Compositions comprising C5 and C6 oligosaccharides

Patent metadata

Field	Value
Publication number	US-9783860-B2
Application number	US-201514661000-A
Country	US
Kind code	B2
Filing date	Mar 18, 2015
Priority date	Dec 30, 2011
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

Compositions comprising C5 and C6 saccharides of varying degrees of polymerization and low levels of undesirable impurities, such as compounds containing sulfur, nitrogen, or metals, are disclosed.

First claim

What is claimed is:

1. A composition, comprising: a water-soluble C6 oligosaccharide hydrolysate; a water-soluble C6 monosaccharide hydrolysate; and impurities wherein said impurities comprise a total amount by weight, based on total weight of said composition, of less than about 5250 ppm of elements Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Ma, Mn, Mo, Na, Ni, P, Pb, S, Sb, Se, Si, Sn, Sr, Ti, Tl, V, and Zn, when said composition is measured for all of said elements:
wherein said water-soluble C6 monosaccharide hydrolysate is present at a level of about 5% by weight to about 20% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition; and
wherein said water-soluble C6 oligosaccharide hydrolysate comprises: about 10% by weight to about 25% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 pentasaccharides.

2. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate comprises a C6 oligosaccharide having a degree of polymerization of about 2 to about 15.

3. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate comprises a C6 oligosaccharide having a degree of polymerization of about 2 to about 13.

4. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate comprises a C6 oligosaccharide having a degree of polymerization of about 2 to about 10.

5. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate comprises a C6 oligosaccharide having a degree of polymerization of about 2 to about 6.

6. The composition of claim 1 , wherein said water-soluble C6 monosaccharide hydrolysate is glucose, galactose, mannose, fructose, or a mixture thereof.

7. The composition of claim 1 , wherein aluminum, if present, comprises less than about 10 ppm by weight of the composition.

8. The composition of claim 1 , wherein calcium, if present, comprises less than about 3000 ppm by weight of the composition.

9. The composition of claim 1 , wherein iron, if present, comprises less than about 350 ppm by weight of the composition.

10. The composition of claim 1 , wherein sulfur, if present, comprises less than about 1000 ppm by weight of the composition.

11. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate is processed from lignocellulosic biomass using supercritical, subcritical, or near critical fluid extraction, or a combination thereof.

12. The composition of claim 1 , wherein levels of said elements are measured by inductively coupled plasma emission spectroscopy.

13. The composition of claim 1 , wherein the ratio of the total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate to said elements is greater than about 45:1.

14. The composition of claim 1 , wherein nitrogen, if present, comprises: less than about 1500 mg of nitrogen per kg of total weight of water-soluble C6 saccharides.

15. The composition of claim 1 , wherein the weight ratio of collective mass of hydrogen and nitrogen to mass of carbon present in said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate is less than about 0.14.

16. The composition of claim 1 , wherein aluminum, calcium, iron and sulfur, if present, comprise, based on total weight of said composition, less than about 10 ppm by weight of aluminum; less than about 3000 ppm by weight of calcium; less than about 350 ppm by weight of iron; and less than about 1000 ppm by weight of sulfur.

17. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate further comprises:
about 10% by weight to about 25% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 disaccharides;
about 10% by weight to about 25% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 trisaccharides;
about 10% by weight to about 25% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of C6 tetrasaccharides; and
about 10% by weight to about 50% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition, of water-soluble C6 saccharides having a degree of polymerization of at least about 6.

18. The composition of claim 17 , wherein said C6 monosaccharides are present at a level of about 7.5% by weight to about 20% by weight, based on total weight of said water-soluble C6 oligosaccharide hydrolysate and said water-soluble C6 monosaccharide hydrolysate in said composition.

19. The composition of claim 1 , further comprising: about 10% by weight to about 25% by weight, based on total weight of water-soluble C6 saccharides present in said composition, of C6 disaccharides.

20. The composition of claim 1 , further comprising: about 10% by weight to about 25% by weight, based on total weight of water-soluble C6 saccharides present in said composition, of C6 trisaccharides.

21. The composition of claim 1 , further comprising: about 10% by weight to about 25% by weight, based on total weight of water-soluble C6 saccharides present in said composition, of C6 tetrasaccharides.

22. The composition of claim 1 , wherein said C6 pentasaccharides are present at a level of about 10% by weight to about 20% by weight, based on total weight of water-soluble C6 saccharides present in said composition.

23. The composition of claim 1 , further comprising: about 10% by weight to about 50% by weight, based on total weight of water-soluble C6 saccharides present in said composition, of water-soluble C6 saccharides having a degree of polymerization of at least about 6.

24. The composition of claim 1 , wherein said C6 monosaccharides are present at a level of about 7.5% by weight to about 20% by weight, based on total weight of water-soluble C6 saccharides present in said composition.

25. The composition of claim 1 , further comprising water.

26. The composition of claim 1 , wherein said water-soluble C6 oligosaccharide hydrolysate is present at a level of about 80% by weight to about 95% by weight, based on total weight of water-soluble C6 saccharides present in said composition; and wherein said water-soluble C6 oligosaccharides have a degree of polymerization of about 2 to about 15.

27. The composition of claim 26 , wherein said water-soluble C6 oligosaccharide hydrolysate is present at a level of about 80% by weight to about 92.5% by weight, based on total weight of water-soluble C6 saccharides present in said composition.

28. The composition of claim 26 , wherein said C6 monosaccharide hydrolysate is present at a level of about 7.5% by weight to about 20% by weight, based on total weight of water-soluble C6 saccharides present in said composition.

29. The composition of claim 26 , further comprising water.

30. The composition of claim 1 , w

Assignees

• Renmatix Inc

Inventors

• Floyd Daniel Clay
• Kadam Kiran
• Kilambi Srinivas

Classifications

• C07H3/06

  Oligosaccharides, i.e. having three to five saccharide radicals attached to each other by glycosidic linkages · CPC title

• C13K1/04

  Purifying · CPC title

• C13B50/00

  Sugar products, e.g. powdered, lump or liquid sugar; Working-up of sugar (C13B40/00, C13B45/00 take precedence; confectionery A23G3/00) · CPC title

• C13K1/02 Primary

  obtained by saccharification of cellulosic materials (manufacture of fodder A23K10/32) · CPC title

• C13K13/007

  Separation of sugars provided for in subclass C13K (C13K3/00 takes precedence) · CPC title