System and method for purification of electrolytic salt

Patent metadata

Field	Value
Publication number	US-9783898-B2
Application number	US-201514933274-A
Country	US
Kind code	B2
Filing date	Nov 5, 2015
Priority date	Jun 14, 2013
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

Methods and systems for removing impurities from an electrolytic salt are disclosed. After removal of impurities from the salt, the salt can be subjected to electrorefining to produce high-purity materials, for example silicon. Impurities are removed from the salt using a system that includes a first working electrode, a counter electrode, and at least one reference electrode. A second working electrode can also be utilized. The salt may be utilized in an electrorefining system, for example a system operated in a single phase or multiple phase operation to produce high-purity materials, such as solar-grade silicon.

First claim

What is claimed is:

1. A method for purifying a salt having multiple impurities, the method comprising:
providing a system comprising a first working electrode, a counter electrode, a reference electrode, and a system control, wherein the first working electrode, the counter electrode, and the reference electrode are electrically coupled to the salt;
setting, via the system control, a desired electrical potential between the reference electrode and the first working electrode;
applying sufficient electrical energy to the system to cause a negatively-charged first targeted impurity within the salt to deposit on the surface of the first working electrode;
removing the first working electrode from the salt;
electrically coupling a second working electrode to the salt;
setting, via the system control, a desired electrical potential between the reference electrode and the second working electrode; and
applying sufficient electrical energy to the system to cause a positively-charged second targeted impurity within the salt to deposit on the surface of the second working electrode.

2. The method of claim 1 , wherein the salt comprises LiCl.

3. The method of claim 1 , wherein the applying sufficient electrical energy to the system to cause the negatively-charged first targeted impurity within the salt to deposit on the surface of the first working electrode comprises applying a positive voltage to the first working electrode by the system control.

4. The method of claim 1 , wherein the applying sufficient electrical energy to the system to cause the positively-charged second targeted impurity within the salt to deposit on the surface of the second working electrode comprises applying a negative voltage to the second working electrode by the system control.

5. A method, comprising:
in a vessel, removing a positively-charged impurity from a salt via operation of a purification system comprising a working electrode, a counter electrode, and a reference electrode by applying a sufficient electrical energy to the system between the reference electrode and the working electrode to cause the positively-charged impurity to deposit on the working electrode, wherein the salt comprises a non-oxygen anion and a metal cation having a more negative standard reduction potential than silicon;
replacing the working electrode with a second working electrode;
in the vessel, removing a negatively-charged impurity from the salt via the purification system by applying a sufficient electrical energy between the reference electrode and the second working electrode to cause the negatively-charged impurity to deposit on the second working electrode; and
in the vessel, electrorefining silicon using the salt as an electrolyte.

6. The method of claim 5 , wherein the salt comprises LiCl.

7. The method of claim 5 , wherein the silicon produced by the step of electrorefining comprises solar-grade silicon.

8. The method of claim 5 , wherein a system control provides an electrical potential between the reference electrode and the second working electrode operated as an anode.

9. The method of claim 5 , wherein a control system provides an electrical potential between the reference electrode and the working electrode operated as a cathode.

Assignees

• Tao Meng
• Han Xiaofei
• Univ Arizona State

Inventors

• Tao Meng
• Han Xiaofei

Classifications

• C25B1/006

  Chemistry & Metallurgy · mapped topic

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25B11/0421

  Chemistry & Metallurgy · mapped topic

• C25B1/26

  Chlorine; Compounds thereof (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• C25B1/14 Primary

  Alkali metal compounds · CPC title