Friction reducing additive

Patent metadata

Field	Value
Publication number	US-9228152-B2
Application number	US-201113582589-A
Country	US
Kind code	B2
Filing date	Mar 3, 2011
Priority date	Mar 4, 2010
Publication date	Jan 5, 2016
Grant date	Jan 5, 2016

Abstract

An automotive engine oil and/or fuel comprising a base stock and an organic polymeric friction reducing additive is claimed. A method of reducing friction in an automotive engine oil and/or fuel by the addition of the organic polymeric friction reducing additive to the base stock is also claimed.

First claim

The invention claimed is:

1. A method of lubricating an automotive engine using an automotive engine oil formulation comprising a base stock and a polymeric friction reducing additive wherein the additive has a molecular weight ranging from 1000 to 30,000 Daltons and comprises the reaction product of:
a) a hydrophobic polymeric sub unit which comprises a polyolefin derivatized to comprise a diacid and/or anhydride group;
b) a hydrophilic polymeric sub unit which comprises a hydrophilic polymer selected from polyethers; and
c) at least one of the following:
i) at least one backbone moiety capable of linking together polymeric sub units; or
ii) a chain terminating group.

2. The method of lubricating of claim 1 , wherein the hydrophobic polymeric sub unit comprises polyisobutylene polymer which has been subjected to maleinisation to form polyisobutylene succinic anhydride having a molecular weight in the range of 300 to 5000 Da.

3. The method of lubricating of claim 1 , wherein the hydrophilic polymeric sub unit comprises a polyethylene glycol.

4. The method of lubricating of claim 1 , wherein the backbone moiety is chosen from a polyol, a polycarboxylic acid and mixtures thereof.

5. The method of lubricating of claim 1 , wherein the chain terminating group is any fatty carboxylic acid.

6. The method of lubricating of claim 1 , wherein the reaction product comprises some block copolymer units formed from linking together during the reaction of some of the hydrophobic and hydrophilic polymeric sub units.

7. The method of lubricating of claim 6 , wherein the number of block copolymer units ranges from 1 to 20.

8. The method of lubricating of claim 1 , wherein the base stock has one of a Group II, Group III or Group IV base oil as its major component.

9. The method of lubricating of claim 1 , wherein the method A reduces friction in the automotive engine.

10. The method of lubricating of claim 6 , wherein the number of block copolymer units ranges from 1 to 15.

11. The method of lubricating of claim 6 , wherein the number of block copolymer units ranges from 1 to 7.

12. The method of lubricating of claim 9 , wherein the hydrophobic polymeric sub unit comprises polyisobutylene polymer which has been subjected to maleinisation to form polyisobutylene succinic anhydride having a molecular weight in the range of 300 to 5000 Da.

13. The method of lubricating of claim 9 , wherein the hydrophilic polymeric sub unit comprises a polyethylene glycol.

14. The method of lubricating of claim 9 , wherein the backbone moiety is chosen from a polyol, a polycarboxylic acid and mixtures thereof.

15. The method of lubricating of claim 9 , wherein the chain terminating group is any fatty carboxylic acid.

16. The method of lubricating of claim 9 , wherein the reaction product comprises some block copolymer units formed from linking together during the reaction of some of the hydrophobic and hydrophilic polymeric sub units.

17. The method of lubricating of claim 16 , wherein the number of block copolymer units ranges from 1 to 20.

18. The method of lubricating of claim 16 , wherein the number of block copolymer units ranges from 1 to 15.

19. The method of lubricating of claim 16 , wherein the number of block copolymer units ranges from 1 to 7.

20. The method of lubricating of claim 9 , wherein the base stock has one of a Group II, Group III or Group IV base oil as its major component.

Assignees

• Thompson Lee
• Randles Steven James
• Boyde Stephen
• Gamwell John
• Readman Nicola
• Croda Int Plc

Inventors

• Thompson Lee
• Randles Steven James
• Boyde Stephen
• Gamwell John
• Readman Nicola

Classifications

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10M145/28 Primary

  of alkylene oxides containing 2 carbon atoms only · CPC title

• C10M145/26 Primary

  Polyoxyalkylenes · CPC title

• C10M145/22

  Polyesters · CPC title