Flashline heater system and method

Patent metadata

Field	Value
Publication number	US-2016264693-A1
Application number	US-201615069778-A
Country	US
Kind code	A1
Filing date	Mar 14, 2016
Priority date	Jun 30, 2011
Publication date	Sep 15, 2016
Grant date	—

Abstract

The present embodiments provide a system and method for separation within a polymer production process. Specifically, a flashline heater configured according to present embodiments may provide more time than is required for complete vaporization of liquid hydrocarbons that are not entrained within a polymer fluff produced within a polymerization reactor. Such extra time may allow for liquid hydrocarbons that are entrained within the polymer fluff to be vaporized.

First claim

1 .- 22 . (canceled)

23 . A method, comprising:
polymerizing an olefin monomer in a reactor using an olefin polymerization catalyst to generate a polymer slurry, wherein the polymer slurry includes polymer fluff and liquid; receiving a discharge stream comprising the polymer slurry from the reactor in a flashline heater; heating the discharge stream in the flashline heater such that the liquid, including liquid entrained within the polymer fluff, vaporizes, wherein the polymer fluff and the vapor generated from vaporization of the liquid substantially reach thermal equilibrium with one another within the flashline heater; receiving the discharge stream in a flash chamber from an outlet of the flashline heater; separating the discharge stream into flash gas and a polymer fluff stream; and discharging the flash gas as an overhead discharge from the flash chamber, wherein at least 98% of the overhead discharge corresponds to the vapor received from the outlet of the flashline heater.

24 . The method of claim 23 , comprising generating polyolefin pellets from the polymer fluff stream downstream of the flash chamber.

25 . The method of claim 23 , comprising discharging the polymer fluff stream directly from the flash chamber to a purge column.

26 . The method of claim 23 , wherein heating the discharge stream in the flashline heater such that the liquid, including liquid entrained in the polymer fluff, vaporizes, comprises directing the discharge stream through the flashline heater for at least 8 seconds.

27 . The method of claim 23 , wherein a temperature difference between the polymer fluff and the vapor exiting the flashline heater is less than 1° F.

28 . The method of claim 23 , wherein heating the discharge stream in the flashline heater such that the liquid, including liquid entrained in the polymer fluff, vaporizes, comprises supplying heat to a first section of the flashline heater using a heat exchange medium and not supplying heat to a second section of the flashline heater.

29 . The method of claim 23 , wherein the liquid of the polymer slurry, upon entry into the flashline heater, includes a first portion and a second portion, wherein the first portion is not entrained in the polymer fluff and the second portion is entrained in the polymer fluff, and wherein the polymer fluff and the vapor substantially reach thermal equilibrium with one another at least 2.5 seconds before reaching the flash chamber.

30 . The method of claim 23 , wherein the liquid of the polymer slurry, upon entry into the flashline heater, includes a first portion and a second portion, wherein the first portion is not entrained in the polymer fluff and the second portion is entrained in the polymer fluff, and wherein the polymer fluff and the vapor substantially reach thermal equilibrium with one another at least 5 seconds before reaching the flash chamber.

31 . The method of claim 30 , wherein the vapor comprises substantially all of the second portion at the outlet of the flashline heater.

32 . A method, comprising:
polymerizing an olefin monomer in a reactor using an olefin polymerization catalyst to generate a polymer slurry, wherein the polymer slurry includes polymer fluff and liquid; receiving the polymer slurry discharged from the reactor in a flashline heater; and heating the discharged polymer slurry in the flashline heater such that at least 75% of the liquid, including liquid entrained within the polymer fluff, vaporizes.

33 . The method of claim 32 , comprising generating polyolefin pellets from the polymer fluff stream downstream of the flash chamber.

34 . The method of claim 32 , wherein at least 98% of the liquid vaporizes.

35 . The method of claim 32 , wherein heating the discharged polymer slurry in the flashline heater such that at least 75% of the liquid vaporizes, comprises directing the discharged polymer slurry through the flashline heater for at least 8 seconds.

36 . The method of claim 32 , wherein vapor generated from vaporizing the liquid and the polymer fluff are substantially in thermal equilibrium with one another at a discharge end of the flashline heater.

37 . The method of claim 36 , wherein the liquid of the polymer slurry, upon entry into the flashline heater, includes a first portion and a second portion, wherein the first portion is not entrained in the polymer fluff and the second portion is entrained in the polymer fluff, and wherein the polymer fluff and the vapor substantially reach thermal equilibrium with one another at least 5 seconds before reaching the discharge end of the flashline heater.

38 . The method of claim 37 , wherein the vapor comprises substantially all of the second portion at the discharge end of the flashline heater.

39 . A method, comprising:
polymerizing an olefin monomer in a reactor using an olefin polymerization catalyst to generate a polymer slurry, wherein the polymer slurry includes polymer fluff and liquid; receiving a discharge stream comprising the polymer slurry from the reactor in a flashline heater; heating the discharge stream in the flashline heater such that the liquid vaporizes; receiving the discharge stream in a flash chamber from an outlet of the flashline heater; separating the discharge stream into flash gas and a polymer fluff stream; and extruding the polymer fluff stream to form one or more pellets in an extrusion/load out system, wherein a temperature of the polymer fluff stream received by the extrusion/load out system is within 25° F. of a melting point of the polymer fluff stream.

40 . The method of claim 39 , comprising discharging the polymer fluff stream from the flash chamber directly to a purge column positioned upstream of the extrusion/load out system.

41 . The system of claim 40 , comprising removing residual olefin polymerization catalyst and the remaining liquid in the purge column.

42 . The method of claim 39 , wherein the temperature of the polymer fluff stream received by the extrusion/load out system is within 1° F. of a melting point of the polymer fluff stream.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Hottovy John D
• Kufeld Scott E

Classifications

• C08F110/02 Primary

  Ethene · CPC title

• B01J8/005 Primary

  Separating solid material from the gas/liquid stream (separation processes per se B01D) · CPC title

• B01D1/24

  to obtain dry solids · CPC title

• B01D1/04

  Evaporators with horizontal tubes · CPC title

• B01J19/1837

  Loop-type reactors · CPC title