Catalyst for olefin polymerization and polymerization thereof

Patent metadata

Field	Value
Publication number	US-9758602-B2
Application number	US-201615051459-A
Country	US
Kind code	B2
Filing date	Feb 23, 2016
Priority date	Feb 23, 2015
Publication date	Sep 12, 2017
Grant date	Sep 12, 2017

Abstract

The present invention describes a process for preparing catalyst for the polymerization of ethylene consisting essentially of the steps of (i) contacting a magnesium based precursor with a solvent; and (ii) then contacting the magnesium based precursor in the solvent with a transition metal compound to obtain the catalyst, wherein step (ii) is single contact step. The present invention also relates to a process for preparation of a catalyst system and a process of polymerizing and/or copolymerizing of ethylene to obtain a polyethylene using the catalyst.

First claim

We claim:

1. A process for preparing catalyst for the polymerization of ethylene consisting essentially of the steps of:
contacting a magnesium based precursor with a solvent; and
(ii) then contacting the magnesium based precursor in the solvent with a transition metal compound to obtain the catalyst,
wherein step (ii) is single contact step; and
wherein the magnesium based precursor is liquid or solid in nature; and
wherein the liquid magnesium based precursor is prepared by contacting magnesium source with organohalide and alcohol in presence of the solvent in a single step; or
wherein the solid magnesium based precursor is prepared by first contacting the magnesium source with organohalide in presence of solvating agent as the first step and then followed by addition of alcohol.

2. The process as claimed in claim 1 , wherein the solvent is aromatic or aliphatic and polar or non polar in nature, and is selected from the group consisting of benzene, decane, kerosene, ethyl benzene, chlorobenzene, dichlorobenzene, toluene, o-chlorotoluene, xylene, dichloromethane, chloroform, cyclohexane and combination thereof.

3. The process as claimed in claim 1 , wherein the contact time with the solvent in step (i) is immediate to 5 h.

4. The process as claimed in claim 1 , wherein the contact temperature with the solvent in step (i) is from 10° C. to 200° C.

5. The process as claimed in claim 1 , wherein the magnesium based precursor is contacted with solvent prior to transition metal contact.

6. The process as claimed in claim 1 , wherein the transition metal compound is represented by M(OR) p X 4-p , where M is selected from the group consisting of Ti, V, Zr, and Hf,; X is a halogen atom; R is a hydrocarbon group and p is an integer having value equal or less than 4, the transition metal compound is selected from the group consisting of transition metal tetrahalide, alkoxy transition metal trihalide/aryloxy transition metal trihalide, dialkoxy transition metal dihalide, trialkoxy transition metal monohalide, tetraalkoxy transition metal, and mixtures thereof; wherein:
(a) the transition metal tetrahalide is selected from the group consisting of titanium tetrachloride, titanium tetrabromide, titanium tetraiodide vanadium tetrachloride, vanadium tetrabromide, vanadium tetraiodide, zirconium tetrachloride, zirconium tetrabromide, zirconium tetraiodide, hafnium tetrachloride, hafnium tetrabromide, and hafnium tetraiodide;
(b) alkoxy transition metal trihalide/aryloxy transition metal trihalide is selected from the group consisting of methoxytitanium trichloride, ethoxytitanium trichloride, butoxytitanium trichloride, phenoxytitanium trichloride, methoxyvanadium trichloride, ethoxyvanadium trichloride, butoxyvanadium trichloride, phenoxyvanadium trichloride, methoxyzirconium trichloride, ethoxyzirconium trichloride, butoxyzirconium trichloride, phenoxyzirconium trichloride, methoxyhafnium trichloride, ethoxyhafnium trichloride, butoxyhafnium trichloride, and phenoxyhafnium trichloride;
(c) dialkoxy transition metal dihalide is selected from the group consisting of diethoxy titanium dichloride, diethoxy vanadium dichloride, diethoxydiethoxy zirconium dichloride, and diethoxydiethoxy hafnium dichloride;
(d) trialkoxy transition metal monohalide is selected from the group consisting of triethoxy titanium chloride, triethoxy vanadium chloride, triethoxy zirconium chloride, and triethoxy hafnium chloride; and
(e) tetraalkoxy transition metal is selected from the group consisting of tetrabutoxy titanium, tetraethoxy titanium, tetrabutoxy vanadium, tetraethoxy vanadium, tetrabutoxy zirconium, tetraethoxy zirconium, tetrabutoxy hafnium, and tetraethoxy hafnium.

7. The process as claimed in claim 1 , wherein the contact temperature with the transition metal compound in step (ii) is between −50° C. and 150° C.

8. The process as claimed in claim 1 , wherein the transition metal compound is a titanium compound and added in amounts ranging from 1 to 20 moles with respect to one mole of magnesium.

9. The process as claimed in claim 1 , wherein the transition metal compound is used either neat or in solvent and wherein the solvent is selected from the group consisting of chlorinated aromatic hydrocarbon, non chlorinated aromatic hydrocarbon, chlorinated aliphatic hydrocarbon, non chlorinated aliphatic hydrocarbon and combination thereof.

10. The process as claimed in claim 9 , wherein the solvent comprises from 40 to 60 volume percent and selected from the group consisting of benzene, decane, kerosene, ethyl benzene, chlorobenzene, dichlorobenzene, toluene, o-chlorotoluene, xylene, dichloromethane, chloroform, cyclohexane and combination thereof.

11. The process as claimed in claim 1 , wherein the contact temperature with the transition metal compound in step (ii) is between −50° C. and 150° C. and heating is instigated at a rate of 0.1 to 10.0° C./minute.

Assignees

• Indian Oil Corp Ltd

Inventors

• Singh Gurmeet
• Kumar Naresh
• Bantu Bhasker
• Kaur Sukhdeep
• Rani Rashmi
• MOMIN Mohasin
• Kapur Gurpreet Singh
• Shashikant
• Basu Biswajit
• Malhotra Ravinder Kumar

Classifications

• C08F110/02

  Ethene · CPC title

• C08F210/08

  Butenes · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F2500/18

  Bulk density · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title