Fibers for polyethylene nonwoven fabric

Patent metadata

Field	Value
Publication number	US-9803295-B2
Application number	US-57864605-A
Country	US
Kind code	B2
Filing date	Apr 8, 2005
Priority date	Apr 30, 2004
Publication date	Oct 31, 2017
Grant date	Oct 31, 2017

Abstract

The present invention relates to nonwoven webs or fabrics. In particular, the present invention relates to nonwoven webs having superior abrasion resistance and excellent softness characteristics. The nonwoven materials comprise monocomponent fibers having a surface comprising a polyethylene, said nonwoven material having a fuzz/abrasion of less than 0.7 mg/cm 3 . The present invention is also related to fibers having a diameter in a range of from 0.1 to 50 denier, said fibers comprising a polymer blend, wherein the polymer blend comprises: from 40 weight percent to 80 weight percent (by weight of the polymer blend) of a first polymer which is a homogeneous ethylene/α-olefin interpolymer having: a melt index of from about 1 to about 1000 grams/10 minutes, and a density of from 0.870 to 0.950 grams/centimeter 3 , and from 74 to 20 percent by weight of a second polymer which is an ethylene homopolymer or an ethylene/α-olefin interpolymer having a melt index of from about 1 to about 1000 grams/10 minutes, and preferably a density which is at least 0.01 grams/centimeter 3 greater than the density of the first polymer.

First claim

What is claimed is:

1. A nonwoven material comprised of fibers having a surface comprising a polyethylene blend, said fibers being selected from the group consisting of monocomponent fibers, bicomponent fibers or mixtures thereof, said nonwoven material having a fuzz/abrasion less than or equal to 0.0214(BW)+0.2714 mg/cm 2 when the material comprises monocomponent fibers and said nonwoven material having a fuzz/abrasion less than or equal to 0.0071(BW)+0.4071 mg/cm 2 when the material consists of bicomponent fibers, wherein BW is the basis weight of the nonwoven material, wherein the fibers are from 0.1 to 50 denier and wherein the polymer blend comprises:
a. from 40 weight percent to 80 weight percent (by weight of the polymer blend) of a first polymer which is a homogeneous ethylene/α-olefin interpolymer having:
i. a melt index of from about 1 to about 1000 grams/10 minutes,
ii. a density of from 0.915 to 0.950 grams/centimeter 3 , and
iii. a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn≦(I10/I2)−4.63, wherein Mw is the weight average molecular weight and Mn is the number average molecular weight; and

b. from 60 to 20 percent by weight of a second polymer which is an ethylene homopolymer or an ethylene/α-olefin interpolymer having:
i. a melt index of from about 1 to about 1000 grams/10 minutes, and
ii. a density which is at least 0.01 grams/centimeter 3 greater than the density of the first polymer;
wherein the overall melt index of the polymer blend is greater than 18 grams/10 min.

2. The nonwoven material of claim 1 wherein the material comprises monocomponent fibers and has a fuzz/abrasion less than or equal to 0.0214(BW)+0.0714 mg/cm 2 .

3. The nonwoven material of claim 1 wherein the material consists of bicomponent fibers and has a fuzz/abrasion less than or equal to 0.0143(BW)+0.1143 mg/cm 2 .

4. The nonwoven material of claim 1 further characterized as having a basis weight of less than 60 GSM.

5. The nonwoven material of claim 1 further characterized as having a tensile strength of greater than 10 N/5 cm in MD.

6. The nonwoven of claim 1 further characterized as having a consolidation area of less than 25%.

7. The nonwoven of claim 1 having a basis weight from about 20 GSM to about 30 GSM.

8. The nonwoven of claim 1 wherein the nonwoven is a spunbond fabric.

9. The nonwoven material of claim 1 wherein fiber is a spunbonded fiber.

10. The nonwoven material of claim 1 wherein the first polymer has a melt index greater than 10 g/10 minutes.

11. The nonwoven material of claim 1 wherein the first polymer has a density in the range of 0.915 to .925 grams/centimeter 3 .

12. The nonwoven material of claim 1 wherein the second polymer has a density which is at least 0.02 grams/centimeter 3 greater than the density of the first polymer.

13. The nonwoven material of claim 1 wherein the material comprises monocomponent fibers and has a flexural rigidity (mN′cm) in the machine direction of less than or equal to 0.0286(BW)−0.3714 and the nonwoven has a basis weight in the range of 20-27 GSM.

14. The nonwoven material of claim 1 wherein the material comprises bicomponent fibers and has a flexural rigidity (mN·cm) less than or equal to 0.0714(BW)−1.0786.

15. A fiber having a diameter in a range of from 0.1 to 50 denier, said fiber comprising a polymer blend, wherein the polymer blend comprises:
a. from 40 weight percent to 80 weight percent (by weight of the polymer blend) of a first polymer which is a homogeneous ethylene/α-olefin interpolymer having:
i. a melt index of from about 1 to about 1000 grams/10 minutes,
ii. a density of from 0.915 to 0.950 grams/centimeter 3 , and
iii. a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn≦(I10/I2)−4.63, wherein Mw is the weight average molecular weight and Mn is the number average molecular weight; and

b. from 60 to 20 percent by weight of a second polymer which is an ethylene homopolymer or an ethylene/α-olefin interpolymer having:
i. a melt index of from about 1 to about 1000 grams/10 minutes, and
ii. a density which is at least 0.01 grams/centimeter 3 greater than the density of the first polymer;

wherein the overall melt index for the polymer blend is greater than 18 g/10 min.

16. A fiber having a diameter in a range of from 0.1 to 50 denier, said fiber comprising a polymer blend, wherein the polymer blend comprises:
a. from 40 weight percent to 80 weight percent (by weight of the polymer blend) of a first polymer which is a homogeneous ethylene/α-olefin interpolymer having:
i. a melt index of from about 1 to about 1000 grams/10 minutes,
ii. a density of from 0.921 to 0.950 grams/centimeter 3 , and
iii. a molecular weight distribution, Mw/Mn, defined by the equation Mw/Mn≦(I10/I2)−4.63, wherein Mw is the weight average molecular weight and Mn is the number average molecular weight; and

b. from 60 to 20 percent by weight of a second polymer which is an ethylene homopolymer or an ethylene/α-olefin interpolymer having:
i. a melt index of from about 1 to about 1000 grams/10 minutes, and
ii. a density which is at least 0.01 grams/centimeter 3 greater than the density of the first polymer.

17. The fiber of claim 15 or 16 wherein the fiber is a spunbond fiber.

18. The fiber of claim 15 or 16 wherein the first polymer comprises 40-60% of the blend.

19. The fiber of claim 15 or 16 wherein the second polymer is a linear ethylene polymer or a substantially linear ethylene polymer.

20. The fiber of claim 15 or 16 wherein the first polymer has a melt index greater than 10 g/10 minutes.

21. The fiber of claim 15 wherein the first polymer has a density in the range of 0.915 to 0.925 grams/centimeter 3 .

22. The fiber of claim 15 or 16 wherein the second polymer has a density which is at least 0.02 grams/centimeter 3 greater than the density of the first polymer.

23. The fiber of claim 16 wherein the overall polymer blend has a melt index greater than 18 g/10 minutes.

24. A fiber of claim 15 or 16 wherein the fiber is selected from the group consisting of staple fibers and binder fibers.

25. The fiber of claim 24 wherein the fiber is a binder fiber and the binder fiber is in the form a sheath-core bicomponent fiber and the sheath of the fiber comprises the polymer blend.

26. The fiber of claim 25 wherein the sheath further comprises a polyolefin grafted with an unsaturated organic compound containing at least one site of ethylenic unsaturation and at least one carbonyl group.

27. The fiber of claim 26 wherein the unsaturated organic compound is maleic anhydride.

28. The fiber of claim 24 wherein the fiber is a binder fiber and the binder fiber is in an airlaid web, and the fiber comprises 5-35% by weight of the airlaid web.

29. The fiber of claim 24 wherein the fiber is a staple fiber and the stable fiber is in a carded web.

Assignees

• Patel Rajen M
• Claasen Gert
• Liang Wenbin
• Katzer Karin
• Stewart Kenneth B
• Allgeuer Thomas
• Nieto Jesus
• Dow Global Technologies Llc

Inventors

• Patel Rajen M
• Claasen Gert
• Liang Wenbin
• Katzer Karin
• Stewart Kenneth B
• Allgeuer Thomas
• Nieto Jesus

Classifications

• D04H3/007

  Addition polymers · CPC title

• Y10T442/608

  Including strand or fiber material which is of specific structural definition · CPC title

• D04H3/147

  Composite yarns or filaments · CPC title

• D01F6/46 Primary

  of polyolefins · CPC title

• D01F8/06

  with at least one polyolefin as constituent · CPC title