Recyclate verification

Patent metadata

Field	Value
Publication number	US-9783645-B2
Application number	US-201715467995-A
Country	US
Kind code	B2
Filing date	Mar 23, 2017
Priority date	Jan 14, 2015
Publication date	Oct 10, 2017
Grant date	Oct 10, 2017

Abstract

A composition for recyclate verification is produced by adding a predetermined quantity of one or more verification compounds to a base resin. Each of the verification compounds is thermally stable over a range of temperatures that includes the maximum processing temperature of the base resin but is less than the degradation temperature of the base resin. In some embodiments, a thermoplastic material provided for verification as a recyclate is analyzed to detect the presence (and, optionally, the loading level) of one or more verification compounds associated with the base resin of the thermoplastic material. In some embodiments, a computer-implemented method for recyclate verification is performed using a computer program product. In some embodiments, a thermoplastic material verified as a recyclate is heated to drive off the verification compound(s), then a known quantity of the verification compound(s) is added to the recyclate, which is then blended with virgin base resin material.

First claim

What is claimed is:

1. A method for producing a composition for recyclate verification, comprising:
providing a base resin, wherein the base resin is capable of being injection molded at a maximum processing temperature;
adding one or more verification compounds in a predetermined quantity, tailored to the base resin, wherein each of the verification compounds is thermally stable over a range of temperatures that includes the maximum processing temperature of the base resin but is less than a degradation temperature of the base resin,
wherein adding one or more verification compounds in a predetermined quantity includes accessing a data file, in a memory connected to a processor, that for each of a plurality of base resins, lists one or more verification compounds and one or more loading levels associated with that particular base resin; and
wherein each of the one or more verification compounds added to the base resin is determined based on the one or more verification compounds listed in the data file as being associated with that particular base resin, and wherein the predetermined quantity of each of the one or more verification compounds is based on the one or more loading levels listed in the data file as being associated with that particular base resin.

2. The method as recited in claim 1 , wherein the composition comprises a set of two or more of the verification compounds.

3. The method as recited in claim 1 , wherein the base resin is a blend of polycarbonate (PC) and acrylonitrile butadiene styrene (ABS), and wherein the one or more verification compounds comprises at least one long chain, mono- or di-carboxylic acid.

4. The method as recited in claim 3 , wherein the at least one long chain, mono- or di-carboxylic acid is selected from the group consisting of azelaic acid and sebacic acid.

5. The method as recited in claim 1 , wherein the base resin is acrylonitrile butadiene styrene (ABS), and wherein the one or more verification compounds comprises 2,5-dihydroxybenzoic acid.

6. The method as recited in claim 1 , wherein adding one or more verification compounds in a predetermined quantity to the base resin includes accessing a data file that, for each of a plurality of base resins, lists one or more verification compounds and one or more loading level ranges associated with that particular base resin.

7. The method as recited in claim 6 , wherein each of the one or more loading level ranges listed in the data file provides a tolerance above and below a nominal loading level for a respective one of the one or more verification compounds.

8. The method as recited in claim 7 , wherein each of the one or more verification compounds added to the base resin is determined based on the one or more verification compounds listed in the data file as being associated with the base resin, and wherein the predetermined quantity of each of the one or more verification compounds added to the base resin is based on the one or more loading level ranges listed in the data file as being associated with the base resin to achieve the nominal loading level for that particular verification compound.

9. A method for producing a composition for recyclate verification, comprising:
providing a base resin, wherein the base resin is capable of being injection molded at a maximum processing temperature;
determining one or more verification compounds associated with the base resin and a loading level range for each of the one or more verification compounds, wherein each of the verification compounds is thermally stable over a range of temperatures that includes the maximum processing temperature of the base resin but is less than a degradation temperature of the base resin, wherein determining one or more verification compounds associated with the base resin and a loading level range for each of the one or more verification compounds includes accessing a data file, in a memory connected to a processor, that for each of a plurality of base resins, lists one or more verification compounds and one or more loading level ranges associated with that particular base resin;
adding the one or more verification compounds associated with the base resin in a predetermined quantity, tailored to the base resin to achieve a nominal loading level for each of the one or more verification compounds that is within the loading level range for each of the one or more verification compounds.

10. The method as recited in claim 9 , wherein the composition comprises a set of two or more of the verification compounds.

11. The method as recited in claim 9 , wherein the base resin is a blend of polycarbonate (PC) and acrylonitrile butadiene styrene (ABS), and wherein the one or more verification compounds comprises at least one long chain, mono- or di-carboxylic acid.

12. The method as recited in claim 11 , wherein the at least one long chain, mono- or di-carboxylic acid is selected from the group consisting of azelaic acid and sebacic acid.

13. The method as recited in claim 9 , wherein the base resin is acrylonitrile butadiene styrene (ABS), and wherein the one or more verification compounds comprises 2,5-dihydroxybenzoic acid.

Assignees

• IBM

Inventors

• Hebig Travis R
• Kuczynski Joseph
• Nickel Steven R

Classifications

• G01N33/442

  Resins; Plastics · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• C08J2300/30

  Polymeric waste or recycled polymer · CPC title

• C08J11/04

  of polymers · CPC title

• C08J2400/00

  Characterised by the use of unspecified polymers · CPC title