Additive manufacturing methods

Patent metadata

Field	Value
Publication number	US-9796137-B2
Application number	US-201514733582-A
Country	US
Kind code	B2
Filing date	Jun 8, 2015
Priority date	Jun 8, 2015
Publication date	Oct 24, 2017
Grant date	Oct 24, 2017

Abstract

An additive manufacturing method includes using hydrogenated titanium in forming an object by additive manufacturing, the object having a first microstructure. The method includes heat treating the hydrogenated titanium and, after completing a shape of the object, dehydrogenating the object. The dehydrogenated object has a second microstructure different from the first microstructure. Also, another additive manufacturing method includes
forming an object containing Ti-6Al-4V, the object having a first microstructure containing columnar structures along a build direction of the additive manufacturing and the object exhibiting mechanical property anisotropy resulting from the columnar structures. After completing a shape of the object, the method includes hydrogenating the Ti-6Al-4V, heat treating the object containing the hydrogenated titanium, and dehydrogenating the heat treated object. The method reduces mechanical property anisotropy and the dehydrogenated object has a second microstructure different from the first microstructure.

First claim

What is claimed is:

1. An additive manufacturing method comprising:
using hydrogenated titanium in forming an object by additive manufacturing, the object having a first microstructure;
heat treating the hydrogenated titanium between about 600 and about 1,000° C.; and
after completing a shape of the object, dehydrogenating the object under vacuum between about 500 and about 1,200° C., the completed shape containing about 0.5 to about 1.2 weight % hydrogen before the dehydrogenating and the dehydrogenated object having a second microstructure exhibiting finer structure compared to the first microstructure such that the dehydrogenated object exhibits a size of alpha colonies, in the smallest dimension of the alpha colonies, of less than about 25 microns and an acicular alpha phase width, in the smallest dimension of the acicular alpha phase in the alpha colonies and in grain boundaries, of less than about 10 microns.

2. The method of claim 1 wherein the use of hydrogenated titanium comprises hydrogenating additive titanium using hydrogen-containing gas while adding titanium to the object.

3. The method of claim 2 wherein the hydrogen-containing gas comprises H 2 .

4. The method of claim 1 wherein the use of hydrogenated titanium comprises using additive manufacturing titanium feedstock containing hydrogen.

5. The method of claim 4 wherein the feedstock comprises titanium hydride powder.

6. The method of claim 4 wherein the feedstock comprises titanium wire containing diffused hydrogen or titanium alloy wire containing diffused hydrogen.

7. The method of claim 1 wherein the dehydrogenating occurs between about 600 and about 1,000° C.

8. The method of claim 1 wherein the heat treating occurs while adding titanium to the object.

9. The method of claim 8 wherein the heat treating comprises melting additive manufacturing titanium feedstock while hydrogenating additive titanium using hydrogen-containing gas and while adding hydrogenated titanium to the object.

10. The method of claim 1 wherein the heat treating occurs after completing the shape of the object and before the dehydrogenating.

11. The method of claim 1 further comprising cooling the object after the heat treating and after completing the shape of the object, but before the dehydrogenating.

12. The method of claim 1 wherein the completed shape comprises about 0.6 to about 1 weight % hydrogen before the dehydrogenating.

13. The method of claim 1 wherein the dehydrogenated object comprises titanium alloyed with aluminum and vanadium.

14. The method of claim 1 wherein the size of alpha colonies is 5 to 25 microns and the acicular alpha phase width is 0.1 to 10 microns.

15. An additive manufacturing method comprising:
using titanium, titanium hydride, aluminum, and vanadium additive manufacturing feedstock in forming an object by additive manufacturing, the object having a first microstructure;
after completing a shape of the object, heat treating the object between about 600 and about 1,000° C.;
cooling the heat treated object; and
dehydrogenating the cooled object under vacuum between about 500 and about 1,200° C., the completed shape containing about 0.5 to about 1.2 weight % hydrogen before the dehydrogenating and the dehydrogenated object having a second microstructure exhibiting finer and more uniform structure compared to the first microstructure such that the dehydrogenated object exhibits a size of alpha colonies, in the smallest dimension of the alpha colonies, of less than about 25 microns and an acicular alpha phase width, in the smallest dimension of the acicular alpha phase in the alpha colonies and in grain boundaries, of less than about 10 microns.

16. The method of claim 15 wherein the dehydrogenating occurs between about 600 and about 1,000° C.

17. The method of claim 15 wherein the completed shape comprises about 0.6 to about 1 weight % hydrogen before the dehydrogenating.

18. The method of claim 15 wherein the dehydrogenated object comprises titanium alloyed with aluminum and vanadium.

19. The method of claim 18 wherein the titanium alloyed with aluminum and vanadium comprises Ti-6Al-4V.

20. An additive manufacturing method comprising:
forming an object containing Ti-6Al-4V by additive manufacturing, the object having a first microstructure containing columnar structures along a build direction of the additive manufacturing and the object exhibiting mechanical property anisotropy resulting from the columnar structures;
after completing a shape of the object, hydrogenating the Ti-6Al-4V using hydrogen-containing gas;
heat treating the object containing the hydrogenated titanium between about 600 and about 1,000° C.; and
dehydrogenating the heat treated object under vacuum between about 500 and about 1,200° C. and reducing mechanical property anisotropy, the completed shape containing about 0.5 to about 1.2 weight % hydrogen before the dehydrogenating and the dehydrogenated object having a second microstructure exhibiting finer structure compared to the first microstructure such that the dehydrogenated object exhibits a size of alpha colonies, in the smallest dimension of the alpha colonies, of less than about 25 microns and an acicular alpha phase width, in the smallest dimension of the acicular alpha phase in the alpha colonies and in grain boundaries, of less than about 10 microns.

Assignees

• Boeing Co

Inventors

• Zhang Hao
• Quarberg Ryan P

Classifications

• B22F3/1007 Primary

  Atmosphere (B22F3/1021 takes precedence) · CPC title

• B22F10/64

  by thermal means (control of energy beam parameters for post heating B22F10/364) · CPC title

• B22F10/25

  Direct deposition of metal particles, e.g. direct metal deposition [DMD] or laser engineered net shaping [LENS] · CPC title

• B22F10/38

  to achieve specific product aspects, e.g. surface smoothness, density, porosity or hollow structures · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title