Gas separation device with nanocomposite membrane

Patent metadata

Field	Value
Publication number	US-9815019-B1
Application number	US-201715683225-A
Country	US
Kind code	B1
Filing date	Aug 22, 2017
Priority date	Oct 22, 2015
Publication date	Nov 14, 2017
Grant date	Nov 14, 2017

Abstract

A nanocomposite membrane including α-Al 2 O 3 membrane support, a γ-Al 2 O 3 intermediate layer that is 300-1200 nm thick and coats a surface of the membrane support, and a nanocomposite layer including SiO 2 and Y 2 O 3 that is 25-150 nm thick and coats a surface of the intermediate layer, wherein the nanocomposite layer is porous with an average largest radius micropore of 0.2-0.6 nm. A method of manufacturing the nanocomposite membrane, whereby the membrane support is coated with the γ-Al 2 O 3 , a silica source is hydrolyzed with a mixture of water, an alcohol solvent, and a Y source with a sol-gel technique yield a Si/Y sol-gel, the membrane support is dip coated with the Si/Y sol-gel, and the nanocomposite membrane is calcined. A method of separating a mixture of gas, whereby the mixture of gas is introduced into a permeance cell and fed through the nanocomposite membrane.

First claim

The invention claimed is:

1. A gas separation device, comprising:
a permeance cell having an upstream feed end and a downstream permeate end, and a nanocomposite membrane between the upstream feed end and the downstream permeate end of the permeance cell,
wherein the nanocomposite membrane is configured to separate a first gas having high permeance through the nanocomposite membrane from a second gas having low permeance through the nanocomposite membrane;
wherein the nanocomposite membrane comprises:
a tubular α-Al 2 O 3 membrane support;
an intermediate layer comprising γ-Al 2 O 3 , wherein the intermediate layer is 300-1200 nm thick and coats a surface of the tubular α-Al 2 O 3 membrane support;
a nanocomposite layer comprising SiO 2 and Y 2 O 3 , wherein the nanocomposite layer is 25-150 nm thick and coats a surface of the intermediate layer;
wherein the nanocomposite layer is porous with an average largest radius micropore 0.2-0.6 nm.

2. The gas separation device of claim 1 , wherein the intermediate layer comprises at least two distinct γ-Al 2 O 3 layers, each distinct γ-Al 2 O 3 layer being 150-600 nm thick.

3. The gas separation device of claim 1 , wherein the Y 2 O 3 the form of nanoparticles with a largest dimension of 1-6 nm, the nanocomposite layer is in the form of a SiO 2 matrix, and the Y 2 O 3 nanoparticles are dispersed in or deposited onto the SiO 2 matrix.

4. The gas separation device of claim 3 , wherein the nanocomposite layer is porous with an average mesopore radius of 1-4 nm.

5. The gas separation device of claim 1 , wherein the molar ratio of Si:Y in the nanocomposite membrane is 1:1 to 5:1.

6. The gas separation device of claim 1 , wherein the nanocomposite membrane has a membrane permeance of 1e −8 -1e −6 mol/m 2 ·sec·Pa for the first gas, and a membrane permeance of 1e −10 -1e −9 mol/m 2 ·sec·Pa for the second gas when a mixture of gas comprising the first gas and the second gas is fed through the permeance cell at a temperature of 100-650° C.

7. The gas separation device of claim 6 , wherein the first gas is H 2 , He, or both, and the second gas is N 2 , CO 2 , or both.

8. The gas separation device of claim 1 , wherein the nanocomposite membrane has a membrane permeance of 1e −8 -1e −6 mol/m 2 ·sec·Pa for the first gas, and a membrane permeance of 1e −10 -1e −9 mol/m 2 ·sec·Pa for the second gas when a mixture of gas comprising the first gas, the second gas, and up to 5 wt % of steam relative to the total weight of the mixture of gas is fed through the nanocomposite membrane.

9. A method of separating a mixture of gas comprising a first gas and a second gas, comprising:
introducing the mixture of gas into the upstream feed end of the permeance cell of the gas separation device of claim 1 , wherein the nanocomposite layer of the nanocomposite membrane faces toward the upstream feed end and forms a permeable barrier between the upstream feed end and the downstream permeate end;
applying a vacuum to the downstream permeate end; and
separating the first gas from the second gas by allowing the first gas to pass through the nanocomposite membrane and to the downstream permeate end, and prohibiting the second gas from passing through the nanocomposite membrane.

10. The method of claim 9 , wherein the first gas is H 2 , He, or both, and the second gas is N 2 , CO 2 , or both.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Zahir Md Hasan

Classifications

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title

• B01D2053/221

  Devices · CPC title

• B01D53/228 Primary

  characterised by specific membranes · CPC title

• B01D2256/16

  Hydrogen · CPC title

• B01D69/10

  Supported membranes; Membrane supports · CPC title