Division of a polyarylene ether solution

Patent metadata

Field	Value
Publication number	US-9809685-B2
Application number	US-201414904610-A
Country	US
Kind code	B2
Filing date	Jul 16, 2014
Priority date	Jul 18, 2013
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

Process for producing polyarylene ether beads from a polyarylene ether solution, comprising the steps of
i) dividing the polyarylene ether solution into droplets, ii) transferring the droplets into a precipitation bath to form polyarylene ether beads in the precipitation bath which (A) comprises at least one aprotic solvent (component (1)) and at least one protic solvent (component (2)), (B) has a temperature of 0° C. to T c , where the critical temperature T c in [° C.] can be determined by the numerical equation T c =(99−c)/0.61 in which c is the concentration of component (1) in the precipitation bath in [% by weight] and (C) has component (1) in concentrations of 5% by weight to c c , where the critical concentration c c in [% by weight] can be determined by the numerical equation c c =99−0.61*T in which T is the temperature in the precipitation bath in [° C.], where

the percentages by weight are each based on the sum of the percentages by weight of component (1) and of component (2) in the precipitation bath.

First claim

The invention claimed is:

1. A process for producing polyarylene ether beads from a polyarylene ether solution, comprising:
i) dividing the polyarylene ether solution into droplets; and
ii) transferring the droplets into a precipitation bath to form polyarylene ether beads in the precipitation bath which
(A) comprises an aprotic solvent (component (1)) and a protic solvent (component (2)), and
(B) has a temperature of 0° C. to T c , where the critical temperature T c in [° C.] is determined by the numerical equation T c =(99−c)/0.61 in which c is the concentration of component (1) in the precipitation bath in [% by weight],
wherein the percentages by weight are each based on the sum of the percentages by weight of component (1) and of component (2) in the precipitation bath,
wherein the precipitation bath comprises water or alcohol as component (2),
the polyarylene ether solution has a concentration of 5 to 50% by weight of polyarylene ether in the aprotic solvent, where the percentages by weight are based on the sum of the percentages by weight of the polyarylene ether and the aprotic solvent,
the polyarylene ether solution on division has a temperature of 15 to 250° C.,
the aprotic solvent is selected from the group consisting of dimethyl sulfoxide, dimethylformamide, sulfolane, diphenyl sulfone, 1,2-dichlorobenzene, hexamethylphosphoramide and mixtures thereof, and
wherein, in the polyarylene ether beads formed from the precipitation bath in (ii), a content of particles having a particle size of less than or equal to 1000 μm is less than 8.15% by weight.

2. The process according to claim 1 , wherein the precipitation bath is agitated.

3. The process according to claim 1 , wherein the polyarylene ether solution on division has a temperature of 20 to 120° C.

4. The process according to claim 1 , wherein the polyarylene ether solution after leaving the division apparatus covers a full distance from the exit point to the precipitation bath surface of 0.10 m to 1.20 m.

5. The process according to claim 1 , wherein the division apparatus used comprises a capillary and/or die plate.

6. The process according to claim 5 , wherein the capillary and/or die plate has a diameter of 0.1 to 5.0 mm.

7. The process according to claim 1 , wherein the polyarylene ether solution and the precipitation bath comprise the same aprotic solvent.

8. The process according to claim 1 , wherein the precipitation bath comprises 12 to 50% by weight, of component (1), where the percentages by weight are each based on the sum of the percentages by weight of component (1) and component (2) in the precipitation bath.

9. The process according to claim 1 , wherein a concentration of component (1) in the precipitation bath is from 5 to 70% by weight.

10. The process according to claim 1 , further comprising stirring the precipitation bath when transferring the droplets into the precipitation bath.

11. The process of claim 1 , wherein, in the polyarylene ether beads precipitated from the precipitation bath in (ii), the content of particles having a particle size of less than or equal to 1000 μm is 0.68% by weight or less.

12. The process according to claim 1 , wherein the polyarylene ether beads are individual beads which are not agglomerated.

Assignees

• Basf Se

Inventors

• Erbes Joerg
• Lange Gerhard
• Kortekamp Tobias
• Schneider Cecile

Classifications

• C08J2381/06

  Polysulfones; Polyethersulfones · CPC title

• C08G65/46

  Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title

• C08J2371/10

  from phenols · CPC title

• C08J3/14 Primary

  by precipitation from solutions {(C08J3/122 takes precedence)} · CPC title

• C08G75/23

  Polyethersulfones · CPC title