with first and second chambers featuring a porous separator located there between. The first chamber of the sensor being connected to atmosphere via a gas diffusion aperture. The gas sensor having a sensing electrode disposed within the first chamber and at least a second electrode disposed within the second chamber. The sensor having an ionic liquid electrolyte disposed within the second chamber where the sensing electrode and at least second electrodes comprise platinum.

First claim

What is claimed is:

1. An apparatus comprising:
a housing having first and second chambers with a porous separator located there between and with the first chamber connected to atmosphere via a gas diffusion aperture;
a sensing electrode disposed within the first chamber;
at least one additional electrode disposed within the second chamber;
an acid doped ionic liquid electrolyte disposed within the second chamber, wherein the acid doped ionic liquid electrolyte comprises an ionic liquid electrolyte and an acid dopant, wherein the sensing electrode and the at least one additional electrode further comprise platinum, and wherein the ionic liquid electrolyte comprises 1,2,4-trimethylpyrazolium methylsulfate.

2. The apparatus as in claim 1 , wherein at least one of the sensing electrode or the at least one additional electrode comprises platinum black.

3. The apparatus as in claim 1 , wherein the apparatus comprises a hydrogen sulfide sensor with substantially no cross-sensitivity to carbon monoxide.

4. The apparatus as in claim 1 , wherein at least one of the sensing electrode or the at least one additional electrode comprises substantially 5% platinum on the carbon.

5. The apparatus as in claim 1 , wherein the acid doped ionic liquid electrolyte comprises about 1% acid doping.

6. The apparatus as in claim 1 , wherein the acid doped ionic liquid electrolyte comprises about 0.1 kg/mol acid doping.

7. An apparatus comprising:
a housing with first and second internal chambers divided by a separator and an aperture connecting the first chamber to atmosphere;
a sensing electrode disposed within the first chamber;
at least one additional electrode disposed within the second chamber;
an acid doped ionic liquid electrolyte disposed within the second chamber, wherein the sensing and the at least one additional electrode further comprise platinum on carbon, wherein the acid doped ionic liquid electrolyte is acid doped with methanesulfonic acid, and wherein the sensing electrode and the at least one additional electrode are configured to provide an output in response to hydrogen sulfide entering through the aperture which is greater than an output in response to carbon monoxide.

8. The apparatus as in claim 7 , wherein at least one of the sensing electrode or the at least one additional electrode comprises platinum black.

9. The apparatus as in claim 7 , wherein at least one of the sensing electrode or the at least one additional electrode comprises substantially 5% platinum on carbon.

10. The apparatus as in claim 7 , wherein the acid doped ionic liquid electrolyte comprises one of: 1-ethyl-3-methylimidazolium hydrogensulfate (EMIM.HS)+methanesulfonic acid (MSA), 1-ethyl-3-methylimidazolium methylsulfate (EMIM.MS)+MSA, 1,2,4-trimethylpyrazolium methylsulfate (TMP.MS)+MSA, N-n-butyl-N-methylpiperidinium bis(trifluoromethane)sulfonimide (BMPI.TFSI)+MSA, N,N,N′,N′-tetraethylsulfamide TES.TFSI+MSA, N,N-dimethylethanolamine bis(trifluoromethane)sulfonimide (DMEA.TFSI)+MSA, or butyldiethanolamine bis(trifluoromethylsulfonyl)imide (BDEA.TFSI)+MSA.

11. The apparatus as in claim 7 , wherein the acid doped ionic liquid electrolyte comprises about 1% acid doping.

12. The apparatus as in claim 7 , wherein the acid doped ionic liquid electrolyte comprises about 0.1 kg/mol acid doping.

13. The apparatus as in claim 7 , wherein the acid doped ionic liquid electrolyte comprises: 1-ethyl-3-methylimidazolium hydrogensulfate doped with 0.1 kg/mol methanesulfonic acid, N,N-Dimethylethanolammonium bis(trifluoromethylsulfonyl)amide doped with 0.1 kg/mol methanesulfonic acid, or 1,2,4-trimethylpyrazolium methylsulfate doped with 1% methanesulfonic acid.

14. An apparatus comprising:
a housing with first and second internal chambers divided by a separator and an aperture connecting the first chamber to atmosphere;
a sensing electrode disposed within the first chamber;
at least one additional electrode disposed within the second chamber;
an acid doped ionic liquid electrolyte disposed within the second chamber and saturating the separator thereby causing the sensing electrode to provide an output in response to hydrogen sulfide entering through the aperture, wherein the sensing and the at least one additional electrode further comprise platinum, wherein the acid doped ionic liquid electrolyte is acid doped with bis(trifluoromethane)sulfonimide acid, and wherein the sensing electrode is configured to provide an output in response to carbon monoxide that is less than an output in response to hydrogen sulfide.

15. The apparatus as in claim 14 , wherein the acid doped ionic liquid electrolyte comprises about 1% acid doping.

16. The apparatus as in claim 14 , wherein the acid doped ionic liquid electrolyte comprises about 0.1 kg/mol acid doping.

17. The apparatus as in claim 14 , wherein the acid doped ionic liquid electrolyte comprises: 1-ethyl-3-methylimidazolium hydrogensulfate, N,N-Dimethylethanolammonium bis(trifluoromethylsulfonyl)amide, or 1,2,4-trimethylpyrazolium methylsulfate.

Assignees

• Honeywell Int Inc
• Honeywell Int Inc

Inventors

• Chapples John
• Jones Martin Geoffrey

Classifications

• G01N27/4045 Primary

  for gases other than oxygen · CPC title

• G01N27/308

  at least partially made of carbon · CPC title

• G01N33/0044

  Sulphides, e.g. H2S · CPC title