Cationic uv-led radiation curable protective varnishes for security documents
US-2024209223-A1 · Jun 27, 2024 · US
US9796864B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9796864-B2 |
| Application number | US-201414471893-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 28, 2014 |
| Priority date | Aug 28, 2014 |
| Publication date | Oct 24, 2017 |
| Grant date | Oct 24, 2017 |
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A solder mask ink composition is disclosed. The solder mask ink composition includes an epoxy resin; a solvent in an amount of at least 20% by weight relative to the total weight of the solder mask ink composition; and optionally a non-ionic surfactant. The ink composition has a viscosity that is less than 1000 cps at a shear rate of 10 s −1 and greater than 30 cps at a shear rate of 495 s −1 and a temperature of 25° C.
Opening claim text (preview).
What is claimed is: 1. A solder mask ink composition, comprising: an epoxy resin of formula 1 where n ranges from about 2 to about 500; a solvent in an amount of at least 20% by weight relative to the total weight of the solder mask ink composition, wherein the solvent is selected from the group consisting of a dialkylene glycol monoalkyl ether solvent, alkoxybenzene, C 5 to C 8 alcohol and a C 2 to C 4 alkanediol, the solvent having a boiling point that is at least 135° C. at atmospheric pressure; and a non-ionic surfactant, the non-ionic surfactant being a polyethylene glycol-block-polypropylene glycol-block-polyethylene glycol, wherein the ink composition has a viscosity that is less than 1000 cps at a shear rate of 10 s −1 and a temperature of 25° C. and greater than 100 cps at a shear rate of 495 s −1 and a temperature of 25° C. 2. The composition of claim 1 , wherein the composition has a viscosity that is less than 800 cps at a shear rate of 10 s −1 . 3. The composition of claim 1 , wherein the composition is an aerosol jet ink composition and can be atomized with a pneumatic atomizer. 4. The composition of claim 1 , wherein the solvent has a vapor pressure of less than 5 mm Hg at 20° C. 5. The composition of claim 1 , wherein the dialkylene glycol monoalkyl ether is selected from the group consisting of a diethylene glycol monoalkyl ether and a dipropylene glycol monoalkyl ether. 6. The composition of claim 1 , wherein the solvent is a diethylene glycol monoalkyl ether of the formula: where R 1 is a C 3 to C 6 alkyl group. 7. The composition of claim 1 , wherein the solvent is butyl carbitol. 8. The composition of claim 1 , wherein the non-ionic surfactant is in an amount of at least 0.01% by weight relative to the total weight of the solder mask ink composition. 9. A solder mask ink composition, comprising: an epoxy resin of formula 1 where n ranges from about 2 to about 500; a solvent in an amount of at least 20% by weight relative to the total weight of the solder mask ink composition, the solvent being a diethylene glycol monoalkyl ether of the formula: where R 1 is a C 3 to C 6 alkyl group, the solvent having a boiling point that is at least 135° C. at atmospheric pressure; and a non-ionic surfactant, wherein the non-ionic surfactant is polyethylene glycol-block-polypropylene glycol-block-polyethylene glycol, wherein the ink composition has a viscosity that is less than 1000 cps at a shear rate of 10 s −1 and a temperature of 25° C. and greater than 100 cps at a shear rate of 495 s −1 and a temperature of 25° C.
containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title
of polyhydric phenols · CPC title
Ethers; Acetals; Ketals; Ortho-esters · CPC title
Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title
Ethylene oxide or propylene oxide copolymers, e.g. pluronics · CPC title
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