Polyamide resin composition and molded article

Patent metadata

Field	Value
Publication number	US-9828491-B2
Application number	US-201514972823-A
Country	US
Kind code	B2
Filing date	Dec 17, 2015
Priority date	Dec 18, 2014
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

A polyamide resin composition comprising a polyamide resin (A), a copper compound (B), a bromide of an alkali metal and/or a bromide of an alkaline earth metal (C), and at least one phosphorus compound (D) selected from the group consisting of tris(2,4-di-t-butylphenyl)phosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite, bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite, bis(2,4-dicumylphenyl)pentaerythritol diphosphite, 2,2′,2″-nitrilo(triethyl-tris(3,3′,5,5′-tetra-t-butyl-1,1′-biphenyl-2,2′-diyl))phosphite, tetrakis(2,4-di-t-butylphenyl)-4,4′-biphenylene diphosphonite, tetrakis(2,4-di-t-butylphenyl)-4,3′-biphenylene diphosphonite, and tetrakis(2,4-di-t-butylphenyl)-3,3′-biphenylene diphosphonate, in an amount of 0.01 to 10% by mass with respect to 100% by mass of the polyamide resin composition, at least one fatty acid compound (E), and an inorganic filler (F).

First claim

The invention claimed is:

1. A polyamide resin composition comprising:
30 to 99.94% by mass of a polyamide resin (A),
0.001 to 0.2% by mass of a copper compound (B),
0.05 to 5% by mass of a bromide of an alkali metal and/or a bromide of an alkaline earth metal (C),
at least one phosphorus (D) compound selected from the group consisting of tris(2,4-di-t-butylphenyl)phosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite, bis(2,6-di-t-butyl-4-methylphenyl)pentaerythritol diphosphite, bis(2,4-dicumylphenyl)pentaerythritol diphosphite, 2,2′,2″-nitrilo(triethyl-tris(3,3′,5,5′-tetra-t-butyl-1,1′-biphenyl-2,2′-diyl))phosphite, tetrakis(2,4-di-t-butylphenyl)-4,4′-biphenylene diphosphonite, tetrakis(2,4-di-t-butylphenyl)-4,3′-biphenylene diphosphonite, and tetrakis(2,4-di-t-butylphenyl)-3,3′-biphenylene diphosphonate, in an amount of 0.01 to 10% by mass with respect to 100% by mass of the polyamide resin composition,
at least one fatty acid compound (E) selected from the group consisting of fatty acid esters, fatty acid amides, and fatty acid metal salts, in an amount of 0.01 to 10% by mass with respect to 100% by mass of the polyamide resin composition, and
10 to 70% by mass of an inorganic filler (F).

2. The polyamide resin composition according to claim 1 , wherein the copper compound (B) is a copper halide compound.

3. The polyamide resin composition according to claim 1 , wherein a molar ratio of a halogen element/a copper element in the polyamide resin composition is 2/1 to 50/1.

4. The polyamide resin composition according to claim 1 , wherein the fatty acid compound (E) has an acid value of 10 mg/g or less.

5. The polyamide resin composition according to claim 1 , wherein the fatty acid compound (E) is a higher fatty acid metal salt with a metal content of 3.5 to 11.5% by mass.

6. The polyamide resin composition according to claim 1 , wherein the content of the copper element in the polyamide resin composition is 0.005% by mass or more with respect to the total mass of the polyamide resin composition.

7. The polyamide resin composition according to claim 1 , wherein the mass ratio [x/y] of the bromide of alkali metal and/or bromide of alkaline earth metal (C) [x] to the phosphorus compound (D) [y] contained in the polyamide resin composition is 100/1 to 1/100.

8. The polyamide resin composition according to claim 1 , wherein the polyamide resin composition does not cause the deposition of the copper element on the surface of a rolled steel (SS400) after the polyamide resin composition is in contact with the rolled steel at a temperature 30° C. higher than the melting point of the polyamide resin (A) for 12 hours.

9. A molded article comprising a polyamide resin composition according to claim 1 .

10. The molded article according to claim 9 , wherein the molded article is a vehicle part.

11. The polyamide resin composition according to claim 1 , wherein the inorganic filler (F) is selected from the group consisting of glass fibers, carbon fibers, glass flakes, talc, kaolin, mica, wollastonite, silica, carbon nanotubes, graphite, calcium fluoride, montmorillonite, swellable fluorine mica, and apatite.

Assignees

• Asahi Kasei Chemicals Corp
• Asahi Chemical Ind

Inventors

• Sakuma Teruaki
• Terada Kazunori

Classifications

• C08K3/16

  Halogen-containing compounds · CPC title

• C08K2003/162

  Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride · CPC title

• C08K5/20

  Carboxylic acid amides · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08K5/5357 Primary

  cyclic · CPC title