Process for the production of an optically selective coating of a substrate for high temperature receiver solar devices and relative material obtained

Patent metadata

Field	Value
Publication number	US-9786799-B2
Application number	US-201314427863-A
Country	US
Kind code	B2
Filing date	Sep 18, 2013
Priority date	Sep 21, 2012
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A process for the production of an optically selective coating of a receiver substrate of a suitable material for solar receiver devices particularly suitable for operating at high temperatures, more specifically for receiver tubes of linear parabolic trough, which comprises: deposition of a layer reflecting infrared radiation consisting of a high-melting metal on a heated receiver substrate of a suitable material; annealing under the same temperature and pressure conditions as the deposition of the reflecting layer; deposition on the high-melting metal of one or more layers of metal-ceramic composite materials (CERMET), wherein the metal is W and the ceramic matrix is YPSZ (“Yttria-Partially Stabilized Zirconia”); deposition on the cermet of an antireflection layer; annealing under the same temperature and pressure conditions as the depositions of the cermet and antireflection layers.

First claim

The invention claimed is:

1. A process for the production of an optically selective coating of a receiver substrate of suitable material for solar receivers suitable for operating at high temperatures comprising:
deposition of a layer reflecting infrared radiation including W metal prevalently in the alpha phase on said heated receiver substrate at a temperature from 400° C. to 600° C.;
annealing under the same temperature and pressure conditions as the deposition of the reflecting layer;
deposition on the W metal prevalently in the alpha phase of one or more layers of metal-ceramic composite materials (CERMET), wherein the ceramic matrix includes YPSZ (“Yttria-Partially Stabilized Zirconia”);
deposition on the cermet of an antireflection layer;
annealing under the same temperature and pressure conditions as the depositions of the cermet and antireflection layers;
wherein the reflecting layer of W is prepared without any previous deposition of a matching layer.

2. The process according to claim 1 , wherein said solar receivers are composed of receiver tubes of linear parabolic troughs.

3. The process according to claim 1 , wherein the antireflection layer includes YPSZ.

4. The process according to claim 1 , wherein the depositions of the reflecting layer, the cermet layer and antireflection layer are carried out by means of simultaneous DC/RF sputtering in a single chamber with movement of the substrate or receiver tube.

5. The process according to claim 1 , wherein the substrate or receiver tube includes stainless steel.

6. The process according to claim 5 , wherein the substrate or receiver tube is polished by a suitable abrasive paste with dimensions not greater than 0.20 microns.

7. The process according to claim 3 , wherein the infrared-reflecting layer including W is prepared by means of the following steps in sequence:
initial vacuum level in the chamber sufficient for preventing oxygen contaminations;
pre-sputtering of the W target;
heating of the substrate;
sputtering and low-velocity oscillation of the substrate above the source of W;
annealing at the same deposition temperature and at the same sputtering pressure.

8. The process according to claim 1 , wherein the layer of W is prepared according to the following conditions:
the initial vacuum level in the chamber at a pressure ranging from 1×10 −6 mbar to 5×10 −6 mbar;
heating of the substrate or receiver tube from 400° C. to 600° C.;
sputtering at a pressure ranging from 2.7×10 −2 mbar to 3.2×10 −2 mbar (Ar 6N), contemporaneously making the substrate oscillate above the DC source at low speed ranging from 0.1 cm/s to 1 cm/s;
annealing for a time ranging from 0.5 h to 2 h at the same temperature and pressure as the sputtering;
so as to obtain the layer of W, prevalently in alpha phase, with a thickness ranging from 200 nm to 900 nm.

9. The process according to claim 1 , wherein the layer of cermet deposited includes W dispersed on a nanometric scale, in an amount ranging from 30 to 70% by volume, in a matrix of YPSZ, in an amount ranging from 70% to 30% by volume.

10. The process according to claim 9 , wherein the layer of cermet is prepared by steps including the following steps in sequence:
pre-sputtering of the YPSZ target;
heating of the substrate or receiver tube;
sputtering and oscillation of the substrate so as to expose it alternatingly to the W and YPSZ sources.

11. The process according to claim 1 , wherein a second layer of cermet including W dispersed on a nanometric scale is deposited, in an amount ranging from 20 to 60% by volume, in a matrix of YPSZ, in an amount ranging from 80 to 40% by volume, the volume percentage of W in said second layer being lower with respect to the layer of cermet previously deposited.

12. The process according to claim 11 , wherein the second layer of cermet is prepared by means of the following steps in sequence:
heating of the substrate or receiver tube;
sputtering and oscillation of the substrate so as to expose it alternatingly to the W and YPSZ sources.

13. The process according to claim 10 , wherein the layer of cermet is prepared by carrying out the pre-sputtering of the YPSZ target at a low power, and for a short time.

14. The process according to claim 10 , wherein the layer of cermet or a second layer of cermet is prepared according to the following conditions:
heating of the substrate or receiver tube from 400° C. to 600° C.;
sputtering at a pressure ranging from 2.7×10 −2 mbar to 3.2×10 −2 mbar (Ar 6N), contemporaneously making the substrate oscillate so as to expose it alternately to the DC and RF sources at a high velocity ranging from 5 cm/s to 15 cm/s.

15. The process according to claim 1 , wherein said antireflection layer (ARL) including YPSZ is deposited on the layer of cermet or on a second layer of cermet.

16. The process according to claim 15 , wherein the ARL is prepared by means of the following steps in sequence:
heating of the substrate or receiver tube;
sputtering and oscillation of the substrate at a low velocity above the RF source of YPSZ;
annealing at the deposition temperature and at the same sputtering pressure for a time ranging from 0.2 h to 1 h.

17. The process according to claim 16 , wherein the ARL is prepared assuring the following conditions:
heating of the substrate or receiver tube within the range of 400° C.-600° C. wherein the substrate or receiver tube includes stainless steel;
sputtering at a pressure ranging from 2.7×10 −2 mbar to 3.2×10 −2 mbar (Ar 6N), contemporaneously making the substrate oscillate above the RF source at a low velocity ranging from 0.1 cm/s to 1 cm/s, or rotating and simultaneously translating the receiver tube, maintaining the YPSZ source fixed;
annealing for a time ranging from 0.2 h to 1 h, at the same deposition temperature and at the same sputtering pressure.

18. An optically selective multilayer coating material of receiver substrates obtained by a method according to claim 1 comprising:
an upper layer of antireflection material;
a lower layer of material reflecting in the infrared including W prevalently in the alpha phase;
at least one intermediate layer of metal-ceramic composite material (CERMET), wherein the metal includes W and the ceramic matrix includes YPSZ (“Yttria-Partially Stabilized Zirconia”),
wherein the lower layer of W is prepared without any previous deposition of a matching layer.

19. The material according to claim 18 , wherein the antireflection material includes YPSZ, the W in the cermet ranging from 20% to 70% by volume and the ceramic YPSZ matrix ranging from 80% to 30% by volume.

20. The material according to claim 18 , characterized in that it has α absorptance and ε H hemispherical emissivity values, at a temperature of 550° C., of 0.893 and 0.087, respectively.

Assignees

• Eni Spa

Inventors

• Spano′ Guido
• Lazzari Carla
• Marella Marcello

Classifications

• C23C14/34

  Sputtering · CPC title

• C23C28/322

  only coatings of metal elements only · CPC title

• C23C14/0688 Primary

  Cermets, e.g. mixtures of metal and one or more of carbides, nitrides, oxides or borides · CPC title

• F24S20/20

  Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants · CPC title

• C23C28/3455

  with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer · CPC title