Friction reducing additive

Patent metadata

Field	Value
Publication number	US-9816045-B2
Application number	US-201514957225-A
Country	US
Kind code	B2
Filing date	Dec 2, 2015
Priority date	Mar 4, 2010
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

An automotive engine oil and/or fuel comprising a base stock and an organic polymeric friction reducing additive is claimed. A method of reducing friction in an automotive engine oil and/or fuel by the addition of the organic polymeric friction reducing additive to the base stock is also claimed.

First claim

The invention claimed is:

1. A non-aqueous automotive engine oil formulation, comprising a base stock, an organic polymeric friction reducing additive, a viscosity index improver, and an additive selected from organo-sulphur compounds and organo-molybdenum compounds, wherein the friction reducing additive has a molecular weight ranging from 1000 to 30,000 Daltons and is the reaction product of:
a) a hydrophobic polymeric sub unit which comprises a polyolefin derivatized to comprise a diacid and/or anhydride group;
b) a hydrophilic polymeric sub unit which comprises a hydrophilic polymer selected from polyethers; and
c) at least one of the following:
i) at least one backbone moiety capable of linking together polymeric sub units; and
ii) a chain terminating group.

2. The automotive engine oil formulation of claim 1 , wherein the hydrophobic polymeric sub unit comprises polyisobutylene polymer which has been subjected to maleinisation to form polyisobutylene succinic anhydride having a molecular weight in the range of 300 to 5000 Da.

3. The automotive engine oil formulation of claim 1 , wherein the hydrophilic polymeric sub unit comprises a polyethylene glycol.

4. The automotive engine oil formulation of claim 1 , wherein the reaction product comprises some block copolymer units formed from linking together during the reaction of some of the hydrophobic and hydrophilic polymeric sub units.

5. The automotive engine oil formulation of claim 4 , wherein the number of block copolymer units ranges from 1 to 20.

6. The automotive engine oil formulation of claim 4 , wherein the number of block copolymer units ranges from 1 to 15.

7. The automotive engine oil formulation of claim 4 , wherein the number of block copolymer units ranges from 1 to 7.

8. The automotive engine oil formulation of claim 1 , wherein the base stock has one of a Group II, Group III or Group IV base oil as its major component.

9. The automotive engine oil formulation of claim 1 , wherein the friction reducing additive is the reaction product of:
a) a hydrophobic polymeric sub unit which comprises a polyolefin derivatized to comprise a diacid and/or anhydride group;
b) a hydrophilic polymeric sub unit which comprises a hydrophilic polymer selected from polyethers; and
c) at least one backbone moiety capable of linking together polymeric sub units.

10. The automotive engine oil formulation of claim 9 , wherein the backbone moiety is chosen from a polyol, a polycarboxylic acid and mixtures thereof.

11. The automotive engine oil formulation of claim 1 , wherein the friction reducing additive is the reaction product of:
a) a hydrophobic polymeric sub unit which comprises a polyolefin derivatized to comprise a diacid and/or anhydride group;
b) a hydrophilic polymeric sub unit which comprises a hydrophilic polymer selected from polyethers; and
c) a chain terminating group.

12. The automotive engine oil formulation of claim 11 , wherein the chain terminating group is any fatty carboxylic acid.

13. The automotive engine oil formulation of claim 1 , wherein the viscosity index improver is selected from the group consisting of polyisobutenes, polymethacrylates acid esters, polyacrylate acid esters, diene polymers, polyalkyl styrenes, alkenyl aryl conjugated diene copolymers, and polyolefins.

14. An automotive engine oil formulation, comprising:
a base stock; and
an automotive engine oil additive package, wherein the automotive engine oil additive package comprises at least one automotive engine oil additive selected from the group consisting of detergents, dispersants, oxidation inhibitors, corrosion inhibitors, rust inhibitors, anti-wear additives, foam depressants, pour point depressants, viscosity index improvers, and mixtures thereof;

wherein the automotive engine oil formulation comprises an organic polymeric friction reducing additive, wherein the friction reducing additive has a molecular weight ranging from 1000 to 30,000 Daltons and is the reaction product of:
a) a hydrophobic polymeric sub unit which comprises a polyolefin derivatized to comprise a diacid and/or anhydride group;
b) a hydrophilic polymeric sub unit which comprises a hydrophilic polymer selected from polyethers; and
c) at least one of the following:
i) at least one backbone moiety capable of linking together polymeric sub units; or
ii) a chain terminating group.

15. The automotive engine oil formulation according to claim 14 wherein the automotive engine oil additive package comprises a viscosity index improver, a foam depressant, and a pour point depressant.

16. An automotive engine oil formulation, comprising a base stock selected from the group consisting of Group I to Group V base oils, an organic polymeric friction reducing additive, a dispersant and a detergent, wherein the friction reducing additive has a molecular weight ranging from 1000 to 30,000 Daltons and is the reaction product of:
a) a hydrophobic polymeric sub unit which comprises a polyolefin derivatized to comprise a diacid and/or anhydride group;
b) a hydrophilic polymeric sub unit which comprises a hydrophilic polymer selected from polyethers; and
c) at least one of the following:
i) at least one backbone moiety capable of linking together polymeric sub units; and
ii) a chain terminating group.

17. The automotive engine oil formulation of claim 16 wherein the dispersant is selected from carboxylic dispersants, amine dispersants, Mannich dispersants and polymeric dispersants.

Assignees

• Croda Int Plc

Inventors

• Thompson Lee
• Randles Steven James
• Boyde Stephen
• Gamwell John
• Readman Nicola

Classifications

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10M145/26

  Polyoxyalkylenes · CPC title

• C10L1/2381

  polyamides; polyamide-esters; polyurethane, polyureas (C10L1/221 takes precedence) · CPC title

• C10M149/18

  Polyamides · CPC title