Modified fluorine-containing copolymer and fluorine resin molded article
US-2016319089-A1 · Nov 3, 2016 · US
US9831014B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9831014-B2 |
| Application number | US-201415108104-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 19, 2014 |
| Priority date | Jan 8, 2014 |
| Publication date | Nov 28, 2017 |
| Grant date | Nov 28, 2017 |
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A heat-resistant electric wire including a core wire and a coating that covers the core wire. The coating is formed from a modified fluorine-containing copolymer that is obtained by irradiating a copolymer with radiation at an exposure of 250 kGy or lower at a temperature of not higher than the melting point of the copolymer. The copolymer is at least one copolymer selected from a copolymer including a tetrafluoroethylene unit and a perfluoro(alkyl vinyl ether) unit and a copolymer including a tetrafluoroethylene unit and a hexafluoropropylene unit.
Opening claim text (preview).
The invention claimed is: 1. A heat-resistant electric wire comprising a core wire and a coating that covers the core wire, the coating being formed from a modified fluorine-containing copolymer that is obtained by irradiating a copolymer with radiation at an exposure of 90 kGy or lower at a temperature of not higher than the melting point of the copolymer, wherein the copolymer including a tetrafluoroethylene unit and a perfluoro(alkyl vinyl ether) unit includes 2.0 to 12 mass % of the perfluoro(alkyl vinyl ether) unit in all the monomer units, wherein the copolymer has 191 or more functional groups per 10 6 carbon atoms and the functional groups include at least one selected from the group consisting of —CF═CF 2 , —CF 2 H, —COF, —COOH, —COOCH 3 ; —CONH 2 , and —CH 2 QH. 2. A method of producing the heat-resistant electric wire according to claim 1 , comprising extrusion-molding, on a core wire, a copolymer including a tetrafluoroethylene unit and a perfluoro(alkyl vinyl ether) unit to provide a coating that covers the core wire, and irradiating the coating with radiation. 3. The production method according to claim 2 , wherein the coating further contains polytetrafluoroethylene.
Homopolymers or copolymers of tetrafluoroethene · CPC title
comprising one or more extruded layers of insulation · CPC title
from other vinyl compounds · CPC title
from vinylfluorides or other fluoroethylenic compounds · CPC title
Homopolymers or copolymers of tetrafluoroethylene · CPC title
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