Adhesive compositions made from propylene-based polymers and crystalline C2/C3 homopolymer

Patent metadata

Field	Value
Publication number	US-9816015-B2
Application number	US-201514958544-A
Country	US
Kind code	B2
Filing date	Dec 3, 2015
Priority date	Jan 14, 2015
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

The present invention is related to adhesive composition, having a polymer blend comprising a first propylene-based polymer, wherein the first propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin, and a second propylene-based polymer, wherein the second propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin; wherein the second propylene-based polymer is different than the first propylene-based polymer; wherein the polymer blend has a melt viscosity, measured at 190° C. and determined according to ASTM D-3236, of about 1,000 cP to about 5,000 cP; a propylene polymer; and wherein the adhesive composition is substantially free of a functionalized polyolefin, wherein the functionalized polyolefin is selected from at least one of a maleic anhydride-modified polypropylene and a maleic anhydride-modified polypropylene wax.

First claim

We claim:

1. An adhesive composition comprising:
a polymer blend comprising a first propylene-based polymer, wherein the first propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin, and a second propylene-based polymer, wherein the second propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin; wherein the second propylene-based polymer differs from the first propylene-based polymer on the basis of at least one of the properties including a comonomer content, a heat of fusion, a crystallinity, a branching index, a weight average molecular weight, a melt viscosity, or a polydispersity; wherein the polymer blend has a melt viscosity, measured at 190° C. and determined according to ASTM D-3236, of about 1,000 cP to about 5,000 cP, wherein the first propylene-based polymer and second propylene-based polymer each have a crystallinity from about 4% to about 30%; and
an ethylene polymer, wherein the ethylene polymer is a homopolymer of ethylene or a copolymer of ethylene units with from about 0.5 to about 4 wt. % C 3 to C 10 alpha-olefin comonomer derived units.

2. The adhesive composition of claim 1 , wherein the polymer blend is present in the amount of about 25 to about 95 wt. % based on the adhesive composition.

3. The adhesive composition of claim 2 , wherein the polymer blend is present in the amount of about 30 to about 80 wt. % based on the adhesive composition.

4. The adhesive composition of claim 1 , further comprising a functionalized polyolefin, wherein the functionalized polyolefin is selected from at least one of a maleic anhydride-modified polypropylene and a maleic anhydride-modified polypropylene wax, wherein the functionalized polyolefin is present in the amount greater than zero and less than or equal to about 5 wt. % based on the adhesive composition.

5. The adhesive composition of claim 1 , further comprising a third propylene polymer, wherein the third propylene polymer is a homopolymer of propylene or a copolymer of propylene units with from about 0.5 to about 4 wt. % ethylene or C 4 to C 10 alpha-olefin comonomer derived units.

6. The adhesive composition of claim 5 , wherein the third propylene polymer is present in the amount greater than zero and less than or equal to about 10 wt. % based on the adhesive composition.

7. The adhesive composition of claim 1 , further comprising one or more tackifiers.

8. The adhesive composition of claim 1 , further comprising a wax, wherein the wax is present in the amount greater than zero and less than or equal to about 5 wt. % based on the adhesive composition.

9. The adhesive composition of claim 1 , wherein the adhesive composition is substantially free of the wax.

10. An article comprising the adhesive composition of claim 1 .

11. An article of claim 10 , wherein the adhesive composition adheres two substrates, and wherein each substrate comprises at least one of paper, cardboard, plastic film, plastic resin, nonwoven, metal, wood, other natural fiber based material, or combinations thereof.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Kalfus Jan
• Schroeyers Jurgen
• Austin Jennifer J
• Coffey James N
• Schauder Jean-Roch

Classifications

• C08L91/06

  Waxes · CPC title

• B32B27/327

  comprising polyolefins obtained by a metallocene or single-site catalyst · CPC title

• C09J123/142 Primary

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09J123/16 Primary

  Elastomeric} ethylene-propylene or ethylene-propylene-diene copolymers {, e.g. EPR and EPDM rubbers · CPC title