Recyclate verification

Patent metadata

Field	Value
Publication number	US-2016200894-A1
Application number	US-201514596324-A
Country	US
Kind code	A1
Filing date	Jan 14, 2015
Priority date	Jan 14, 2015
Publication date	Jul 14, 2016
Grant date	—

Abstract

A composition for recyclate verification is produced by adding a predetermined quantity of one or more verification compounds to a base resin. Each of the verification compounds is thermally stable over a range of temperatures that includes the maximum processing temperature of the base resin but is less than the degradation temperature of the base resin. In some embodiments, a thermoplastic material provided for verification as a recyclate is analyzed to detect the presence (and, optionally, the loading level) of one or more verification compounds associated with the base resin of the thermoplastic material. In some embodiments, a computer-implemented method for recyclate verification is performed using a computer program product. In some embodiments, a thermoplastic material verified as a recyclate is heated to drive off the verification compound(s), then a known quantity of the verification compound(s) is added to the recyclate, which is then blended with virgin base resin material.

First claim

1 - 5 . (canceled)

6 . A method for producing a composition for recyclate verification, comprising:
providing a base resin, wherein the base resin is capable of being injection molded at a maximum processing temperature; adding one or more verification compounds in a predetermined quantity to the base resin, wherein each of the verification compounds is thermally stable over a range of temperatures that includes the maximum processing temperature of the base resin but is less than a degradation temperature of the base resin.

7 . The method as recited in claim 6 , wherein the composition comprises a set of two or more of the verification compounds.

8 . The method as recited in claim 6 , wherein the base resin is a blend of polycarbonate (PC) and acrylonitrile butadiene styrene (ABS), and wherein the one or more verification compounds comprises at least one long chain, mono- or di-carboxylic acid.

9 . The method as recited in claim 8 , wherein the at least one long chain, mono- or di-carboxylic acid is selected from the group consisting of azelaic acid and sebacic acid.

10 . The method as recited in claim 6 , wherein the base resin is acrylonitrile butadiene styrene (ABS), and wherein the one or more verification compounds comprises 2,5-dihydroxybenzoic acid.

11 . A method for verifying recyclate, comprising:
providing a thermoplastic material for verification as a recyclate, wherein the thermoplastic material comprises a base resin; identifying the base resin of the thermoplastic material; determining a verification compound associated with the identified base resin; analyzing the thermoplastic material to detect the presence of the verification compound.

12 . The method as recited in claim 11 , further comprising:
reporting the thermoplastic material as a verified recyclate if the presence of the verification compound is detected.

13 . The method as recited in claim 12 , further comprising:
driving off the verification compound from the verified recyclate thermoplastic material; adding a known quantity of the verification compound to the verified recyclate thermoplastic material; blending the virgin base resin material and the verified recyclate thermoplastic material having the known quantity of the verification compound added thereto.

14 . The method as recited in claim 12 , wherein determining a verification compound associated with the identified base resin comprises determining a plurality of verification compounds associated with the identified base resin, wherein analyzing the thermoplastic material to detect the presence of the verification compound comprises analyzing the thermoplastic material to detect the presence of each of the plurality of verification compounds, and wherein reporting the thermoplastic material as a verified recyclate if the presence of the verification compound is detected comprises detecting the presence of each of the plurality of verification compounds in the thermoplastic material.

15 . The method as recited in claim 14 , further comprising:
driving off each of the plurality of verification compounds from the verified recyclate thermoplastic material; adding a known quantity of each of the plurality of verification compounds to the verified recyclate thermoplastic material; blending the virgin base resin material and the verified recyclate thermoplastic material having the known quantity of each of the verification compounds added thereto.

16 . The method as recited in claim 11 , wherein analyzing the thermoplastic material to detect the presence of the verification compound comprises analyzing the thermoplastic material to measure a loading level of the verification compound in the thermoplastic material, the method further comprising:
determining whether the loading level of the verification compound in the thermoplastic material is within a loading level range; reporting the thermoplastic material as a verified recyclate if the measured loading level of the verification compound in the thermoplastic material is within the loading level range.

17 . The method as recited in claim 16 , further comprising:
driving off the verification compound from the verified recyclate thermoplastic material; adding a known quantity of the verification compound to the verified recyclate thermoplastic material; blending the virgin base resin material and the verified recyclate thermoplastic material having the known quantity of the verification compound added thereto.

18 . The method as recited in claim 16 , wherein determining a verification compound associated with the identified base resin comprises determining a plurality of verification compounds associated with the identified base resin, wherein analyzing the thermoplastic material to measure a loading level of the verification compound in the thermoplastic material comprises analyzing the thermoplastic material to measure a loading level of each of the plurality of verification compounds in the thermoplastic material, wherein determining whether the measured loading level of the verification compound in the thermoplastic material is within a loading level range comprises determining whether the measured loading level of each of the plurality of verification compounds in the thermoplastic material is within a corresponding loading level range, and wherein reporting the thermoplastic material as a verified recyclate if the measured loading level of the verification compound in the thermoplastic material is within the loading level range comprises determining if the measured loading level of each of the plurality of verification compounds in the thermoplastic material is within the corresponding loading level range.

19 . The method as recited in claim 18 , further comprising:
driving off each of the plurality of verification compounds from the verified recyclate thermoplastic material; adding a known quantity of each of the plurality of verification compounds to the verified recyclate thermoplastic material; blending the virgin base resin material and the verified recyclate thermoplastic material having the known quantity of each of the verification compounds added thereto.

20 . A computer program product comprising:
a plurality of executable instructions provided on computer readable media, wherein the executable instructions, when executed by at least one processor in a digital computing device, cause the digital computing device to perform the method as recited in claim 11 .

21 . A method for verifying recyclate, comprising:
providing a thermoplastic material for verification as a recyclate, wherein the thermoplastic material comprises a base resin; identifying the base resin of the thermoplastic material; determining a verification compound associated with the identified base resin; analyzing the thermoplastic material to detect the presence of the verification compound, wherein analyzing the thermoplastic material to detect the presence of the verification compound comprises analyzing the thermoplastic material to measure a loading level of the verification compound in the thermoplastic material; determining whether the loading level of the verification compound in the thermoplastic material is within a loading level range; reporting the thermoplastic material as a verified recyclate if the measured loading level of the verification compound in the thermoplastic material is within the loading level range.

22 . A computer program product comprising:
a plurality of executable instructions provided on computer readable media, wh

Assignees

• IBM

Inventors

• Hebig Travis R
• Kuczynski Joseph
• Nickel Steven R

Classifications

• C08K5/092 Primary

  Polycarboxylic acids · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• G01N33/442

  Resins; Plastics · CPC title

• C08J2447/00

  Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers (C08J2445/00 takes precedence; of conjugated diene rubbers C08J2409/00 - C08J2421/00) · CPC title

• C08J3/203

  Solid polymers with solid and/or liquid additives · CPC title