Solid electrolyte and lithium based battery using the same

Patent metadata

Field	Value
Publication number	US-9815914-B2
Application number	US-201213652807-A
Country	US
Kind code	B2
Filing date	Oct 16, 2012
Priority date	Dec 17, 2011
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

A solid electrolyte includes an interpenetrating polymer network and a lithium salt dispersed in the interpenetrating polymer network. The interpenetrating polymer network includes CH 2 —CH 2 O n segments, and is formed by polymerizing a first monomer R 1 —O CH 2 —CH 2 —O n R 2 , a second monomer R 3 —O CH 2 —CH 2 —O m R 4 and an initiator. Each “R 1 ”, “R 2 ” and “R 3 ” includes —C═C— group or —C≡C— group. The “R 4 . . . ” includes an alkyl group or a hydrogen atom. The “m” and “n” are integer. Molecular weights of the first monomer and the second monomer are more than or equal to 100, and less than or equal to 800. The first monomer is less than or equal to 50% of the second monomer by weight. The lithium salt is less than or equal to 10% the second monomer by weight. A lithium based battery using the solid electrolyte is also provided.

First claim

What is claimed is:

1. A solid electrolyte, consisting of:
an interpenetrating polymer network comprising CH 2 —CH 2 —O n segments, the interpenetrating polymer network formed by polymerizing only two monomers consisting of a first monomer R 1 —O CH 2 —CH 2 —O n R 2 and a second monomer R 3 —O CH 2 —CH 2 —O m R 4 , and an initiator, wherein the first monomer is polyethyleneglycol (200) dimethacrylate, “200” represents a molecular weight of the polyethyleneglycol (200) dimethacrylate; and the second monomer is methoxy polyethylene glycol (350) monoacrylate, “350” represents a molecular weight of the methoxy polyethylene glycol (350) monoacrylate; and
a lithium salt dispersed in the interpenetrating polymer network,
wherein each “R 1 ”, “R 2 ” and “R 3 ” comprises —C═C— group or —C≡C— group; the “R 4 ” comprises an alkyl group or a hydrogen atom; the “m” and “n” are integers; molecular weights of the first monomer or the second monomer are more than or equal to 100 and less than or equal to 800; the first monomer is less than or equal to 50% of the second monomer by weight; the lithium salt is less than or equal to 10% of the second monomer by weight; and the solid electrolyte is a plasticizer-free solid electrolyte.

2. The solid electrolyte of claim 1 , wherein a molecular structure of the interpenetrating polymer network comprises an open circle structure.

3. The solid electrolyte of claim 1 , wherein each “R 1 ”, “R 2 ” and “R 3 ” comprises unsaturated chain hydrocarbon groups or unsaturated chain hydrocarbon groups with carbonyl.

4. The solid electrolyte of claim 3 , wherein each “R1”, “R2” and “R3” comprises ethenyl (—CH═CH2), ethynyl (—C≡CH), allyl (—CH═CH—CH3, or —(CH3)C═CH2), propinyl (—C≡C—CH3), or ethenyl ketonic group

5. The solid electrolyte of claim 1 , wherein the lithium salt is selected from a group consisting of lithium perchlorate, lithium hexafluoro-phosphate, lithium tetrafluoro-borate, lithium bis(oxalate)-borate, lithium manganate, lithium iron phosphate, lithium nickelate, lithium cobalt oxide, and combinations thereof.

6. The solid electrolyte of claim 1 , wherein the initiator is a photo-initiator selected from a group consisting of 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl-1-[4-(methylthio)-phenyl]-2-morpholino-propiopheno, and dimethylol propionic acid.

7. The solid electrolyte of claim 1 , wherein the initiator is a thermo-initiator selected from a group consisting of chloride gas, bromine gas, organic peroxide, and azo initiator.

8. The solid electrolyte of claim 1 , wherein the lithium salt is lithium perchlorate.

9. The solid electrolyte of claim 8 , wherein the initiator is dimethylol propionic acid.

10. The solid electrolyte of claim 9 , wherein the polyethyleneglycol (200) dimethacrylate is about 2.5% by weight of the methoxy polyethylene glycol (350) monoacrylate.

11. The solid electrolyte of claim 10 , wherein the lithium perchlorate is about 5% of the methoxy polyethylene glycol (350) monoacrylate by weight.

12. The solid electrolyte of claim 11 , wherein the dimethylol propionic acid is about 0.1% by weight of the methoxy polyethylene glycol (350) monoacrylate.

13. A lithium based battery, comprising:
an anode,
a cathode; and
a solid electrolyte attached between the anode and the cathode, and the solid electrolyte consisting of:
an interpenetrating polymer network comprising CH 2 —CH 2 —O n segments, and the interpenetrating polymer network formed by polymerizing only two monomers consisting of a first monomer R 1 —O CH 2 —CH 2 —O n R 2 and a second monomer R 3 —O CH 2 —CH 2 —O m R 4 , and an initiator, wherein the first monomer is polyethyleneglycol (200) dimethacrylate, “200” represents a molecular weight of the polyethyleneglycol (200) dimethacrylate; and the second monomer is methoxy polyethylene glycol (350) monoacrylate, “350” represents a molecular weight of the methoxy polyethylene glycol (350) monoacrylate; and
a lithium salt dispersed in the interpenetrating polymer network, and the lithium salt is LiClO 4 ;
wherein, each “R 1 ”, “R 2 ” and “R 3 ” comprises —C═C— group or —C≡C— group; the “R 4 ” comprises an alkyl group or a hydrogen atom; the “m” and “n” are integers; the first monomer is about 2.5% of the second monomer by weight, LiClO 4 is about 7.5% of the second monomer by weight, and the solid electrolyte is a plasticizer-free solid electrolyte.

14. The lithium based battery of claim 13 , wherein each “R 1 ”, “R 2 ” and “R 3 ” comprises ethenyl, ethynyl, allyl, propinyl, or ethenyl ketonic group.

15. A solid electrolyte, comprising:
an interpenetrating polymer network comprising CH 2 —CH 2 —O n segments, the interpenetrating polymer network formed by polymerizing only two monomers consisting of a first monomer R 1 —O CH 2 —CH 2 —O n R 2 , and a second monomer R 3 —O CH 2 —CH 2 —O m R 4 , and an initiator; wherein the first monomer is polyethyleneglycol (200) dimethacrylate, “200” represents a molecular weight of the polyethyleneglycol (200) dimethacrylate; and the second monomer is methoxy polyethylene glycol (350) monoacrylate, “350” represents a molecular weight of the methoxy polyethylene glycol (350) monoacrylate; and
a lithium salt dispersed in the interpenetrating polymer network and being in solid solution;
wherein each “R 1 ”, “R 2 ” and “R 3 ” comprises —C═C— group or —C≡C— group; the “R 4 ” comprises an alkyl group or a hydrogen atom; the “m” and “n” are integers; the first monomer is less than or equal to 50% of the second monomer by weight; and the lithium salt is less than or equal to 10% of the second monomer by weight.

16. The solid electrolyte of claim 15 , wherein the first monomer is about 5% of the second monomer by weight.

Assignees

• Wang Li
• He xiang-ming
• Li Jian-Jun
• Gao Jian
• Jiang Chang-Yin
• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Wang Li
• He xiang-ming
• Li Jian-Jun
• Gao Jian
• Jiang Chang-Yin

Classifications

• C08F2/48 Primary

  by ultraviolet or visible light · CPC title

• H01M2300/0082

  Organic polymers · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• C08F220/286

  and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate · CPC title