Scintillator, radiation detection unit, and method of manufacturing scintillator

Patent metadata

Field	Value
Publication number	US-9766353-B2
Application number	US-201314423854-A
Country	US
Kind code	B2
Filing date	Jul 31, 2013
Priority date	Sep 4, 2012
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

Provided is a scintillator that includes: first phosphors each including an inorganic fluorescent compound; and a second phosphor including a fluorescent resin.

First claim

The invention claimed is:

1. A scintillator, comprising:
a first light-emitting section that includes a plurality of first phosphors and a plurality of second phosphors that binds the plurality of first phosphors; and
a second light-emitting section overlaid on the first light-emitting section, wherein the second light-emitting section includes a plurality of third phosphors and a plurality of fourth phosphors that binds the plurality of third phosphors,
wherein
the plurality of first phosphors further includes a plurality of first inorganic fluorescent compounds and the plurality of third phosphors further includes a plurality of second inorganic fluorescent compounds, and
the plurality of second phosphors includes a first resin to absorb energy of radiation impinging thereupon, a first organic fluorescent compound to convert the energy of radiation into a first visible light, and a first wavelength conversion compound to convert the first visible light into a second visible light, wherein the second visible light is different in wavelength from that of the first visible light.

2. The scintillator according to claim 1 ,
wherein the plurality of fourth phosphors includes a second resin and a second organic fluorescent compound.

3. The scintillator according to claim 2 ,
wherein the first resin and the second resin are thermoplastic resins.

4. The scintillator according to claim 1 ,
wherein the second phosphor further includes a second wavelength conversion compound.

5. The scintillator according to claim 1 ,
wherein the plurality of first phosphors and the plurality of third phosphors are configured to emit fluorescent light in different first wavelength bands, and
the plurality of second phosphor and the plurality of fourth phosphors are configured to emit fluorescent light in different second wavelength bands that are further different from the first wavelength bands.

6. The scintillator according to claim 5 , wherein the scintillator is configured to emit higher luminance in wavelength bands that include an overlap of the first wavelength bands and the second wavelength bands.

7. The scintillator according to claim 1 ,
wherein density of the plurality of first phosphors in the first light-emitting section is different from density of the plurality of third phosphors in the second light-emitting section.

8. The scintillator according to claim 1 ,
wherein the plurality of first phosphors and the plurality of third phosphors differ from each other with respect to the plurality of first inorganic fluorescent compounds and the plurality of second inorganic fluorescent compounds included in the plurality of first phosphors and the plurality of third phosphors, respectively based at least on composition, shape or size.

9. The scintillator according to claim 1 ,
wherein a first radiation transmitted by the first light-emitting section is converted into fluorescent light by the second light-emitting section, and a second radiation transmitted by the second light-emitting section is converted into fluorescent light by the first light-emitting section.

10. The scintillator according to claim 1 ,
wherein the plurality of second phosphors and the plurality of fourth phosphors differ from each other with respect to fluorescent resins included in the plurality of second phosphors and the plurality of fourth phosphors, based on one or both of: a structural unit and molecular weight.

11. A radiation detection unit, comprising:
a scintillator that includes:
a first light-emitting section and a second light-emitting section overlaid on the first light-emitting section, wherein
the first light-emitting section includes a plurality of first phosphors and a plurality of second phosphors that binds the plurality of first phosphors, and
the second light-emitting section includes a plurality of third phosphors and a plurality of fourth phosphors that binds the plurality of third phosphors,
wherein
the plurality of first phosphors further includes a plurality of first inorganic fluorescent compounds and the plurality of third phosphors further includes a plurality of second inorganic fluorescent compounds, and
the plurality of second phosphors includes a first resin to absorb energy of radiation impinging thereupon, a first organic fluorescent compound to convert a the energy of radiation into a first visible light, and a first wavelength conversion compound to convert the first visible light into a second visible light, wherein the second visible light is different in wavelength from that of the first visible light; and

a photoelectric conversion component.

12. The radiation detection unit according to claim 11 ,
wherein the photoelectric conversion component includes single crystal silicon.

13. The radiation detection unit according to claim 11 ,
wherein the photoelectric conversion component has sensitivities at emission wavelengths of the plurality of first phosphors, the plurality of second phosphors, the plurality of third phosphors, and the plurality of fourth phosphors.

14. The radiation detection unit according to claim 11 , further comprising a radiation irradiation section.

15. A method of manufacturing a scintillator, comprising:
mixing a plurality of first phosphors with a plurality of second phosphors in a first light-emitting section, and a plurality of third phosphors with a plurality of fourth phosphors in a second light-emitting section,
wherein the second light-emitting section is overlaid on the first light-emitting section,
wherein the plurality of second phosphors binds the plurality of first phosphors and the plurality of third phosphors binds the plurality of fourth phosphors,
wherein the plurality of first phosphors further includes a plurality of first inorganic fluorescent compounds and the plurality of third phosphors further includes a plurality of second inorganic fluorescent compounds, and
wherein the plurality of second phosphors includes a first resin to absorb energy of radiation impinging thereupon, a first organic fluorescent compound to convert the energy of radiation into a first visible light, and a first wavelength conversion compound to convert the first visible light into a second visible light, wherein the second visible light is different in wavelength from that of the first visible light; and

curing the plurality of second phosphors and the plurality of fourth phosphors.

16. The method of manufacturing the scintillator according to claim 15 ,
wherein the plurality of second phosphors and the plurality of fourth phosphors differ from each other with respect to thermoplastic resins included in the plurality of second phosphors and the plurality of fourth phosphors.

17. A scintillator, comprising:
a first composite that includes a first plurality of phosphor particles, wherein each particle of the first plurality of phosphor particles includes a first inorganic fluorescent compound and a first resin that binds the first plurality of phosphor particles;
a second composite that includes a second plurality of phosphor particles, wherein each particle of the second plurality of phosphor particles includes a second inorganic fluorescent compound and a second resin that binds the second plurality of phosphor particles,
wherein the first plurality of phosphor particles and the second plurality of phosphor particles differ from each other with respect to the first inorganic fluorescent compound and the second inorganic fluorescent compounds contained therein, respectively; and
a second phosphor that binds the f

Assignees

• Sony Corp

Inventors

• Kawanishi Mitsuhiro
• Igarashi Takahiro
• Oguchi Shinichi

Classifications

• G01T1/2018

  Scintillation-photodiode combinations · CPC title

• C09K2211/1416

  Condensed systems · CPC title

• G01T1/2033 Primary

  Selection of materials · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• C09K2211/1408

  Carbocyclic compounds · CPC title