Method of controlling addition rate of an odor control chemical

Patent metadata

Field	Value
Publication number	US-9815718-B2
Application number	US-201313757487-A
Country	US
Kind code	B2
Filing date	Feb 1, 2013
Priority date	Feb 3, 2012
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

A method of controlling addition rate of an odor control chemical to a wastewater line by adding odor control chemical to the wastewater. The method includes measuring a level of dissolved sulfides in the wastewater line using a sulfide probe placed in said wastewater line, transferring data on the level of dissolved sulfides to a computing unit, determining a required odor control chemical addition rate in said computing unit based on said level of dissolved sulfides, and adding the odor control chemical at said required addition rate. The method allows for accurate on-line control of the level of H 2 S in the wastewater line.

First claim

The invention claimed is:

1. A method of controlling an addition rate of an odor control chemical comprising an iron salt to a wastewater line, comprising:
measuring a level of dissolved sulfides in the wastewater line based on a signal proportional to a true weight of sulfide per volume using a spectrophotometric sulfide probe placed in the wastewater line;
calculating a required odor control chemical addition rate based on a desired ratio of the measured dissolved sulfides to an amount of elemental iron in the iron salt, said required odor control chemical addition rate being at least 7 times the measured level of dissolved sulfides by a weight to weight ratio of the elemental iron in the iron salt to the dissolved sulfide; and
adding in real time with said measuring the odor control chemical comprising the iron salt to the wastewater line at the required odor control chemical addition rate, wherein a time delay between the measuring the level of dissolved sulfides, calculating the required odor control chemical addition rate, and adding the odor control chemical, is less than 60 minutes.

2. A method of controlling an addition rate of an odor control chemical comprising an iron salt to a wastewater line, comprising:
measuring a level of dissolved sulfides in the wastewater line based on a signal proportional to a true weight of sulfide per volume using a spectrophotometric sulfide probe placed in the wastewater line;
calculating a required odor control chemical addition rate based on a desired ratio of the measured dissolved sulfides to an amount of elemental iron in the iron salt, wherein a ratio of the required odor control chemical addition rate to the measured level of dissolved sulfides is progressively increased with decreasing level of dissolved sulfides, the ratio being less than 10:1 with at least a first dissolved sulfide level and more than 80:1 with at least a second dissolved sulfide level smaller than the first dissolved sulfide level; and
adding in real time with said measuring the odor control chemical comprising the iron salt to the wastewater line at the required odor control chemical addition rate, wherein a time delay between the measuring the level of dissolved sulfides, calculating the required odor control chemical addition rate, and adding the odor control chemical, is less than 60 minutes.

3. The method according to claim 1 or claim 2 , wherein a computing unit is adapted to utilize wastewater line retention time when determining the required odor control chemical addition rate.

4. The method according to claim 1 or claim 2 , wherein a computing unit is programmed to take into account sulfide generation downstream of the addition point of the odor control chemical.

5. The method according to claim 1 or claim 2 , wherein the measuring, and calculating are arranged so as to provide an automatic feedback loop, controlled by a computing unit, to drive the adding of the odor control chemical.

6. The method according to claim 1 or claim 2 , wherein said spectrophotometric sulfide probe is capable of providing a signal which is relative to the sulfide weight in the wastewater flow.

7. The method according to claim 1 or claim 2 , wherein the iron salt is selected from the group of Ferrous Chloride, Ferric Chloride, blend of Ferrous/Ferric Chloride, Ferrous Sulfate, Ferric Sulfate, blend of Ferrous/Ferric Sulfate, Ferric Nitrate, or other blend thereof.

8. The method according to claim 1 or claim 2 , further comprising
measuring a pH, biochemical oxygen demand (BOD) level, temperature and/or total flow of wastewater in the wastewater,
taking into account the pH, temperature and/or total flow of wastewater in a computing unit when determining the required addition rate of the odor control chemical.

9. The method according to claim 1 or claim 2 , comprising measuring the level of dissolved sulfides upstream of said addition point of the odor control chemical.

10. The method according to claim 1 or claim 2 , comprising measuring the level of dissolved sulfides at a downstream measurement point that is downstream of said addition point of the odor control chemical.

11. The method according to claim 1 or claim 2 , comprising measuring the level of dissolved sulfides both upstream and downstream of said addition point of the odor control chemical.

12. The method according to claim 1 or claim 2 , wherein the downstream measurement point is 2-10 km downstream of said addition point of the odor control chemical.

13. The method according to claim 1 or claim 2 , wherein the downstream measurement point is 1-20 hours downstream of said addition point of the odor control chemical.

14. The method according to claim 1 or claim 2 , wherein the odor control chemical added into a mixing sleeve in the wastewater line.

15. The method according to claim 1 or claim 2 , wherein the required odor control chemical addition rate is determined so as to bring the level of dissolved sulfides, in particular H 2 S, to a level of less than 5 ppm in the wastewater line.

16. The method according to claim 1 or claim 2 , wherein the required odor control chemical addition rate is determined so as to bring the concentration of dissolved sulfides to a level of less than 0.25 mg/l.

17. The method according to claim 1 or claim 2 , wherein the odor control chemical is FeCl 2 .

Assignees

• Kemira Oyj

Inventors

• Land Greg
• Abinet Roderick
• Soper David

Classifications

• C02F2209/003

  Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process · CPC title

• C02F2209/265

  in the gas phase · CPC title

• C02F2209/06

  pH · CPC title

• C02F2209/40

  Liquid flow rate · CPC title

• C02F1/58 Primary

  by removing specified dissolved compounds (using ion-exchange C02F1/42; softening water C02F5/00) · CPC title