Process to produce soft polypropylene-based nonwovens

Patent metadata

Field	Value
Publication number	US-9303158-B2
Application number	US-201414484383-A
Country	US
Kind code	B2
Filing date	Sep 12, 2014
Priority date	Aug 4, 2008
Publication date	Apr 5, 2016
Grant date	Apr 5, 2016

Abstract

Disclosed herein is a nonwoven fabric comprising within the range of from 50 to 99 wt %, by weight of the composition, of a reactor grade propylene-α-olefin copolymer possessing within the range of from 5 to 35 wt %, by weight of the copolymer, of units derived from one or more of ethylene and/or C 4 to C 12 α-olefins; a melt flow rate (230° C./2.16 kg) within the range of from 500 to 7500 g/10 min; and a weight average molecular weight of less than 200,000; and a second polypropylene having a melting point, T m , of greater than 110° C. and a melt flow rate (230° C./2.16 kg) within the range of from 20 to 7500 g/10 min; wherein the fabric has a CD Elongation value of greater than 50% (measuring the fabric of 35 g/m 2 basis weight). The fabric described herein can be used in structures comprising one or more layers of the fabric described herein, and can include any number of other fabric layers made from other materials.

First claim

The invention claimed is:

1. A method of forming a nonwoven fabric comprising:
(a) reacting propylene with an α-olefin selected from ethylene and C 4 to C 12 α-olefins and a bridged metallocene catalyst composition at a temperature within the range of from 80 to 120° C.;
(b) isolating a reactor grade propylene-α-olefin copolymer possessing a melt flow rate within the range of from 500 to 7500 g/10 min and a weight average molecular weight of less than 200,000;
(c) blending within the range of from 50 to 99 wt %, by weight of the composition, of the reactor grade propylene-α-olefin copolymer and a second polypropylene to form a composition; and
(d) meltblowing the composition to form a nonwoven fabric, wherein the fabric has a CD Elongation value of greater than 50 grams (measuring the fabric of 35 g/m 2 basis weight).

2. The method of claim 1 , further comprising the step of annealing the fibers or fabric at a temperature within the range of from 70 to 130° C. for 1 to 10 seconds.

3. The method of claim 1 , wherein the α-olefin is selected from ethylene, 1-butene, 1-octene and 1-hexene.

4. The method of claim 1 , blending within the range of from 70 to 90 wt %, by weight of the fabric, of the reactor grade propylene-α-olefin copolymer.

5. The method of claim 1 , wherein chain scissioning byproducts are substantially absent from the reactor grade propylene-α-olefin copolymer.

6. The method of claim 1 , wherein the fabric has an MD Elongation value within the range of from 30 to 80%, and a CD Elongation value within the range of from 50 to 90% (measuring the fabric of 35 g/m 2 basis weight in both cases).

7. The method of claim 1 , wherein the fabric has a Hydrostatic Head value of greater than 30 mbar (measuring the fabric of 35 g/m 2 basis weight).

8. The method of claim 1 , wherein the fabric has an Air Permeability value of greater than 40 ft 3 /ft 2 /min (12.2 m 3 /m 2 /min) (measuring the fabric of 35 g/m 2 basis weight).

9. The method of claim 1 , wherein the composition is meltblown at a melt temperature within the range of from 230 to 280° C. and a throughput within the range of from 0.2 to 2.0 g/hole/min.

Assignees

• Exxonmobil Chem Patents Inc

Inventors

• Datta Sudhin
• Thurman Derek W
• Cheng Chia Y
• Peng Kuangyao B

Classifications

• Y10T442/602

  Nonwoven fabric comprises an elastic strand or fiber material · CPC title

• Y10T442/69

  Autogenously bonded nonwoven fabric · CPC title

• D01F6/46

  of polyolefins · CPC title

• D04H1/4291

  Olefin series · CPC title

• D01D5/0985

  by means of a flowing gas (e.g. melt-blowing) · CPC title