Catalyst recovery system, hydrocarbon synthesis reaction apparatus, hydrocarbon synthesis reaction system, and catalyst recovery process

Patent metadata

Field	Value
Publication number	US-9776160-B2
Application number	US-201213978772-A
Country	US
Kind code	B2
Filing date	Jan 13, 2012
Priority date	Jan 13, 2011
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

A catalyst recovery system that includes a concentrated slurry production unit that concentrates a slurry extracted from a reactor main unit and continuously produces a concentrated slurry, a first discharge unit that discharges the concentrated slurry from the concentrated slurry production unit, a solidified slurry production unit that cools the concentrated slurry discharged from the concentrated slurry production unit, thereby solidifying the liquid medium within the concentrated slurry and producing a solidified slurry, and a recovery mechanism that recovers the solidified slurry from the solidified slurry production unit.

First claim

What is claimed is:

1. A catalyst recovery system for recovering catalyst particles incorporated within a slurry contained inside a reactor main unit, the catalyst recovery system comprising:
a concentrated slurry production unit that concentrates the slurry extracted from the reactor main unit and continuously produces a concentrated slurry,
a first discharge unit that discharges the concentrated slurry from the concentrated slurry production unit,
a solidified slurry production unit that cools the concentrated slurry discharged from the concentrated slurry production unit, thereby solidifying a liquid medium within the concentrated slurry and producing a solidified slurry, and
a recovery mechanism that recovers the solidified slurry from the solidified slurry production unit.

2. The catalyst recovery system according to claim 1 , wherein
the concentrated slurry production unit comprises a settling tank, and
the slurry inside the settling tank is concentrated by the catalyst particles settling within a lower portion of the liquid medium, and is then separated into the concentrated slurry and a clarified slurry having a lower catalyst particle content than the concentrated slurry.

3. The catalyst recovery system according to claim 2 , wherein
the settling tank comprises:
a supply port through which the slurry is supplied,
a discharge port to which the first discharge unit is connected, and
an extraction port through which the clarified slurry is extracted, and
inside the settling tank there are provided:

a partitioning wall, which partitions the inside of the settling tank into a lower chamber, to which the supply port and the discharge port are connected and which is located within a lower portion of the settling tank, and an upper chamber to which the extraction port is connected and which is located within an upper portion of the settling tank, and
a connection passage that passes through the partitioning wall and interconnects the lower chamber and the upper chamber.

4. The catalyst recovery system according to claim 3 , wherein
the partitioning wall is inclined in a downward direction from the supply port toward a central axis of the settling tank.

5. The catalyst recovery system according to claim 4 , wherein
an inclined wall that is inclined in a downward direction from the supply port toward a central axis of the settling tank is disposed inside the settling tank beneath the partitioning wall, with a space provided between the inclined wall and the partitioning wall, and
an angle of inclination of the inclined wall is at least as large as an angle of repose of the catalyst particles.

6. The catalyst recovery system according to claim 3 , wherein
a regulation device that restricts the catalyst particles from ascending through the connection passage is provided within the connection passage.

7. The catalyst recovery system according to claim 6 , wherein
the regulation device comprises a baffle plate that extends from an inner peripheral surface of the connection passage, and
the baffle plate is inclined in a downward direction from the inner peripheral surface of the connection passage toward a passage axis of the connection passage.

8. The catalyst recovery system according to claim 3 , wherein
an oil collection tube, an inside of which is connected to the extraction port and which blocks connection between the extraction port and the upper chamber, is provided inside the upper chamber,
a through-hole that interconnects inside the oil collection tube with the upper chamber is provided in the oil collection tube, and
a flow surface area of the through-hole is larger than a flow surface area of the extraction port.

9. The catalyst recovery system according to claim 2 , wherein
the settling tank comprises a tank heating device that heats an inside of the settling tank.

10. The catalyst recovery system according to claim 2 , wherein
the settling tank comprises an interface detection device that detects a settling interface of the concentrated slurry inside the settling tank.

11. The catalyst recovery system according to claim 2 , wherein
the first discharge unit comprises:
a first upper line that discharges the concentrated slurry from the settling tank,
a temporary hopper into which the concentrated slurry is discharged from the first upper line,
a first lower line that discharges the concentrated slurry from the temporary hopper,
a first upper valve that opens and closes the first upper line, and
a first lower valve that opens and closes the first lower line.

12. The catalyst recovery system according to claim 11 , wherein
the temporary hopper comprises a hopper heating device that heats an inside of the temporary hopper.

13. The catalyst recovery system according to claim 11 , wherein
the temporary hopper comprises a first hopper pressurization device that pressurizes an inside of the temporary hopper.

14. The catalyst recovery system according to claim 2 , further comprising:
a clarified line through which the clarified slurry is extracted from the settling tank, wherein
a pressure reducing valve that reduces a pressure of the clarified slurry inside the clarified line is provided within the clarified line.

15. The catalyst recovery system according to claim 14 , further comprising:
a centrifugal separator to which the clarified slurry is supplied from the clarified line, and
a second discharge unit that discharges a residual catalyst-containing slurry separated from the clarified slurry by the centrifugal separator, wherein
the second discharge unit comprises:
a second upper line that discharges the residual catalyst-containing slurry from the centrifugal separator,
a residual catalyst hopper into which the residual catalyst-containing slurry is discharged from the second upper line, and
a second lower line that discharges the residual catalyst-containing slurry from the residual catalyst hopper, and
the residual catalyst hopper comprises a second hopper pressurization device that pressurizes an inside of the residual catalyst hopper.

16. The catalyst recovery system according to claim 1 , wherein
the solidified slurry production unit comprises:
a cooling hopper into which the concentrated slurry is discharged and
a cooling device that cools the inside of the cooling hopper, and
the cooling hopper comprises a gas disposal line through which gas inside the cooling hopper is discarded.

17. The catalyst recovery system according to claim 1 , wherein
the recovery mechanism comprises a crushing device that crushes the solidified slurry.

18. A hydrocarbon synthesis reaction apparatus that synthesizes hydrocarbon compounds by bringing a synthesis gas comprising hydrogen gas and carbon monoxide gas as main components into contact with a slurry prepared by suspending solid catalyst particles within a liquid medium, the apparatus comprising:
a reactor main unit that contains the slurry and is supplied with the synthesis gas, and
the catalyst recovery system according to claim 1 .

19. A hydrocarbon synthesis reaction system comprising:
the hydrocarbon synthesis reaction apparatus according to claim 18 ,
a synthesis gas production unit that reforms a hydrocarbon feedstock to produce the synthesis gas, and supplies the synthesis gas to the reactor main unit, and
an upgrading unit that produces liquid fuels from the synthesis gas.

20. A catalyst recovery process for recovering catalyst particles incorporated within a slurry contai

Assignees

• Shibata Toshiyuki
• Honda Hidekatsu
• Kawamura Akira
• Japan Oil Gas & Metals Jogmec
• Inpex Corp
• Jx Nippon Oil & Energy Corp
• Japan Petroleum Exploration Co Ltd
• Cosmo Oil Co Ltd
• Nippon Steel & Sumikin Eng Co

Inventors

• Shibata Toshiyuki
• Honda Hidekatsu
• Kawamura Akira

Classifications

• B01J2219/185

  vertical · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• B01D21/0045

  Plurality of essentially parallel plates · CPC title

• C10G2300/70

  Catalyst aspects · CPC title

• B01D21/0048

  Plurality of plates inclined in alternating directions · CPC title