Method for making porous mullite-containing composites

Patent metadata

Field	Value
Publication number	US-9764991-B2
Application number	US-201214345423-A
Country	US
Kind code	B2
Filing date	Nov 7, 2012
Priority date	Nov 21, 2011
Publication date	Sep 19, 2017
Grant date	Sep 19, 2017

Abstract

Porous aluminum-containing ceramic bodies are treated to form acicular mullite crystals onto the surfaces of their pores. The crystals are formed by contacting the body with a fluorine-containing gas or a source of both fluorine and silicon atoms to form fluorotopaz at the surface of the pores, and then decomposing the fluorotopaz to form acicular mullite crystals. This process allows the surface area of the ceramic body to be increased significantly while retaining the geometry (size, shape, general pore structure) of the starting body. The higher surface area makes the body more efficient as a particulate filter and also allows for easier introduction of catalytic materials.

First claim

What is claimed is:

1. A porous aluminate-containing ceramic body, wherein the aluminate is not acicular mullite, the ceramic body having acicular mullite crystals from decomposition of fluorotopaz bonded to an external surface of the ceramic body and internal pore surfaces of at least some of the pores, wherein a surface area of the ceramic body is increased to about 1.5 to about 10 times that of an aluminate-containing ceramic body without acicular mullite crystals, and wherein the ceramic body is a filter for removing particulate matter from combustion exhaust streams.

2. The ceramic body of claim 1 , wherein the aluminate is selected from alumina, aluminum titanate, non-acicular mullite, cordierite and an alkali aluminosilicate.

3. The ceramic body of claim 1 , wherein the ceramic body is densified to at least 90% of its theoretical density, except for the presence of the pores.

4. The ceramic body of claim 1 , which has a porosity of about 30% to 85%.

5. The ceramic body of claim 1 , wherein the pore size is from 5 to 50 microns, as measured by mercury porosimetry.

6. The ceramic body of claim 1 , which is a honeycomb having one or more axially-extending cells defined by intersecting axially-extending porous walls.

7. The ceramic body of claim 1 , wherein the acicular mullite crystals are bonded to the internal surface of at least some of the pores by contacting the pores with a gaseous fluorine-containing compound or a gaseous source of silicon atoms and fluorine atoms to form a fluorotopaz on the internal surface of at least some of the pores and heating the ceramic body to convert the fluorotopaz to the acicular mullite crystals.

8. The ceramic body of claim 7 , wherein the fluorine-containing compound is one or more of SiF 4 , AlF 3 , HF, Na 2 SiF 6 , NaF, NH 4 F, methylene difluoride, trifluoromethane, tetrafluoromethane, 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,2-trifluoroethane, 1,1,1-trifluoroethane, 1,1-difluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,2,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoroethane, 1,1,2,2,3-pentafluoropentane, 1,1,1,4,4,4-hexafluorobutane and 1,1,1,3,3-pentafluorobutane.

9. The ceramic body of claim 1 , wherein the acicular mullite crystals are uniformly distributed throughout the pores of the ceramic body.

10. A process for making the porous aluminate-containing ceramic body of claim 1 , comprising
(a) contacting the pores of a starting porous aluminate-containing ceramic body with a gaseous fluorine-containing compound or, if the starting porous aluminate-containing ceramic body does not contain silicon, a gaseous source of silicon atoms and fluorine atoms, at a temperature from 700 to 1200° C. to form a fluorotopaz on at least a portion of the surface of the pores of the porous aluminate-containing ceramic body and then
(b) heating the ceramic body to a temperature of 1000 to 1500° C. to convert the fluorotopaz to acicular mullite whiskers attached to the surfaces of the pores of the ceramic body and to an external surface of the ceramic body.

11. The process of claim 10 , wherein the aluminate is selected from alumina, aluminum titanate, non-acicular mullite, cordierite and an alkali aluminosilicate.

12. The process of claim 10 , wherein the starting ceramic body preferably is densified to at least 90% the theoretical density, except for the presence of the pores.

13. The process of claim 10 , wherein the starting ceramic body has a porosity of about 30% to 85%.

14. The process of claim 10 , wherein the pore size is from 5 to 50 microns, as measured by mercury porosimetry.

15. The process of claim 10 , wherein the fluorine-containing compound is one or more of SiF 4 , AlF 3 , HF, Na 2 SiF 6 , NaF, NH 4 F, methylene difluoride, trifluoromethane, tetrafluoromethane, 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,2-trifluoroethane, 1,1,1-trifluoroethane, 1,1-difluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,2,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoroethane, 1,1,2,2,3-pentafluoropentane, 1,1,1,4,4,4-hexafluorobutane and 1,1,1,3,3-pentafluorobutane.

16. The process of claim 10 , wherein the starting ceramic body is a honeycomb having one or more axially-extending cells defined by intersecting axially-extending porous walls.

17. The process of claim 10 , wherein the surface area of the product ceramic body is increased to 1.5 to 10 times that of the starting ceramic body.

18. The process of claim 10 further comprising, after step b), depositing a metal onto the surface of the ceramic body.

Assignees

• Dow Global Technologies Llc

Inventors

• Pyzik Aleksander J
• Shinkel Nicholas M
• Ziebarth Robin P

Classifications

• C04B38/0054

  the pores being microsized or nanosized · CPC title

• C04B41/5037

  Clay, Kaolin · CPC title

• C04B35/62863

  Silicon carbide · CPC title

• C04B41/457

  Non-superficial impregnation or infiltration of the substrate · CPC title

• C04B35/478

  based on aluminium titanates · CPC title